Kokchetavite, a new polymorph of K-feldspar (KAlSi3O8), has been identified as micrometer-size inclusions in clinopyroxene and garnet in a garnet-pyroxene rock from the Kokchetav ultrahigh-pressure terrane, Kazakhstan. Kokchetavite has a hexagonal structure with a =5.27(1) Å, c=7.82(1) Å, V=188.09 Å3, Z=1, and is found to be associated with phengite + /-cristobalite (or quartz) + siliceous glass ± phlogopite/titanite/calcite/zircon, occurring as multi-phase inclusions in clinopyroxene and garnet. It is concluded that kokchetavite could not be an exsolution phase in host minerals. Instead, it might be metastably precipitated from an infiltrated K-rich melt during rock exhumation. Alternatively, although less likely, kokchetavite might be derived from dehydration of K-cymrite, which, in turn, was formed at high pressures. In either case, kokchetavite is a metastable polymorph of K-feldspar. 相似文献
Accurate sea surface flux measurements are crucial for
understanding the global water and energy cycles. The oceanic
evaporation, which is a major component of the global oceanic fresh
water flux, is useful for predicting oceanic circulation and
transport. The global Goddard Satellite-based Surface Turbulent
Fluxes Version-2 (GSSTF2; July 1987--December 2000) dateset that was
officially released in 2001 has been widely used by scientific
community for global energy and water cycle research, and regional
and short period data analyses. We have recently been funded by NASA
to resume processing the GSSTF dataset with an objective of
continually producing a uniform dataset of sea surface turbulent
fluxes, derived from remote sensing data. The dataset is to be
reprocessed and brought up-to-date (GSSTF2b) using improved input
datasets such as a recently upgraded NCEP/DOE sea surface
temperature reanalysis, and an upgraded surface wind and microwave
brightness temperature V6 dataset (Version 6) from the Special
Sensor Microwave Imager (SSM/I) produced by Remote Sensing Systems
(RSS). A second new product (GSSTF3) is further proposed with a
finer temporal (12-h) and spatial (0.25ox0.25o)
resolution. GSSTF2b (July 1987--December 2008) and GSSTF3 (July
1999--December 2009) will be released for the research community to
use by late 2009 and early 2011, respectively. 相似文献
The local and geometrical structure around gold (III) e.g., Au3+ ions in aqueous solution with different OH−/Cl− molar ratios, has been investigated by X-ray absorption spectroscopy (XAS). X-ray absorption near-edge structure (XANES) spectra of [AuCln(OH)4−n]− solutions have been calculated and the multiple-scattering spectral features have been attributed to Cl d-states, axial water molecules and the replacement of Cl− ligands by OH− ligands. A square–planar geometry for [AuCln(OH)4−n]− with two axial water molecules has been identified. Moreover, a spectral correlation between XANES features and the type of planar atoms has been identified. By extended X-ray absorption fine structure spectra (EXAFS), the planar Au bond distances in the solutions have also been determined, e.g., 2.28 Å for Au–Cl and 1.98 Å for Au–O, respectively. The same EXAFS analysis provides evidence that the peak at about 4.0 Å in solutions with the lowest OH−/Cl− molar ratio arises from collinear Cl–Au–Cl multiple-scattering contributions. For the first time, a complete detailed reconstruction of the hydration structure of an Au ion at different pH values has been achieved. 相似文献
Biogrouting is a new ground improvement method that has been studied in recent years. This method involves mainly the use of a microbially induced calcite precipitation process to bind soil particles to increase the strength or to fill in the pores of soil or joints of rock for seepage control. There are two major challenges in the use of biogrout for seepage control through rock joints. The first is how to inject the biogrout solutions, and the second is to understand the mechanisms for the formation of calcite under seepage flow. In this paper, a study on the injection of biogrout solution and the formation of precipitates along a circular 1D flow channel is presented. To minimize the influence of flow, a new one-phase injection method to inject bacterial solution and cementation agents simultaneously was adopted in this study. Factors affecting the formation and distribution of precipitates along the flow channel such as flow velocity, flow rate, and aperture of flow channel were investigated. The experimental results indicated that less calcite was precipitated at locations further away from the injection point due to depletion of the reactants’ concentrations along the flow path. Using the one-phase injection method, the bacterial activity had a major effect on the accumulation of the calcite on the inner surface of the flow channel. The total calcite precipitated on the surface of the flow channel increased slightly with increasing bacterial activity or flow rate. An equation to predict the distance travelled by the biosolution has been derived based on the testing results.
