Comprehension and hydrogeological conceptualization of aquifer in arid and semi-arid regions using integrated hydrogeological information system: case of the deep aquifer of Zéramdine-Béni Hassen (east-central Tunisia)

In arid and semi-arid regions, the groundwater overexploitation caused drawdown in piezometric levels and a degradation of chemical water quality. That is why the groundwater monitoring needs a good comprehension of the hydrogeological aquifer properties. This is specially the case of Zéramdine–Béni Hassen deep aquifer (east-central Tunisia). Seismic profiles interpretation highlights the existence of the Zéramdine fault corridor, the Boumerdès anticline, the Moknine and Mahdia grabens that represent lateral boundaries for the study aquifer. The outcrop of the aquifer is located in the Zéramdine, Béni Hassen and Ain Ben Jannet regions, where two lithostratigraphic sections were realized. The piezometric study shows that the principal groundwater flow is from west to east. A secondary flow is from NW to SE. The hydrochemical study of 22 sample shows that the aquifer is characterized by freshwater, dominated by Na–Ca–Cl–SO4 facies. The salinity increase is from the west to the east, which coincides with the principal water flow direction. The integration of all results deduced from the hydrogeophysic, hydrodynamic and hydrochemical studies is developed to investigate hydrological processes of Zéramdine–Béni Hassen aquifer and consequently to propose a conceptual model, which will help to propose a rescue plan for the studied aquifer and to implement a spatial hydrogeological database using the global information system and then to characterize the complex aquifer system.     

A framework for dealing with uncertainty due to model structure error

Although uncertainty about structures of environmental models (conceptual uncertainty) is often acknowledged to be the main source of uncertainty in model predictions, it is rarely considered in environmental modelling. Rather, formal uncertainty analyses have traditionally focused on model parameters and input data as the principal source of uncertainty in model predictions. The traditional approach to model uncertainty analysis, which considers only a single conceptual model, may fail to adequately sample the relevant space of plausible conceptual models. As such, it is prone to modelling bias and underestimation of predictive uncertainty.     

Combining a rainfall–runoff model and a regionalization approach for flood and water resource assessment in the western Po Valley,Italy

ABSTRACT

Selecting the best structure and parameterization of rainfall–runoff models is not straightforward and depends on a broad number of factors. In this study, the “Modello Idrologico Semi-Distribuito in continuo” (MISDc) was tested on 63 mountainous catchments in the western Po Valley (Italy) and the optimal model parameters were regionalized using different strategies. The model performance was evaluated through several indexes analysing hydrological regime, high-flow condition and flow–duration curve (FDC). In general, MISDc provides a good fit behaviour with a Kling-Gupta Efficiency index greater than 0.5 for 100% and 84% of cases for calibration and validation, respectively. Concerning the regionalization, spatial proximity approach is the most accurate solution obtaining satisfactory performance. Lastly, the predicted FDCs showed an excellent similarity with the observed ones. Results encourage to apply MISDc over the study area for flood forecasting and for assessing water resources availability thanks to the modest computational efforts and data requirements.     

ASSESSMENT OF A SIMPLE METHOD FOR THE DETERMINATION OF NB AND TA AT THE SUB-μG/G LEVEL IN SILICATE ROCKS BY ICP-MS

We report Nb and Ta data for 15 international silicate rock standards, obtained by inductively coupled plasma-mass spectrometry (ICP-MS) measurement following decomposition with HF-HNOs-HCI.⁹⁵ Moand¹⁸⁵Re were used as internal standards, and calibration lines were constructed with artificial solutions. Typical relative standard deviations are better than 10% above 0.2 μg/g, and detection limits for Nb and Ta are 40 and 0.8 ng/g, respectively. The results are generally in good agreement with published data. Moreover, this study points out the Nb-Ta heterogeneity of some standard reference materials on the 100 mg scale.     

Trace element study of high- and low-refractive index Muong Nong-type tektites from Indochina

Abstract— Previous work indicates that Muong Nong-type tektites from Indochina with low refractive indices and high silica contents contain relict mineral grains while those with high refractive indices and low silica contents do not. Instrumental Neutron Activation Analysis (INAA) was used to determine selected trace element concentrations for four Muong Nong-type tektites with high refractive indices and no relict mineral inclusions and one with low refractive index and relict inclusions, to determine if there are any systematic differences in trace element compositions between the two groups. The data also were compared with published trace element data for sixteen Muong Nong-type tektites which have low refractive indices and, therefore, should contain relict inclusions. Except for Ta which had lower concentrations in the high refractive index group, there is no consistent difference in trace element compositions between the two groups. We interpret these results to indicate a single, slightly heterogeneous source for the Muong Nong-type tektites, rather than different source regions.     

Conceptual modelling to assess the influence of hydro-climatic variability on runoff processes in data scarce semi-arid Andean catchments

Using hydro-meteorological time series of 50 years and in situ measurements, the dominant runoff processes in perennial Andean headwater catchments in Chile were determined using the hydrological model HBV light. First, cluster analysis was used to identify dry, wet and intermediate years. From these, sub-periods were identified with contrasting seasonal climatic influences on streamflow. By calibrating the model across different periods, impacts on model performance, parameter sensitivity and identifiability were investigated, providing insights into differences in hydrological processes. The modelling approach suggested that, independently of a dry or wet period of calibration, the streamflow response is mostly consistent with flux from groundwater storage, while only a small fraction comes from direct routing of snowmelt. The variation of model parameters, such as the groundwater rate coefficient, was found to be consistent with differing recharge in wet and dry years. The resulting snowmelt–groundwater model is a realistic hypothesis of the hydrological operation of such complex, data scarce and semi-arid Andean catchments. This model may also be a useful tool for predictions of seasonal water availability and a basis for further field studies.     

