Field comparison of passive sampling and biological approaches for measuring exposure to PAH and alkylphenols from offshore produced water discharges

Polycyclic aromatic hydrocarbons (PAH) and alkylphenols (AP) that are present in routine discharges of produced water (PW) from the offshore industry continue to cause concern. The suitability of biological methods and chemical based passive samplers to determine exposure to these compounds was tested by deploying them around an oil installation and at reference locations in the North Sea. PAH and AP were analysed either as parent compounds in passive samplers and mussel tissue or as metabolites in fish bile. Generally the pattern of exposure relative to proximity to the discharge was represented by mussels, SPMDs and fish for PAH. Fish and SPMDs showed good correlation for PAH accumulations, whereas some differences were apparent between mussels and SPMDs. POCIS was the only technique tested that could accurately measure the most abundant AP in PW. The advantages of biologically independent measures of exposure for inclusion in discharge monitoring studies are outlined.     

The craton: Its effect on the distribution of seismicity and stress in North America

The gross distribution of seismicity in North America suggests the interior platform and shield provinces are relatively stable and significantly affect the intraplate stress field. Focal mechanisms and in-situ stress measurements indicate the cratonic areas of North America must be relatively immobile with respect to the eastern and western portions of the continent. Simple kinematic models are presented to illustrate the importance of the craton in any attempt to explain the general pattern of intraplate stress and seismicity in North America.     

COCORP deep seismic reflection traverses of the U.S. Cordillera

Summary. COCORP seismic reflection traverses of the U.S. Cordillera at 40°N and 48.5°N latitude reveal some fundamental similarities as well as significant differences in reflection patterns. On both traverses, autochthonous crust beneath thin-skinned thrust belts of the eastern part of the Cordillera is unreflective; immediately to the west the Cordilleran interior is very reflective above a flat, prominent reflection Moho. Mesozoic accreted terranes in the western part of the orogen are underlain on both traverses by very complex reflection patterns, in constrast to more easily deciphered patterns beneath areas of Cenozoic accretion. The prominent reflection Moho beneath the orogenic interior on both transects probably evolved through a combination of magmatic and deformational processes during Cenozoic extension. The main differences between the two traverses lie in the reflection patterns of the middle and lower crust in the Cordilleran interior; these differences are probably related to the way Cenozoic extension was accommodated at depth. Laminated middle and lower crust above the reflection Moho in the western Basin and Range (40°N) may be related to magmatism, ductile pure shear and large-scale transposition during Cenozoic extension. By contrast, beneath the eastern Basin and Range (40°N), and the orogenic interior in the NW United States (48.5°N), Cenozoic extension was probably accommodated along dipping deformation zones throughout the crust.     

The Meteoritical Bulletin,No. 102

Meteoritical Bulletin 102 contains 3141 meteorites including 12 falls (Boumdeid (2003), Boumdeid (2011), Braunschweig, Chelyabinsk, Dongyang, Draveil, Heyetang, Indian Butte, Katol, Ladkee, Ouadangou, Xining), with 2611 ordinary chondrites, 264 HED achondrites, 124 carbonaceous chondrites, 30 ureilites, 20 Martian meteorites, 16 primitive achondrites, 16 Rumuruti chondrites, 15 mesosiderites, 12 iron meteorites, 10 lunar meteorites, 9 enstatite chondrites, 4 enstatite achondrites, 4 Pallasites, 4 ungrouped achondrites, and 2 angrites, and with 1708 from Antarctica, 956 from Africa, 294 from South America, 126 from Asia, 47 from North America, 6 from Europe (including Russia), and 4 from Oceania. Information about approved meteorites can be obtained from the Meteoritical Bulletin Database (MBD) available on line at http://www.lpi.usra.edu/meteor/ .     

Temporal and Spatial Variability of Mesozooplankton in a Shallow Sub-Tropical Bay: Influence of Top-Down Control

Quantifying the relationship between mesozooplankton and water quality parameters identifies the factors that structure the mesozooplankton community and can be used to generate hypotheses regarding the mechanisms that control the mesozooplankton population and potentially the trophic network. To investigate this relationship, mesozooplankton and water quality data were collected in Florida Bay from 1994 to 2004. Three key characteristics were found in the mesozooplankton community structure: (1) there are significant differences between the four sub-regions of Florida Bay; (2) there is a break in May of 1997 with significant differences before and after this date; and (3) there is a positive correlation between mesozooplankton abundance and salinity. The latter two characteristics are closely correlated with predator abundance, indicating the importance of top-down control. Hypersaline periods appear to provide a refuge from predators, allowing mesozooplankton to increase in abundance despite the increased physiological stress.     

