基于相似系数的1种算法在遥感图像分类中的应用

用基于向量夹角余弦的相似系数方法对黄河三角洲 1 998年 1 2月份的 Landsat- 5TM遥感影像进行了分类 ,分类精度分析表明用夹角余弦作为分类的相似性度量指标是合理的。这种遥感图像的分类方法简单 ,在实际分类中可以作为常用的方法之一。     

Thermal and haline fronts in the Yellow/East China Seas: Surface and subsurface seasonality comparison

Seasonal variability of surface and subsurface thermal/haline fronts in the Yellow/East China Seas (YES) has been investigated using three-dimensional monthly-mean temperature and salinity data from U.S. Navy’s Generalized Digital Environmental Model (Version 3.0). The density-compensated Cheju-Yangtze Thermal/Haline Front has (northern and southern) double-tongues. The northern tongue is most evident throughout the depth from December to April. The southern tongue is persistent at the subsurface with conspicuous haline fronts. The thermal (haline) frontal intensity of the northern tongue is controlled mainly by the temperature (salinity) variation on the shoreward (seaward) side of the front. The cold water over the Yangtze Bank is influential in generating the southern tongue and intensifying the Tsushima Thermal Front. The year-round Cheju-Tsushima Thermal Front is evident throughout the depth and intensifies from July to December. The northern arc of the Yangtze Ring Haline Front is manifest in spring and is sustained until summer, whereas the southern one is fully developed in summer because of eastward migration of the Yangtze Diluted Water. The area showing strong frontal intensity in the Chinese Coastal Haline Front shifts seasonally north and south along the Zhejiang-Fujian coast. The Generation and evolution of YES fronts are closely associated with YES circulation (inferred from the linkage of the water masses). Moreover, the subsurface temperature/salinity evolution on the fronts in the Yellow Sea differs from that in the East China Sea owing to local factors such as wintertime vertical mixing and a summertime strong thermocline above the Yellow Sea Bottom Cold Water.     

A Comprehensive Method for Precise Determination of Re,Os, Ir,Ru, Pt,Pd Concentrations and Os Isotopic Compositions in Geological Samples

A comprehensive method for the precise determination of Re, Os, Ir, Ru, Pt and Pd concentrations as well as Os isotopic compositions in geological samples is presented. Samples were digested by the Carius tube method, and the Os was extracted by conventional CCl₄ method. The Re, Ir, Ru, Pt and Pd were first subgroup separated from the matrix elements into Re‐Ru, Ir‐Pt and Pd by a 2‐ml anion exchange column. Subsequently, the Re‐Ru was further purified by a secondary 0.25 ml anion exchange column or by microdistillation of Ru using CrO₃‐H₂SO₄ as an oxidant followed by a secondary 0.25 ml anion exchange separation of Re. The Pd and Ir‐Pt were further successively purified by an Eichrom‐LN column to completely remove Zr and Hf, respectively. Rhenium, Ir, Ru, Pt and Pd were individually measured by multi‐collector inductively coupled plasma‐mass spectrometry (MC‐ICP‐MS), except for Ru after microdistillation purification was analysed by negative‐thermal ionisation mass spectrometry (N‐TIMS). The analytical results for peridotite reference material WPR‐1 agree well with the previously published data. Finally, several mafic rock reference materials including TDB‐1, WGB‐1, BHVO‐2, BCR‐2, BIR‐1a and DNC‐1a were analysed for Re‐Os isotopes and platinum‐group element concentrations to test their suitability for certification.     

Evolving patterns of the fluids within the TAG hydrothermal field

The mixing of seawater/hydrothermal fluid within the large seafloor hydrothermal sulfide deposits plays a key role in the formation processes of the sulfide deposits. Some issues attract considerable attentions in the study of seafloor hydrothermal system in recent years, such as the relationships among different types of vent fluids, the characteristics of chemical compositions and mineral assemblages of the hydrothermal deposits and their governing factors. Combined with the measured data of hydrothermal fluid in the TAG field, the thermodynamic model of mixing processes of the heated seawater at different temperatures and the hydrothermal fluid is calculated to understand the precipitation mechanism of anhydrite and the genetic relationships between the black and white smoker fluids within the TAG mound. The results indicate that the heating of seawater and the mixing of hydrothermal fluid/seawater are largely responsible for anhydrite precipitation and the temperature of the heated seawater is not higher than 150°C and the temperature of the end-member hydrothermal fluid is not lower than 400°C. Based on the simulated results, the evolving patterns of fluids within the TAG deposit are discussed. The mixed fluid of the end-member hydrothermal fluid and the seawater heated by wall rock undergoes conductive cooling during upflowing within the deposit and forms “White Smoker” eventually. In addition, the end-member hydrothermal fluid without mixed with seawater, but undergoing conductive cooling, vents out of the deposit and forms “Black Smoker”. Supported by China Ocean Mineral Resources Research and Development Association Program (Grant No. DY115-02-1-01) and National Basic Research Program of China (Grant No. G2000078503)     

