A Case Study on the Effects of Heterogeneous Soil Moisture on Mesoscale Boundary-Layer Structure in the Southern Great Plains, U.S.A. Part I: Simple Prognostic Model

The atmospheric boundary-layer (ABL) depth was observed by airborne lidar and balloon soundings during the Southern Great Plains 1997 field study (SGP97). This paper is Part I of a two-part case study examining the relationship of surface heterogeneity to observed ABL structure. Part I focuses on observations. During two days (12–13 July 1997) following rain, midday convective ABL depth varied by as much as 1.5 km across 400 km, even with moderate winds. Variability in ABL depth was driven primarily by the spatial variation in surface buoyancy flux as measured from short towers and aircraft within the SGP97 domain. Strong correlation was found between time-integrated buoyancy flux and airborne remotely sensed surface soil moisture for the two case-study days, but only a weak correlation was found between surface energy fluxes and vegetation greenness as measured by satellite. A simple prognostic one-dimensional ABL model was applied to test to what extent the soil moisture spatial heterogeneity explained the variation in north–south ABL depth across the SGP97 domain. The model was able to better predict mean ABL depth and variations on horizontal scales of approximately 100 km using observed soil moisture instead of constant soil moisture. Subsidence, advection, convergence/divergence and spatial variability of temperature inversion strength also contributed to ABL depth variations. In Part II, assimilation of high-resolution soil moisture into a three-dimensional mesoscale model (MM5) is discussed and shown to improve predictions of ABL structure. These results have implications for ABL models and the influence of soil moisture on mesoscale meteorology     

Seasonal to decadal forcing of high water level percentiles in the German Bight throughout the last century

For the purpose of coastal planning and management, especially under changing climatic conditions, enhanced knowledge about the evolution of extreme sea levels in the past, present, and future is required. This paper presents statistical analyses of high seasonal water level percentiles of 13 tide gauges in the German Bight, spanning over a period of up to 109 years throughout the twentieth and twenty-first centuries. Seasonal and annual high percentile time series of water levels were investigated in comparison to the mean sea level (MSL) for changes on seasonal, inter-annual, and decadal timescales. While throughout the first half of the twentieth century extreme water levels generally followed changes in MSL, during the second half of the century, linear extreme sea level trends exceeded those in MSL in the order of 9–64 cm per century. The largest, although insignificant, contribution to the magnitude of these trends occurs in the winter season (January to March), while smaller but, due to the generally lower atmospheric variability, significant changes are observed during spring (April to June). The observed multi-decadal trends are generally in good agreement with multi-decadal trends in the corresponding percentiles of local zonal surface winds. Only small parts of the trends remain unexplained. It is suggested that these remaining trends result from modifications in the local tidal regime. For the aspects of coastal planning, the findings clarify that in the German Bight, in addition to changes in MSL, potential changes in storminess and in the tidal regime significantly contribute to the development of extreme water levels. Since these factors have influenced the characteristic of extremes throughout the recent past, they also have to be taken into account when estimating design water levels for, e.g., dikes (in a warming climate) under changing greenhouse gas emissions.     

The system H2O-NaCl. Part I: Correlation formulae for phase relations in temperature-pressure-composition space from 0 to 1000 °C, 0 to 5000 bar, and 0 to 1 XNaCl

Realistic simulations of fluid flow in geologic systems have severely been hampered by the lack of a consistent formulation for fluid properties for binary salt-water fluids over the temperature-pressure-composition ranges encountered in the Earth’s crust. As the first of two companion studies, a set of correlations describing the phase stability relations in the system H₂O-NaCl is developed. Pure water is described by the IAPS-84 equation of state. New correlations comprise the vapor pressure of halite and molten NaCl, the NaCl melting curve, the composition of halite-saturated liquid and vapor, the pressure of vapor + liquid + halite coexistence, the temperature-pressure and temperature-composition relations for the critical curve, and the compositions of liquid and vapor on the vapor + liquid coexistence surface. The correlations yield accurate values for temperatures from 0 to 1000 °C, pressures from 0 to 5000 bar, and compositions from 0 to 1 X_NaCl (mole fraction of NaCl). To facilitate their use in fluid flow simulations, the correlations are entirely formulated as functions of temperature, pressure and composition.     

Carbon,sulfur, oxygen and strontium isotope records,organic geochemistry and biostratigraphy across the Permian/Triassic boundary in Abadeh,Iran

Pelagic deposits at Abadeh represent a complete biostratigraphic record across the Permian/Triassic boundary (PTB). The presumed water depth during deposition of these sediments was between 60 and 90 m. Similar to other Permian/Triassic boundary sections, the succession at Abadeh is characterised by a negative carbon isotope shift of approximately 4. The values start to decrease in the lower C. changxingensis - C. deflecta s.l. Zone, reach –0.12 (V-PDB) in the uppermost Permian just below the PTB, remain low to the early I. isarcica Zone (–0.32) and increase subsequently in the upper I. isarcica Zone. For the time interval of the PTB negative carbon isotope excursion, between the C. iranica and the I. isarcica Zones, no correlation exists between the ¹³C_carb and the ¹⁸O_carb. The above observations argue against the conclusion of Heydari et al. (2001) that the carbon isotope event at the P/T transition is an alteration artefact and not a global signal. The decrease in ¹³C_carb is accompanied by a ~5 (and potentially up to 10) increase in ³⁴S_SSS. Together, these features are thought to reflect a complex global event, notably the development of widespread anoxic oceans with anoxic bottom layers rising onto the shelves. For the carbon isotope drop, other factors, such as the collapse of ocean primary productivity may also have played a role. The ⁸⁷Sr/⁸⁶Sr ratios of Dzhulfian seawater show only a minor increase from 0.70705 to 0.70710, reaching 0.70720 in the Dorashamian. The increase becomes steeper in the Early Triassic reaching 0.70754 in the N. dieneri Zone. The rise of the strontium isotope values is thought to be related to enhanced continental weathering under humid climatic conditions in the uppermost Permian (C. meishanensis - H. praeparvus Zone) and the lack of a dense land vegetation in the Early Triassic, prior to the Spathian (Upper Olenekian).     