Assessing spatial variability in soil characteristics with geographically weighted principal components analysis

Dimensionality reduction methods such as principal components analysis (PCA) provide a means of identifying trends in soil characteristics which may be represented by a wide range of variables. However, these characteristics may be highly spatially variable and so the results from PCA represent, in some sense, an “average” of locally distinct characteristics. One approach to account for these local differences is to introduce a geographical weighting scheme into the PCA process. In this paper, such an approach is assessed in the exploration of soil characteristics in the state of Pennsylvania, USA. Data from 878 georeferenced soil profiles which include different soil parameters (n = 12) were extracted from the National Soil Survey Center database. Where data are parts of compositions (e.g., percentages of sand, silt, and clay), analysis using raw data is not appropriate and such data were transformed using log ratios (specifically, balances). Single variables (i.e., those which are not parts of compositions) were logged. The first two principal components explain over 50% of the variance. The mapped values suggest marked spatial variation in soil characteristics, but it is not possible to assess which of these variables explain most variation in particular regions from the simple maps of raw variables. Geographically weighted PCA (GWPCA) provides additional information which is obscured by PCA, and it also provides a set of component scores and loadings at all data locations. The soil variable with the largest loading at most locations of Pennsylvania is the logged base saturation (BSln), and this supports the findings of the conventional PCA analysis. While BSln loads most highly in most of the eastern third, the middle and the south west of the state, the northwest is less spatially consistent in terms of the variables which explain most variation. For GWPC 1, the variable with the second largest loading at most locations (i.e., primarily the south and west) is CEC.B1 (the log ratio of Ca, Mg, and Na to K and EXACID), while CEC.B2 (the log ratio of Ca and Mg to Na), pHln (logged pH) and BSln dominate in other areas. The GWPCA results suggest that there is marked spatial variation in multivariate soil characteristics across Pennsylvania state and that results from standard PCA obscure this considerable variation.     

Storage of carbon in U.S. forests predicted from satellite data,ecosystem modeling,and inventory summaries

A plant and soil simulation model based on satellite observations of vegetation and climate data was used to estimate the potential carbon pools in standing wood biomass across all forest ecosystems of the conterminous United States up to the year 1997. These modeled estimates of vegetative carbon potential were compared to aggregated measurements of standing wood biomass from the U. S. Forest Service’s national Forest Inventory and Analysis (FIA) data set and the Carbon Online Estimator (COLE) to understand: 1) predominant geographic variations in tree growth rate and 2) local land cover and land use history including the time since the last stand-replacing disturbance (e.g., from wildfire or harvest). Results suggest that although wood appears to be accumulating at high rates in many areas of the U.S. (Northwest and Southeast), there are still extensive areas of relatively low biomass forest in the late 1990s according to FIA records. We attribute these low biomass accumulation levels to the high frequency of disturbances, which can be observed even in high production areas such as the Southeast due to frequent forest harvests. Ecosystem models like the one presented in this study have been coupled with satellite observations of land cover and green plant density to uniquely differentiate areas with a high potential for vegetative carbon storage at relatively fine spatial resolution.     

Quaternary eolian dunes in the Savannah River valley,Jasper County,South Carolina,USA

Sand hills in the Savannah River valley in Jasper County (South Carolina, USA) are interpreted as the remnants of parabolic eolian dunes composed of sand derived from the Savannah River and stabilized by vegetation under prevailing climate conditions. Optically stimulated luminescence ages reveal that most of the dunes were active ca. 40 to 19 ka ago, coincident with the last glacial maximum (LGM) through early deglaciation. Modern surface winds are not sufficient for sustained eolian sand transport. When the dunes were active, winds blew at velocities of at least 4 m/s from west to east, and some vegetation was present. The ratio of annual precipitation to potential evapotranspiration (P:PE) was less than the modern ratio of 1.23 and may have been < 0.30, caused by stronger winds (which would have resulted in greater evaporation) and/or reduced precipitation. The Savannah River dunes are part of a larger assemblage of eolian dunes that were active in the eastern United States during and immediately after the LGM, suggesting that eolian sediment behavior in this region has been controlled by regional forcing mechanisms during the Quaternary.     

Stable chlorine isotope evidence for non-marine chloride in Badenian evaporites, Carpathian mountain region

Routine trace-element geochemistry suggests that components in putative marine halite evaporites may be partly of nonmarine origin, but such interpretations are commonly ambiguous. Stable chlorine isotopes may provide a less-ambiguous marker of chloride origin where δ³⁷Cl departs from the range predicted for evaporite formation from seawater. Bedded halite with primary sedimentary textures preserves original δ³⁷Cl values. Measurable change in δ³⁷Cl can be generated by incongruent dissolution of halite, but only if less than half the original halite remains. Badenian (middle Miocene) halite from the Forecarpathian and from the East Slovakian and Transcarpathian basins has a δ³⁷Cl range of – 0.2 to 0.8‰. Two phenomena cannot be explained by simple evaporation of 0.0‰ seawater. At Wieliczka, the Shaft Salt has distinctive δ³⁷Cl values (– 0.2 to 0.0‰) relative to neighbouring salt beds (0.2 to  0.6‰), requiring a large, abrupt input of brine with negative δ³⁷Cl. Halite with high (0.6 – 0.8‰) δ³⁷Cl near the base of the East Slovakian and Transcarpathian evaporites requires a large input of chloride with positive δ³⁷Cl into the basins. Expulsion of basin brine with non-0‰δ³⁷Cl into the evaporite basins may account for the nonmarine chloride sources.