全文获取类型
收费全文 | 269篇 |
免费 | 20篇 |
国内免费 | 3篇 |
专业分类
测绘学 | 7篇 |
大气科学 | 19篇 |
地球物理 | 73篇 |
地质学 | 91篇 |
海洋学 | 32篇 |
天文学 | 32篇 |
自然地理 | 38篇 |
出版年
2024年 | 2篇 |
2022年 | 2篇 |
2021年 | 2篇 |
2020年 | 7篇 |
2019年 | 8篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 13篇 |
2015年 | 4篇 |
2014年 | 13篇 |
2013年 | 21篇 |
2012年 | 20篇 |
2011年 | 32篇 |
2010年 | 26篇 |
2009年 | 22篇 |
2008年 | 8篇 |
2007年 | 13篇 |
2006年 | 9篇 |
2005年 | 14篇 |
2004年 | 8篇 |
2003年 | 7篇 |
2002年 | 9篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1996年 | 1篇 |
1994年 | 5篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1979年 | 1篇 |
1973年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有292条查询结果,搜索用时 12 毫秒
51.
52.
53.
Stephanodiscus niagarae populations in a core from Lake Ontario show systematic variation in radial puncta number and mean valve diameter. Puncta number is stable in specimens from samples deposited between 1720 and 1844. Puncta number gradually increases in samples deposited between 1860 and 1947, then increases rapidly to high numbers in samples deposited after 1964. Mean valve diameter is relatively high in specimens from samples deposited between 1720 and 1959. Diameter of specimens deposited during this period fluctuates around a mean of 63.2 m. Mean diameter of specimens deposited from 1959 to 1980 is only 42.5 m. We conclude that the trend in puncta number reflects the time course of eutrophication in Lake Ontario. We interpret the precipitous decline in mean diameter as an indication that conditions in the lake after the late 1950's did not permit sexual reproduction in this species. 相似文献
54.
Eric H. Oelkers Sergey V. Golubev Claire Chairat Oleg S. Pokrovsky Jacques Schott 《Geochimica et cosmochimica acta》2009,73(16):4617-6554
The surface chemistry of natural wollastonite, diopside, enstatite, forsterite, and albite in aqueous solutions was characterized using both electrokinetic techniques and surface titrations performed for 20 min in batch reactors. Titrations performed in such reactors allow determination of both proton consumption and metal release from the mineral surface as a function of pH. The compositions, based on aqueous solution analysis, of all investigated surfaces vary dramatically with solution pH. Ca and Mg are preferentially released from the surfaces of all investigated divalent metal silicates at pH less than ∼8.5-10 but preferentially retained relative to silica at higher pH. As such, the surfaces of these minerals are Si-rich and divalent metal poor except in strongly alkaline solutions. The preferential removal of divalent cations from these surfaces is coupled to proton consumption. The number of protons consumed by the preferential removal of each divalent cation is pH independent but depends on the identity of the mineral; ∼1.5 protons are consumed by the preferential removal of each Ca atom from wollastonite, ∼3 protons are consumed by the preferential removal of each Mg or Ca atom from diopside or enstatite, and ∼4 protons are consumed by the preferential removal of each Mg from forsterite. These observations are interpreted to stem from the creation of additional ‘internal’ adsorption sites by the preferential removal of divalent metal cations which can be coupled to the condensation of partially detached Si. Similarly, Na and Al are preferentially removed from the albite surface at 2 > pH > 11; mass balance calculations suggest that three protons are consumed by the preferential removal of each Al atom from this surface over this entire pH range. Electrokinetic measurements on fresh mineral powders yield an isoelectric point (pHIEP) 2.6, 4.4, 3.0, 4.5, and <1, for wollastonite, diopside, enstatite, forsterite, and albite, respectively, consistent with the predominance of SiO2 in the surface layer of all of these multi-oxide silicates at acidic pH. Taken together, these observations suggest fundamental differences between the surface chemistry of simple versus multi-oxide minerals including (1) a dependency of the number and identity of multi-oxide silicate surface sites on the aqueous solution composition, and (2) the dominant role of metal-proton exchange reactions on the reactivity of multi-oxide mineral surfaces including their dissolution rate variation with aqueous solution composition. 相似文献
55.
56.
Claire Rollion-Bard Dominique Blamart Yannicke Dauphin 《Geochimica et cosmochimica acta》2010,74(4):1338-173
We present ion microprobe measurements of oxygen isotopic compositions in the deep-sea coral Lophelia pertusa. Compared to bulk skeletal aragonite fibres, the EMZ (early mineralization zone), near the inside of the calyx, was systematically depleted in 18O. Rayleigh fractionation from a semi-closed fluid reservoir does not explain this and other geochemical differences. Furthermore, pH values estimated from skeletal δ11B data are inconsistent with the idea that EMZ (or centres of calcification) 18O depletion reflects a more alkaline calcification environment. Our data, combined with microstructural and geochemical observations, indicate that the aragonitic fibres and EMZ are formed by a compartmentalized mineralization calicoblastic ectoderm, which exerts strong biological control on the composition of the skeleton. Hence, we propose a new model whereby amorphous calcium carbonates (ACC) are precursors to the EMZ, whereas the fibre precipitation is probably governed by kinetic processes. 相似文献
57.
