Geomechanical model for the post-Variscan evolution of the Permocarboniferous–Mesozoic basins in Northeast Germany

The Permocarboniferous basins in Northeast Germany formed on the heterogeneous and eroded parts of the Variscan orogene and its deformed northern foreland. Transtensional tectonic movements and thermal re-equilibration lead to medium-scale crustal fragmentation, fast subsidence rates and regional emplacement of large amounts of mostly acidic volcanics. The later basin formation and differentiation was triggered by reversals of the large-scale stress field and reactivation of prominent zones of weakness like the Elbe Fault System and the Rhenohercynian/Saxothuringian boundary that separate different Variscan basement domains in the area. The geomechanical behaviour of the latter plays an important role for the geodynamic evolution of the medium to large-scale structural units, which we can observe today in three dimensions on structural maps, geophysical recordings and digital models. This study concentrates on an area that comprises the southern Northeast German Basin, the Saale Basin, the Flechtingen High, the Harz Mountains High and the Subhercynian Basin. The presented data include re-evaluations of special geological and structural maps, the most recent interpretation of the DEKORP BASIN 9601 seismic profile and observations of exposed rock sections in Northeast Germany. On the basis of different structural inventories and different basement properties, we distinguish two structural units to the south and one structural unit to the north of the Elbe Fault System. For each unit, we propose a geomechanical model of basin formation and basin inversion, and show that the Rhenohercynian Fold and Thrust Belt domain is deformed in a thin-skinned manner, while the Mid-German Crystalline Rise Domain, which is the western part of the Saxothuringian Zone, rather shows a thick-skinned deformation pattern. The geomechanical model for the unit north to the Elbe Fault System takes account to the fact that the base of the Zechstein beneath the present Northeast German basin shows hardly any evidence for brittle deformation, which indicates a relative stable basement. Our geomechanical model suggests that the Permocarboniferous deposits may have contributed to the structural stiffness by covering small to medium scale structures of the upper parts of the brittle basement. It is further suggested that the pre-Zechstein successions underneath the present Northeast German basin were possibly strengthening during the Cretaceous basin inversion, which resulted in stress transfer to the long-lived master faults, as indicated for example by the shape of the salt domes in the vicinity of the latter faults. Contrary to this, post-Zechstein successions deformed in a different and rather complex way that was strongly biased by intensive salt tectonic movements.     

Cation distribution and structure modelling of spinel solid solutions

 This paper presents an improved generalisation of cation distribution determination based on an accurate fit of all crystal-chemical parameters. Cations are assigned to the tetrahedral and octahedral sites of the structure according to their scattering power and a set of bond distances optimised for spinel structure. A database of 295 spinels was prepared from the literature and unpublished data. Selected compositions include the following cations: Mg²⁺, Al³⁺, Si⁴⁺, Ti⁴⁺, V³⁺, Cr³⁺, Mn²⁺, Mn³⁺, Fe²⁺, Fe³⁺, Co²⁺, Ni²⁺, Zn²⁺ and vacancies. Bond distance optimisation reveals a definite lengthening in tetrahedral distance when large amounts of Fe³⁺ or Ni²⁺ are present in the octahedral site. This means that these cations modify the octahedral angle and hence the shared octahedral edge, causing an increase in the tetrahedral distance with respect to the size of the cations entering it. Some applications to published data are discussed, showing the capacity and limitations of the method for calculating cation distribution, and for identifying inconsistencies and inaccuracies in experimental data. Received: 19 February 2001 / Accepted: 1 June 2001     

Volcanic and tectonic controls of lacustrine and alluvial sedimentation in the Stephanian coal-bearing sequence of the Malpàs-Sort Basin, Catalonian Pyrenees

The infill of a small Variscan basin shows a complex succession of lacustrine and alluvial sediments whose pattern of distribution through time appears to have changed in response to contemporaneous volcanism. Following initial deposition of pyroclastic breccias and extrusion of lavas, small lakes were established on the floor of the basin. Their infills were probably locally controlled by relief on top of the lavas but the pattern was disrupted by phases of mass movement from the basin margin which emplaced debris flows and a sedimentary mélange containing large blocks of limestone and led to extensive soft-sediment deformation. This complex sequence of events culminated in the emplacement of a widespread ash-flow bed. An alluvial plain, established during a period of rather uniform subsidence, was rapidly drowned to give an extensive lake whose progradational infill led to re-establishment of an alluvial plain. The deposition of a widespread airfall tuff coincided with the onset of differential subsidence during which major channel sandstones were stacked in association with poorly drained palaeosols in the east of the area, whilst a mudstone-dominated sequence characterized by well-drained palaeosols developed in the west. A return to more uniform subsidence appears to have coincided with the cessation of volcanic activity.     

The marine Devonian stratigraphy of Great Britain

Exposed marine Devonian rocks of Great Britain are in South-West England where successions together span most of the Devonian Period. The Geological Conservation Review (GCR) sites of the volume are located in Cornwall and Devon, the latter providing the historic stratotype of the Devonian System. Site stratigraphies are linked to basins of three sub-provinces. Those represent different, albeit largely penecontemporaneous, tectonosedimentary regimes of the differing settings of the Rhenohercynian Zone. The sites and their selection criteria based on their international and national importance in understanding Devonian geological history are listed. A History of Research section provides a detailed review of work on the Devonian rocks of the province from 1839, when Sedgwick and Murchison proposed establishment of the system, to the present and the recent recognition of the relationships between its numerous successions and their dependence upon, extensional and contractional tectonic structures and processes. Other sections detail the Stratigraphical Framework of Devonian strata; Devonian Chronostratigraphy, tracing development and refinement of the Series’ and Stages of the system; and Biostratigraphy, in relation to the faunal groups of the province and their relevance to biozone establishment and environmental discrimination. The chapter concludes with an explanation of current understanding of the evolution of the plate settings of the province that determined the nature of the marine Devonian and its stratigraphy in South-West England.     

A diagnostic model using ashfall data to determine eruption characteristic and atmospheric conditions during a major volcanic event

A model is developed for estimating location of a volcano relative to sample points in an associated ashfall, cloud height during eruption, and mean wind velocity during ash deposition. The ash deposit must cover a large area and have an elongate axis. The model appears to be applicable both to recent and to unobserved ashfalls in the past, provided adequate and representative ash samples are available. The opportunity to test the diagnostic model on volcanic ashfalls is limited by sparsity of the necessary input data. From more than 20 ashfalls described in the literature, the 1947 Hekla (Iceland) eruption is the only one which includes suitable particle size analyses taken from samples related to a well-defined axis. The application of the model to the Hekla ashfall is discussed.     

Uptake of radioactivity by marine sediments and implications for monitoring metal pollutants

The value of studying artificially-produced radionuclides in the marine environment is discussed in the wider context of monitoring sediments for other metal pollutants. Differences in the dispersion of selected radionuclides discharged from the same known source are used to illustrate the sort of changes in phase or speciation which must occur with other metal pollutants, but which cannot be demonstrated directly because of the multiplicity of sources. Various chemical and physical procedures are discussed which can be applied to a study of heavy metal associations with marine sediments, as are questions such as the existence, or otherwise, of mechanisms for the slow release of adsorbed material from the buried sediment back into the water column. Suggestions are made as to how radionuclide studies may be helpful in answering questions such as these, which are considered to be vital for the meaningful interpretation of sediment analyses.