Acta Geotechnica - Few studies have focused on the influence of particle shape on the mechanical properties of cemented sand. To address this lack of information, this study investigated the... 相似文献
Metamorphic garnet commonly contains needle‐like rutile inclusions as well as equant rutile inclusions that surround quartz inclusions and range in size from submicrometer to nanometer. Although the origin of these equant rutile inclusions, that is, exsolution or non‐exsolution, has important implications for petrological and tectonic processes, the crystallographic characteristics of these inclusions have rarely been studied because of the small sizes and analytical difficulties involved. Here, we report the crystallographic characteristics pertinent to the genetic origin of minute equant rutile inclusions in cloudy, nearly spherically shaped garnet domains with Ti‐depleted compositions surrounding quartz inclusions in ultrahigh‐pressure garnet from several diamondiferous Erzgebirge quartzofeldspathic gneissic rock samples. TEM analyses show that the equant rutile crystals in cloudy garnet domains are partially bounded by the low‐energy {100}rt ± {110}rt ± {101}rt facets and have rather random crystallographic orientation relationships (CORs) with the garnet host, with preferential alignment of low‐energy lattice planes, for example, {100}rt//{112}grt, for some rutile crystals. Although the rather random CORs are unlikely to be attributed to solid‐state exsolution subjected to the stringent topotactic garnet lattice constraints, the characteristic subhedral {100}rt ± {110}rt ± {101}rt crystal forms of rutile can be rationalized by a metasomatic dissolution‐reprecipitation mechanism via a fluid phase. In this scenario, the quartz+fluid inclusions in garnet were first subjected to decompression microcracking during rock exhumation, followed by dissolution of Ti‐bearing garnet matrix at the crack tips or along the crack surfaces and subsequent reprecipitation of rutile, apatite, gahnite, akdalaite, and Ti‐depleted garnet. The rapid coalescence between rutile and garnet crystals in fluid or direct attachment of rutile crystals onto the dissolving crack surfaces would then yield the rather random CORs as reported here. These results, along with previous work on rutile needles, indicate rather diverse genesis of rutile inclusions in various crystal forms, thus shedding light on the controversial exsolution origin for other inclusion suite/microstructure in minerals. 相似文献
The Xilingol Complex comprises biotite gneisses and amphibolite interlayers with extensive migmatization. Four representative samples were documented and found to record either two or three metamorphic stages. Phase modelling using thermocalc suggests that the observed assemblages represent the final stages that underwent cooling from temperature peaks, and are consistent with a fluid‐absent solidus in P–T pseudosections. Their P–T conditions are further constrained to be 5–6 kbar/680–725°C and 4–5 kbar/650–680°C for two garnet‐bearing gneiss samples, 4–5 kbar/660–730°C for a cordierite‐bearing gneiss sample, and 4–5 kbar/680–710°C for an amphibolite sample based on mineral composition isopleths, involving measured Mg content in biotite, anorthite in plagioclase, grossular and pyrope in garnet and Ti content in amphibole. The peak temperature conditions recovered are 760–790°C or >760°C at 5–6 kbar based on the composition isopleths of plagioclase, biotite, garnet and especially the comparison of melt contents between the calculated and observed. A pre‐peak heating process with slight decompression can be suggested for some samples on the basis of the core–rim increase in the plagioclase anorthite, and the stability of ilmenite. Zircon U–Pb dating using the LA‐ICP‐MS method provides systemic constraints on the metamorphic ages of the Xilingol Complex to be 348–305 Ma, interpreted to represent the post‐peak cooling stages. Moreover, metagabbroic dykes that intruded into the Xilingol Complex yield 317 ± 3 Ma from magmatic zircon, and are considered to have played a significant role for heat advection triggering the high‐T and low‐P metamorphism. Thus, the clockwise P–T paths involving pre‐peak heating, peak and post‐peak cooling recovered for the Xilingol Complex are consistent with an extensional setting in the Carboniferous that developed on a previous orogen in response to addition of mantle‐derived materials probably together with upwelling of the asthenospheric mantle. 相似文献