西藏高原MODIS每日积雪产品去云算法过程对比验证研究

基于MODIS积雪产品的多种去云方法过程在西藏高原开展对比验证,并以漏测误差L(%)、多测误差M(%)、总体精度O(%)、积雪分类精度S(%)及kappa系数(K_hat)作为验证精度评价指标;主要研究方法有上下午星结合去云法(方法Ⅰ)、连续三天结合去云法(方法Ⅱ)以及基于数字高程模型的Snowl去云法(方法Ⅲ).并采用高分辨率Landsat遥感数据对所得结果开展验证对比工作,为了使验证结果更具有代表性,选取了西藏高原典型的5个区域用于其验证范围.结果表明:方法Ⅰ和方法Ⅱ有较好的去云效果,适合于在西藏高原开展利用;方法Ⅲ在西藏高原没有起到特殊的去云作用,该方法的前提假设是在西藏高原需要考虑山地和高原作分析;通过三种方法去云之后在5个区域效果总体上表现为漏测误差和多测误差都有减少,总体精度和积雪分类精度分别在60%~98%及60%~95%之间,kappa系数在0.10~0.56间,一致性精度表现一般.     

还原氧化石墨烯复合方式对Ag-TiO2基光电极电子传输性能的影响

为进一步提高Ag-TiO₂光催化效能,制备了还原氧化石墨烯（rGO）复合Ag-TiO₂基的光电极。先通过对比不同的复合方式探究rGO对Ag-TiO₂光催化剂表面电子传输和四环素降解效能的影响;再通过电化学阻抗谱测量、莫特-肖特基曲线等电化学手段对电极进行表征。结果表明：分层复合方式主要降低载体表面控制电极双层/薄膜的界面电阻,而全混复合方式主要降低总电荷转移电阻;分层电极的电子供体浓度随rGO质量分数增加而增大;在rGO质量分数为0.45%和0.25%时,分层复合和全混复合材料对四环素的降解速率分别比Ag-TiO₂提高11.4%和2.3%;在外加0.5 V偏压下,分层复合电极LG6降解效率比未加外偏压时提高了5.3%,而全混复合电极MG2效率没有提升。分层复合方式能更有效地提高光催化剂表面电子传输效能。     

Study on the Preparation and Antileukemic Activity of New Lipophilic 1-β-D-arabinofuranosylcytosine Derivatives

Cytarabine(1-β-D-arabinofuranosylcytosine, Ara-C), isolated from a Caribbean sponge species Tethyacrypta, is the first antitumor drug from a marine resource. In 1980, the US Food and Drug Administration approved this drug for the treatment of different types of leukemia. This drug has a short plasma half-life, low stability, limited bioavailability, and severe side effects. To improve stability and bioavailability, we synthesized nine novel derivatives by blocking the cytarabine metabolic sites and improving lipophilicity. The c Log P values of the newly synthesized compounds were calculated. All the synthesized compounds were more lipophilic than cytarabine, resulting in membrane permeability and bioavailability improvement. The antitumor activities against leukemia cell line HL-60 were evaluated by using the MTT assay. The bioassay results revealed that the IC_(50) values of compounds 5, 8 and 9 were 0.080, 0.090 and 0.057 μmol L~(-1), respectively, which was similar with that of cytarabine(0.056 μmol L~(-1),). In comparison, compound 4 with a phosphate group at O5' was inactive. Because phosphoester bonds are easily hydrolyzed by alkaline phosphatase and are commonly used in producing prodrug strategies, compound 4 might also be metabolized in vivo and generate compound 3 or even cytarabine through a multi-step reaction. Thus, compound 4 might be a promising compound to be developed as a prodrug.     

利用Jason-1数据监测呼伦湖水位变化

卫星测高为内陆水域水位变化的实时和连续监测提供了一种高效的技术工具．但是这种应用受到数据点覆盖稀疏的限制。利用Jason-13年（2002-2004）GDRs测高数据作简单的数据编辑,并进行必要的地球物理改正．最后得到内蒙古地区呼伦湖水位变化的时间序列。呼伦湖地区由于近年来持续干旱,水位呈现明显的下降趋势．年平均下降约0．3～0．5m。在一般的内陆水域．水位变化主要取决于降雨量和蒸发量,所以,根据卫星测高所得的水位变化信息．可以为区域气候变化的研究提供一种全新的技术与方法。     

盐度胁迫对小黄鱼(Larimichthys polyactis)抗氧化酶、非特异性免疫酶和Na+/K+-ATP酶活力的影响

为了研究不同盐度对小黄鱼生理的影响,以人工养殖的4月龄小黄鱼(体质量为(12.6±3.1)g)为实验对象,将在自然海水(对照组盐度为22.1)中养殖的小黄鱼转入到盐度为5(低盐组)和34.5(高盐组)的海水中进行急性盐度胁迫处理10 d,测定并分析肝脏中超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、碱性磷酸酶(AKP...     

微绿球藻对氮和磷营养盐需求的研究

通过单因子实验和正交实验方法，研究了对虾高位池一种优良藻株微绿球藻（Nannochloris oculata)对N和P营养盐需求，结果表明：微绿球藻在NO3-N浓度为28．30mg/L和PO4-P浓度为2．076mg/L时，比增长率最大值（μmax)出现最佳值，微绿球藻以各种起始密度培养和小规模培养的均能得到较好的生长效果，μmax可较好地反映微藻种群对多因子的适应性和在对虾池塘中的竞争能力。