Oxygen and carbon isotopic systematics of aragonite speleothems and water in Furong Cave, Chongqing, China

To understand oxygen and carbon stable isotopic characteristics of aragonite stalagmites and evaluate their applicability to paleoclimate, the isotopic compositions of active and fossil aragonite speleothems and water samples from an in situ multi-year (October 2005-July 2010) monitoring program in Furong Cave located in Chongqing of China have been examined. The observations during October 2005-June 2007 show that the meteoric water is well mixed in the overlying 300-500-m bedrock aquifer, reflected by relatively constant δ¹⁸O, ±0.11-0.14‰ (1σ), of drip waters in the cave, which represents the annual status of rainfall water. Active cave aragonite speleothems are at oxygen isotopic equilibrium with drip water and their δ¹⁸O values capture the surface-water oxygen isotopic signal. Aragonite-to-calcite transformation since the last glaciation is not noticeable in Furong stalagmites. Our multi-year field experiment approves that aragonite stalagmite δ¹⁸O records in this cave are suitable for paleoclimate reconstruction. With high U, 0.5-7.2 ppm, and low Th, 20-1270 ppt, the Furong aragonite stalagmites provide very precise chronology (as good as ±20s yrs (2σ)) of the climatic variations since the last deglaciation. The synchroneity of Chinese stalagmite δ¹⁸O records at the transition into the Bølling-Allerød (t-BA) and the Younger Dryas from Furong, Hulu and Dongge Caves supports the fidelity of the reconstructed East Asian monsoon evolution. However, the Furong record shows that the cold Older Dryas (OD) occurred at 14.0 thousand years ago, agreeing with Greenland ice core δ¹⁸O records but ∼200 yrs younger than that in the Hulu record. The OD age discrepancy between Chinese caves can be attributable to different regionally climatic/environmental conditions or chronological uncertainty of stalagmite proxy records, which is limited by changes in growth rate and subsampling intervals in absolute dating. Seasonal dissolved inorganic carbon δ¹³C variations of 2-3‰ in the drip water and 5-7‰ in the pool and spring waters are likely attributed to variable degrees of CO₂ degassing in winter and summer. The variable δ¹³C values of active deposits from −11‰ to 0‰ could be caused by kinetically mediated CO₂ degassing processes. The complicated nature of pre-deposition kinetic isotopic fractionation processes for carbon isotopes in speleothems at Furong Cave require further study before they can be interpreted in a paleoclimatic or paleoenvironmental context.     

Cold seeps in Monterey Bay, California: Geochemistry of pore waters and relationship to benthic foraminiferal calcite

An extensive geochemical and biogeochemical examination of CH₄ seeps in the Clam Flats area of Monterey Bay provides insight into the character of relationships between seep geochemistry and benthic foraminiferal geochemistry. The area is characterized by sulfide-rich fluids. Sulfide increases are associated with large increases in alkalinity, as well as small decreases in dissolved Ca and Mg. In addition, only small increases in NH₄ are observed, but values of δ¹³C of dissolved inorganic C are as low as −60‰ at shallow depths (<3 cm). These observations indicate that all these processes are related to the bacterial oxidation of CH₄, which is transported upward by slow seepage of pore fluids. The geochemistry of the pore fluids should be relevant to the geochemistry of the carbonate tests of living and dead foraminifera. However, a profound disequilibrium of approximately an order of magnitude occurs between the δ¹³C values of stained (cytoplasm-containing) foraminiferal carbonate and the C isotope values of ambient pore water dissolved inorganic C. Reasons are unclear for this isotopic disequilibrium, but have important implications for interpretations of foraminiferal carbonate as a paleoenvironmental proxy. Much fine scale work is needed to fully understand the relationships between the biogeochemistry of benthic foraminifera and the geochemistry of the pore waters where they live.     