Alteration and chemical U-Th-total Pb dating of heterogeneous high-uranium zircon from a pegmatite from the Aduiskii massif,middle Urals,Russia

Mineralogy and Petrology - The U-Th-Pb isotope system in the accessory mineral zircon may be disturbed, as for instance by the secondary loss of radiogenic lead. The recognition of such alteration...     

Detecting thermal anomalies within the Molasse Basin, southern Germany

The groundwater flow regime at great depth within the Molasse Basin (SW Germany) was studied. Data relevant for a flow model at 600–1,600 m depth are sparse in the western part of the basin. However, temperature measurements are available covering much of the area at a wide range of depths. Therefore, a thermal 3D steady-state model was set up with the aim of comparing modeled with observed subsurface temperatures. Stratigraphic information from many boreholes was also available, but only a few values of rock thermal conductivity and heat-production rate could be obtained. Some strong thermal residual anomalies were identified with respect to the purely conductive model, especially along fault zones, and within stratigraphic layers with high hydraulic conductivity. These anomalies can be explained by various advective heat-transport mechanisms, yet most explanations can be eliminated. The most plausible constellation explaining the major positive thermal anomalies of 10 Kelvin and more is a fault zone of E–W strike, intersected by an aquifer with flow parallel to the fault zone. This concept was investigated by using a simplified type model. In spite of some shortcomings, the method presented here can be used to identify temperature anomalies, and to identify possible explanations.     

MODIS Derived Equilibrium Line Altitude Estimates for Purogangri Ice Cap,Tibetan Plateau,and their Relation to Climatic Predictors (2001–2012)

The variation of the equilibrium line altitude can be used as an indicator for glacier mass balance variability. Snow lines at the end of the ablation period are suitable proxies for the annual equilibrium line altitude on glaciers. We investigate snow lines at Purogangri ice cap on the central Plateau in order to study the interannual variability of glacier mass balance. Datasets of the daily Moderate Resolution Imaging Spectroradiometer snow product MOD10A1 were used to infer transient snow line variability during 2001–2012 and to derive regional‐scale, annual equilibrium line altitude. The Moderate Resolution Imaging Spectroradiometer snow albedo embedded within the snow product was compared with high‐resolution Landsat imagery. An albedo threshold was established to differentiate between ice and snow and the 13th percentile of the altitudes of snow‐covered pixels was chosen to represent the snow line altitude. The second maximum of the snow line altitudes in the ablation period was taken as a proxy for the annual equilibrium line altitude. A linear correlation analysis was carried out (1) between interannual variability of the equilibrium line altitude at Purogangri ice cap and various climate elements derived from the High Asia Reanalysis, and (2) between interannual variability of the equilibrium line altitude and the circulation indices North Atlantic Oscillation and Indian Summer Monsoon. Results suggest that air temperature and meridional wind speed above ground in July, as well as the lower tropospheric zonal wind in June and August play a crucial role in the development of the annual equilibrium line altitude.     

Origin and Petrogenetic Implications of Spessartine Garnet in Highly‐Fractionated Granite from the Central Eastern Desert of Egypt

A highly-fractionated garnet-bearing muscovite granite represents the marginal granitic facies of the Abu-Diab multiphase pluton in the Central Eastern Desert of Egypt. New electron microprobe analyses(EMPA) and laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) data from garnets are reported, in order to constrain their origin and genesis. Garnet in the Abu-Diab host granite is euhedral to subhedral, generally homogeneous and, in rare cases, it shows weak zonation. The garne...     

岩溶区和碎屑岩区林地和农田土壤氮矿化过程对比研究

通过15N标记法和MCMC氮素转化模型,研究了岩溶区(石灰性土壤)和碎屑岩区(红壤)林地和农田土壤易分解有机氮矿化(M易)、难分解有机氮矿化(M难)和总有机氮矿化(M总)速率.结果发现,土壤矿化速率受土壤类型和土地利用方式的显著影响.林地石灰性土壤M总 (3.71 mg N/kg)显著低于林地红壤(5.57mg N/kg),石灰性土壤MNab(1.81 mg N/kg)与MNrec(1.90 mg N/kg)相近,而红壤M易 (4.60 mg N/kg)显著高于M难 (0.96 mg N/kg).林地变为农田后,石灰性土壤M总显著提高,而红壤显著降低.与林地相比,岩溶区农田土壤M易提高了72.5%,而M难下降了33.7%.碎屑岩区农田土壤M易和M难分别降低至2.47和0.46 mg N/kg.岩溶区土壤CaO和MgO含量与M易呈显著负相关,而与M难呈显著正相关,表明岩溶区土壤钙镁含量是影响氮矿化速率的重要因素.