Hydrological characteristics of karstic groundwater in the northeast Viet Nam as studied by isotopic techniques

The stable water isotopic composition (δ²H and δ¹⁸Ο), tritium (³H) activity, dissolved organic carbon, alkalinity, as well as the composition of carbon 13 (δ¹³C) in dissolved inorganic carbon (DIC) of 36 water samples taken from 16 resurgences in the northeast provinces of Viet Nam in the dry (Mar 2008) and rainy (June 2008) seasons were analyzed to elucidate hydrological characteristics of the karstic aquifers in the area. The stable water isotopic composition of the water samples collected clearly demonstrated that the karstic groundwater in the region was recharged from the local meteorological water. The tritium activity in the samples was found to be in between 3 and 4 TU, falling in the range of the ³H activity in the local precipitation and thus meaning that the traveling of recharge water to the resurgences was very short. Concentrated and diffuse allogenic recharges seem to be important sources of karstic groundwater in the study region. Water in the karstic aquifers could be classified into three types as: (a) water from karstic areas with dense vegetation cover that causes DIC be depleted in carbon 13 (¹³δ<?12‰ vs. Pee Dee Belemnite standard of Vienna, VPDB); (b) water from karstic areas with poor vegetation cover that originates DIC with carbon 13 composition ranging from ?11 to ?12‰; and (c) surface water from lakes, springs and rivers that has DIC with enriched carbon 13 (δ¹³C >?10‰). This implies that there are several sources of carbon dioxide contributing to the DIC in water of the karstic aquifers in the study region. Among other potential sources, the atmospheric CO₂, CO₂ from carbonate rock dissolution, biomineralization of soil organic matters and plant roots respiration seem to be important sources of the DIC in the waters of this region. The results show high vulnerability towards anthropogenic contaminants of karstic groundwater in the study region.     

Geochemical and Sr-Nd isotopic study of alkaline syenites in Liangtun-Kuangdonggou, Liaoning Province, China： Evidence for enriched mantle before 1.86 Ga and implications

The 1.86 Ga Liangtun-Kuangdonggou complex (LKC) is one of the oldest alkaline syenite bodies so far discovered in China. This syenite suite has elevated contents of total alkali (K2O Na2O), with an average of 10.50%, and a mean Rittmann Index (σ) of 6.48. The intrusions have slightly higher concentrations of K2O than those of Na2O on a weight percent basis, indicating the rocks belong to potassium-rich alkaline syenite series. Total rare-earth element concentrations (∑REE ) of the rocks are relatively high, ranging from 324×10 -6 to 1314×10 -6, with a mean value of 666×10 -6. The REE patterns are subparallel and rightward steep with (La/Yb)N >33, showing mild negative to positive Eu anomalies (δEu: 0.63-1.15). All samples exhibit strong LILE and LREE enrichments and TNT (Nb, Ta, Ti) and P depletions in multi-element spidergrams. On the εSr(t)-εNd(t) correlation diagram, most analytical data points plot within the enriched mantle field with low ( 87Sr/86Sr)i ratios (0.7045-0.7051) and negative εNd(t) values (-3.72--3.97), falling among those kimberlites from Fuxian County, Liaoning Provinve, from Mengyin County, Shandong Province and the Ⅱ-type kimberlites from South Africa. These characteristics imply that the LKC-rocks may have the same source as the above-mentioned kimberlites, i.e., they have close connections to the materials derived from enriched mantle reservoirs, further revealing that the upper mantle beneath the northeastern part of the North China Plate had been highly enriched before 1.86 Ga. Geodynamically, the LKC-rocks were formed in a within-plate environment with close genetic connections to rift-related alkaline magma activities possibly controlled by ancient mantle plumes.     

浙江晚中生代雁荡山地貌成因及其与火山构造协同性演化规律

浙江雁荡山是东南沿海一座典型的晚中生代破火山，以发育丰富的白垩纪流纹质火山岩地貌为特色，主要包括火山岩相剖面和火山岩地貌两种类型地质遗迹。本次通过详细的野外地质调查、岩石学研究及遥感图像分析，进一步将其中火山岩相剖面划分为溢流相、基底涌流相、火山碎屑流相、空落相剖面地质遗迹四小类；火山岩地貌分为叠嶂、锐峰和岩洞地貌地质遗迹三小类，并综合分析了其分布规律与成因演化过程。研究表明这些地质遗迹的分布和演化明显受到火山构造与火山岩相的控制。另外，研究区显著发育3级夷平面，反映其至少经历过3期隆升- 剥蚀事件，是太平洋板块、菲律宾海板块与欧亚大陆板块相互作用的动力学过程及印度板块碰撞远程效应的综合影响结果，同时其也是研究流纹质火山岩地貌成因与演化过程的理想基地。     