Sulfide oxidation as a process for the formation of copper-rich magmatic sulfides

Typical magmatic sulfides are dominated by pyrrhotite and pentlandite with minor chalcopyrite, and the bulk atomic Cu/Fe ratio of these sulfides is typically less than unity. However, there are rare magmatic sulfide occurrences that are dominated by Cu-rich sulfides (e.g., bornite, digenite, and chalcopyrite, sometimes coexisting with metallic Cu) with atomic Cu/Fe as high as 5. Typically, these types of sulfide assemblages occur in the upper parts of moderately to highly fractionated layered mafic–ultramafic intrusions, a well-known example being the Pd/Au reef in the Upper Middle Zone of the Skaergaard intrusion. Processes proposed to explain why these sulfides are so unusually rich in Cu include fractional crystallization of Fe/(Ni) monosulfide and infiltration of postmagmatic Cu-rich fluids. In this contribution, we explore and experimentally evaluate a third possibility: that Cu-rich magmatic sulfides may be the result of magmatic oxidation. FeS-dominated Ni/Cu-bearing sulfides were equilibrated at variable oxygen fugacities in both open and closed system. Our results show that the Cu/Fe ratio of the sulfide melt increases as a function of oxygen fugacity due to the preferential conversion of FeS into FeO and FeO_1.5, and the resistance of Cu₂S to being converted into an oxide component even at oxygen fugacities characteristic of the sulfide/sulfate transition (above FMQ?+?1). This phenomenon will lead to an increase in the metal/S ratio of a sulfide liquid and will also depress its liquidus temperature. As such, any modeling of the sulfide liquid line of descent in magmatic sulfide complexes needs to address this issue.     

Stability and equation of state of post-aragonite BaCO3

At ambient conditions, witherite is the stable form of BaCO₃ and has the aragonite structure with space group Pmcn. Above ~10 GPa, BaCO₃ adopts a post-aragonite structure with space group Pmmn. High-pressure and high-temperature synchrotron X-ray diffraction experiments were used to study the stability and equation of state of post-aragonite BaCO₃, which remained stable to the highest experimental P–T conditions of 150 GPa and 2,000 K. We obtained a bulk modulus K ₀ = 88(2) GPa with $K'$  = 4.8(3) and V ₀ = 128.1(5) ų using a third-order Birch-Murnaghan fit to the 300 K experimental data. We also carried out density functional theory (DFT) calculations of enthalpy (H) of two structures of BaCO₃ relative to the enthalpy of the post-aragonite phase. In agreement with previous studies and the current experiments, the calculations show aragonite to post-aragonite phase transitions at ~8 GPa. We also tested a potential high-pressure post–post-aragonite structure (space group C222 ₁ ) featuring four-fold coordination of oxygen around carbon. In agreement with previous DFT studies, ΔH between the C222 ₁ structure and post-aragonite (Pmmn) decreases with pressure, but the Pmmn structure remains energetically favorable to pressures greater than 200 GPa. We conclude that post–post-aragonite phase transformations of carbonates do not follow systematic trends observed for post-aragonite transitions governed solely by the ionic radii of their metal cations.     

An enhanced MEMS-INS/GNSS integrated system with fault detection and exclusion capability for land vehicle navigation in urban areas

We describe an enhanced quality control algorithm for the MEMS-INS/GNSS integrated navigation system. It aims to maintain the system’s reliability and availability during global navigation satellite system (GNSS) partial and complete data loss and disturbance, and hence to improve the system’s performance in urban environments with signal obstructions, tunnels, bridges, and signal reflections. To reduce the inertial navigation system (INS) error during GNSS outages, the stochastic model of the integration Kalman filter (KF) is informed by Allan variance analysis and the application of a non-holonomic constraint. A KF with a fault detection and exclusion capability is applied in the loosely and tightly coupled integration modes to reduce the adverse influence of abnormal GNSS data. In order to evaluate the performance of the proposed navigation system, road tests have been conducted in an urban area and the system’s reliability and integrity is discussed. The results demonstrate the effectiveness of different algorithms for reducing the growth of INS error.     

Rethinking the regularity in mobility patterns of personal vehicle drivers: A multi-city comparison using a feature engineering approach

Large-scale trajectory data offer a finer lens into the regularity in individual mobility choices. Previous studies have exerted efforts to measure the regularity in people's location visiting patterns. However, the complexity of travel behavior at different spatial and temporal scales has not been adequately considered. To capture regularity in a more comprehensive manner, we construct human mobility profiles with interpretable features at three levels, that is, location, motif, and route, on personal vehicle drivers. A feature engineering approach is designed to analyze the extent to which individuals exhibit multi-level regularity. The analysis pipeline includes feature selection, user segmentation and profiling, and feature importance evaluation. Our empirical study analyzed over 4 million trips of 3743 personal vehicle drivers collected over a month in six metropolitan areas in the United States. The weak correlations between features confirm the validity of quantifying regularity from different aspects. We discovered five clusters of drivers (i.e., gig drivers, homebodies, movers, typical drivers, and work-focused commuters) that differ in their regularity to commute to the workplace and the inclination to participate in non-work activities. A similar driver segmentation and profiling pattern is found in all of the studied metro areas. The minor differences are interpreted from the distribution of mobility features and urban features. The proposed method using multi-level feature engineering provides a generic framework to study regularity and can be readily adapted to other mobility data sources by customizing the features. The improved understanding of mobility patterns within the built environment is valuable for innovating urban transportation solutions.     