> 25 MeV Proton Events Observed by the High Energy Telescopes on the STEREO A and B Spacecraft and/or at Earth During the First ∼ Seven Years of the STEREO Mission

Using observations from the High Energy Telescopes (HETs) on the STEREO A and B spacecraft and similar observations from near-Earth spacecraft, we summarize the properties of more than 200 individual >?25 MeV solar proton events, some detected by multiple spacecraft, that occurred from the beginning of the STEREO mission in October 2006 to December 2013, and provide a catalog of these events and their solar sources and associations. Longitudinal dependencies of the electron and proton peak intensities and delays to onset and peak intensity relative to the solar event have been examined for 25 three-spacecraft particle events. Expressed as Gaussians, peak intensities fall off with longitude with σ=47±14^° for 0.7?–?4 MeV electrons, and σ=43±13^° for 14?–?24 MeV protons. Several particle events are discussed in more detail, including one on 3 November 2011, in which ～?25 MeV protons filled the inner heliosphere within 90 minutes of the solar event, and another on 7 March 2012, in which we demonstrate that the first of two coronal mass ejections that erupted from an active region within ～?1 hour was associated with particle acceleration. Comparing the current Solar Cycle 24 with the previous cycle, the first >?25 MeV proton event was detected at Earth in the current solar cycle around one year after smoothed sunspot minimum, compared with a delay of only two months in Cycle 23. Otherwise, solar energetic particle event occurrence rates were reasonably similar during the rising phases of Cycles 23 and 24. However, the rate declined in 2013, reflecting the decline in sunspot number since the peak in the northern-hemisphere sunspot number in November 2011. Observations in late 2013 suggest that the rate may be rising again in association with an increase in the southern sunspot number.     

Landslide deposits as stratigraphical markers for a sequence‐based glacial stratigraphy: a case study of a Younger Dryas system in the Eastern Alps

Detailed ¹⁰Be and ¹⁴C dating and supporting pollen analysis of Alpine Lateglacial glacial and landslide deposits in the Hohen Tauern Mountains (Austria) constrain a sequence‐based stratigraphy comprising a major landslide (13.0±1.1 ka) overlain by till and termino‐lateral moraines of an advancing (12.6±1.0 ka) and retreating (11.3±0.8 ka) glacier in turn overlain by a minor landslide (10.8±1.1 ka). These results define glacier activity during the Younger Dryas age Egesen stadial bracketed by landslide activities during the Bølling‐Allerød interstadial and the Preboreal. In contrast to recent studies on Holocene glaciation in the Alps, no traces of any Holocene glacier advance bigger than during the Little Ice Age are documented. Furthermore, this study demonstrates the advantages of using an allostratigraphical approach based on unconformity‐bounded sedimentary units as a tool for glacial stratigraphy in formerly glaciated mountain regions, rather than a stratigraphy based on either isolated morphological features or lithostratigraphical characteristics.     

Diagenetic Alteration of Magnetic Signals by Anaerobic Oxidation of Methane Related to a Change in Sedimentation Rate

Geochemical and rock magnetic investigations of sediments from three sites on the continental margin off Argentina and Uruguay were carried out to study diagenetic alteration of iron minerals driven by anaerobic oxidation of methane (AOM). The western Argentine Basin represents a suitable sedimentary environment to study nonsteady-state processes because it is characterized by highly dynamic depositional conditions. Mineralogic and bulk solid phase data document that the sediment mainly consists of terrigenous material with high contents of iron minerals. As a typical feature of these deposits, distinct minima in magnetic susceptibility (κ) are observed. Pore water data reveal that these minima in susceptibility coincide with the current depth of the sulfate/methane transition (SMT) where HS⁻ is generated by the process of AOM. The released HS⁻ reacts with the abundant iron (oxyhydr)oxides resulting in the precipitation of iron sulfides accompanied by a nearly complete loss of magnetic susceptibility. Modeling of geochemical data suggest that the magnetic record in this area is highly influenced by a drastic change in mean sedimentation rate (SR) which occurred during the Pleistocene/Holocene transition. We assume that the strong decrease in mean SR encountered during this glacial/interglacial transition induced a fixation of the SMT at a specific depth. The stagnation has obviously enhanced diagenetic dissolution of iron (oxyhydr)oxides within a distinct sediment interval. This assumption was further substantiated by numerical modeling in which the mean SR was decreased from 100 cm kyr⁻¹ during glacial times to 5 cm kyr⁻¹ in the Holocene and the methane flux from below was fixed to a constant value. To obtain the observed geochemical and magnetic patterns, the SMT must remain at a fixed position for ∼9000 yrs. This calculated value closely correlates to the timing of the Pleistocene/Holocene transition. The results of the model show additionally that a constant high mean SR would cause a concave-up profile of pore water sulfate under steady state conditions.