Threshold of wave generation on Titan’s lakes and seas: Effect of viscosity and implications for Cassini observations 总被引:1,自引:0,他引:1
Motivated by radar and near-infrared data indicating that Titan’s polar lakes are extremely smooth, we consider the conditions under which a lake surface will be ruffled by wind to form capillary waves. We evaluate laboratory data on wind generation and derive, without scaling for surface tension effects, a threshold for pure methane/ethane of ∼0.5-1 m/s. However, we compute the physical properties of predicted Titan lake compositions using the National Institute for Standards Technology (NIST) code and note that dissolved amounts of C3 and C4 compounds are likely to make Titan lakes much more viscous than pure ethane or methane, even without allowing for suspended particulates which would increase the viscosity further. Wind tunnel experiments show a strong dependence of capillary wave growth on liquid viscosity, and this effect may explain the apparent absence so far of waves, contrary to prior expectations that generation of gravity waves by wind should be easy on Titan. On the other hand, we note that winds over Titan lakes predicted with the TitanWRF Global Circulation Model indicate radar observations so far have in any case been when winds have been low (∼0.5-0.7 m/s), possibly below the wave generation threshold, while peak winds during summer may reach 1-2 m/s. Thus observations of Titan’s northern lakes during the coming years by the Cassini Solstice mission offer the highest probability of observing wind-roughening of lake surfaces, while observations of Ontario Lacus in the south will likely continue to show it to be flat and smooth. 相似文献
58.
Claire Workman Love Dalen Sergey Vartanyan Beth Shapiro Pavel Kosintsev Andrei Sher Anders Gotherstrom Ian Barnes 《Quaternary Science Reviews》2011,30(17-18):2304-2308
Patterns in the spatial or temporal distribution of genotypes may be indicative of natural selection. Previous work on the woolly mammoth melanocortin-1 receptor (Mc1r) gene identified three polymorphic positions that suggest Pleistocene populations may have harboured both light- and dark-haired mammoths (Rompler et al., 2006, 313: 62). Here, we extend this work and present the first population-level analysis of a functional gene in an extinct species. We genotyped the Mc1r gene in 47 woolly mammoth samples excavated from sites across the central portion of the woolly mammoths’ former range to examine the extent of variation of this polymorphism through time and across space. Only one individual was found to be heterozygous, indicating that the frequency of the ‘light’ mutant allele was very low. We conclude that light-coloured woolly mammoths would have been very rare, and may even have been non-existent if the ‘light’ mutant allele was strongly selected against in its homozygotic form. With the increasing availability of large-scale sequencing technologies, population-level datasets capable of identifying local adaptation will become increasingly attainable. 相似文献
59.
Data were obtained for rubidium in six geological reference materials by isotopic dilution thermal ionisation mass spectrometry (ID-TIMS) and wavelength dispersive X-ray fluorescence spectrometry (WD-XRF). The results found by one technique compare very well with the other within the respective analytical uncertainties and are also in good agreement with data from previously published values. The particular case of low Rb determinations in reference sample BIR-1 is discussed. 相似文献
60.
Claire L. Schelske Arthur Peplow Mark Brenner Craig N. Spencer 《Journal of Paleolimnology》1994,10(2):115-128
Sediment cores from three lakes were dated with210Pb using a constant rate of supply (CRS) model. We used low-background gamma counting to measure naturally occurring levels of210Pb,226Ra, and137Cs in sediment samples because sample preparation is simple and non-destructive,226Ra activity provides a direct measure of supported210Pb activity for each sample analyzed, and137Cs activity may provide an independent age marker for the 1962–1963 peak in atmospheric fallout of this radionuclide. In one core supported210Pb activity was estimated equally well from226Ra activity of each sampling interval or from the mean total210Pb activity of constant activity samples at depth. Supported210Pb activity was constant with depth in this core. In a short freeze core, determining226Ra activity of every sample proved advantageous in estimating supported210Pb activity because supported210Pb activity could be estimated from210Pb measurements only at the deepest sampling interval. Supported210Pb activity estimated from226Ra activity also yielded more precise estimates of highly variable sedimentation rates. In the third core226Ra activity exceeded210Pb activity at the top of the core and varied 20 fold with depth. This high input of226Ra in disequilibrium with210Pb is attributed to recent erosion of radium-bearing materials in the drainage basin. These data invalidate the assumption that supported210Pb activity is constant in sediment cores and can be estimated from the mean total210Pb activity at depths where210Pb activity is constant. We recommend using gamma counting or another independent assay of226Ra to validate the assumption of constant supported210Pb activity in sediment cores if there is reason to expect that226Ra activity varies with depth.This is the fourth of a series of papers to be published by this journal following the 20
th
anniversary of the first application of210Pb dating of lake sediments. Dr. P.G. Appleby is guest editing this series. 相似文献