新疆若羌县红柳沟Ⅰ号剖面新元古界成冰系冰沟南组硅质岩特征与沉积环境*

新疆若羌县红柳沟Ⅰ号剖面出露厚约300 m的新元古界成冰系冰沟南组的细粒沉积物和碳酸盐岩等,并发现有沥青油气显示。通过厚160 m左右硅质岩剖面实测以及岩石学、地球化学等研究表明: 红柳沟Ⅰ号剖面中的硅质岩主要由石英、黏土构成,有微量的含铁、锰、磷的独立矿物;具有隐晶质、微晶石英和粗-巨晶石英“镶嵌结构”3种结构类型;硅质岩中SiO₂、Fe₂O₃、Ba和δEu_n值相对较高,Al₂O₃、MnO、MnO/TiO₂、U/Th和Sr/Ba值较低,∑REE、Sr/Ba、MnO₂/TiO₂和δCe_n值等呈现有规律的变化;δ³⁰Si值平均为-0.43‰(-0.8‰~0.3‰),$\delta^{18}O_{Snow}$值平均为20.42‰(16.0‰~26.0‰),估算的平均温度为90 ℃(52~127 ℃),指示了硅质岩具有多个沉积旋回,在海水与热水参与的大陆边缘盆地中沉积,并经历了早成岩期、浅埋藏期以及与多期走滑断裂活动有关的热流体与大气淡水的叠加改造。     

云南老王寨金矿的深部地质过程——来自显微岩相学和元素地球化学的证据

通过老王寨金矿围岩、蚀变岩石、矿石的显微岩相学和元素地球化学的系统研究发现：伴随硅化、碳酸盐化等蚀变和硫化物矿化,岩（矿）石中发育沿粒间、裂隙或角闪石解理纹贯入或穿插的黑色不透明超显微隐晶,经电子探针、扫描电镜和能谱分析鉴定,该固体物质主要由超显微晶石英、硅酸盐、碳酸盐、硫化物以及呈熔离交生关系的金红石、白钨矿和镜铁矿（磁铁矿）组成;熔离交生结构与沉淀共晶结构共存的特有岩相学特征指示成矿流体具备由熔体性质向热液性质转化的特性。结合岩（矿）石稀土微量元素研究,认为这种在透射光显微镜下呈黑色不透明的超显微隐晶固体物质,是具熔浆流体特点和超临界流体性质的地幔流体引发交代蚀变的直接微观表现之一;在交代蚀变过程中其性质由熔浆向地壳热液过渡,同时与地壳物质发生混染而有利于成矿作用的进行。     

鲁中碳酸岩中磷灰石同位素地球化学研究

鲁中地区分布着100多个碳酸岩体，微量元素含量及稀土配分等均与世界典型碳酸岩相近。而碳酸岩的碳氧及斑晶磷灰石的锶、钛同位素组成与典型地幔物质有差异，与富集地幔颇为近似，从而证实在山东地区陆壳下存在富集地幔源区。     

一种新的、快速的碳、氮、硫同位素测定手段──EA－IRMS连线分析技术

一种新的、快速的碳、氮、硫同位素测定手段──ＥＡ－ＩＲＭＳ连线分析技术储雪蕾（中国科学院地质研究所，北京１０００２９）关键词元素分析仪－同位素比值质谱仪，连线分析碳，氮，硫同位素碳、氮、硫三种元素的稳定同位素在地学、生态学、环境科学等领域受到了重视，...     

大别山早白垩世变质核杂岩的结构与演化

大别山中部混合岩-片麻岩穹隆的构造属性认识方面一直众说纷纭.通过对中大别杂岩及其边界剪切带或断裂带的构造解析,并结合对前人相关研究的总结,我们将中大别杂岩厘定为早白垩世的变质核杂岩,其中商麻断裂与晓天-磨子潭断裂和水吼-五河剪切带构成了一个完整的拆离断层带,并将变质核杂岩的形成时间限定在145～120 Ma.中大别杂岩...     

黄铁矿的微量元素及热电性和晶体形态分析

金矿床中黄铁矿的微量元素、热电性、晶体形态等标形特征与其形成的物理化学环境及介质条件密切相关。该标型特征在判别不同矿化类型、揭露金矿床空间的变化规律、评价矿体和预测深部矿体等方面都具有一定的代表性和典型性。同时 ,黄铁矿微量元素的分析方法具有易于采样、易于分析、经济有效、方便实用的特点 ,是金矿找矿矿物学研究及应用中行之有效的方法。     

双线偏振雷达测雨效果的对比分析

本文根据1993、1994年15次层状云和12次对流云降雨过程的地面降雨资料和C波段双线偏振雷达资料，对双线偏振雷达和普通雷达测量不同强度降雨的效果进行了评估和比较。结果表明，从相对误差来看，双线偏振雷达使普通雷达的小雨高估、大雨低估的测量误差趋势减弱，它对小到中雨的测量结果优于普通雷达。双线偏振雷达大雨高估的现象可能与强对流性降雨中冰相粒子的存在有关。