Exhibitions

In this paper we propose the use of ‘Encountering’ a location-based game (LBG) based on the Wherigo platform to facilitate interdisciplinary student learning about places on field courses. Deploying a mobile, digital map-based platform addresses significant challenges – such as the sacrifice of context specificity and methodological applicability and depth. It also runs the danger of ‘gamifying’ the fieldwork, blinding the participant to their own agency and emergent encounters. Interactive and layered digital map interfaces have affordances that can potentially overcome such challenges. We claim that one such affordance is the ability to play through the map. In other words, maps – and digital maps in particular – offer the possibility of decoupling results-orientated actions from free-form serendipitous engagement with the field. Our argument is two-fold. First, that LBG toolsets such as Wherigo can provide a ‘common ground’ for students engaging in place-based interdisciplinary research, by providing a material, cartographic basis for playful investigation. Second, that they can facilitate the production of ‘spaces of epistemological failure’, allowing students to challenge taken-for-granted conceptual and methodological axioms within and across disciplines.     

Introducing HTDP 3.1 to transform coordinates across time and spatial reference frames

The National Geodetic Survey, an office within the National Oceanic and Atmospheric Administration, recently released version 3.1 of the Horizontal Time-Dependent Positioning (HTDP) utility for transforming coordinates across time and between spatial reference frames. HTDP 3.1 introduces improved crustal velocity models for both the contiguous United States and Alaska. The new HTDP version also introduces a model for estimating displacements associated with the magnitude 7.2 El Mayor–Cucapah earthquake of April 4, 2010. In addition, HTDP 3.1 enables its users to transform coordinates between the newly adopted International Terrestrial Reference Frame of 2008 (ITRF2008) and IGS08 reference frames and other popular reference frames, including current realizations of NAD 83 and WGS84. A more convenient format to enter a list of coordinates to be transformed has been added. Users can now also enter dates in the decimal year format as well as the month-day-year format. The new HTDP utility, explanatory material and instructions are available at http://www.ngs.noaa.gov/TOOLS/Htdp/Htdp.shtml.     

Landcover Classification in the Taieri River Catchment,New Zealand: A Focus on the Riparian Zone

Abstract

Riparian vegetation has a fundamental influence on the biological, chemical and physical nature of rivers. The quantification of riparian landcover is now recognised as being essential to the holistic study of the ecosystem characteristics of rivers. Medium resolution satellite imagery is now commonly used as an efficient and cost effective method for mapping vegetation cover; however such data often lack the resolution to provide accurate information about vegetation cover within riparian corridors. To assess this, we measure the accuracy of SPOT multispectral satellite imagery for classification of riparian vegetation along the Taieri River in New Zealand. In this paper, we discuss different sampling strategies for the classification of riparian zones. We conclude that SPOT multispectral imagery requires considerable interpretative analysis before being adequate to produce sufficiently detailed maps of riparian vegetation required for use in stream ecological research.     

Qualitative GIS to Relate Perceptions with Behaviors among Fishers on Risky,Rocky Coasts

This article presents an innovative mixed methodology that integrates qualitative geographic information systes (GIS) methods to expand the examination of space in the context of people’s lived experiences and risk. We emphasize the specific ways in which individuals perceive risk by treating risk as relational. Conceptualizing risk as relational challenges traditional assumptions of risk by rejecting that risk is the combination of physical and social elements. Instead, a relational understanding explores the socioenvironmental interactions that are perceived as hazardous, as they emerge in space. Such claims have long animated risk research, but only recently have methodological advances opened opportunities for relational analyses. Using hazardous coasts as the case, we analyze rock fishers’ risk perceptions and whether those perceptions influence their movement. Analytically, we relate rock fishers’ Global Positioning System movement with participant observations, video, semistructured interviews, and sketch maps anchored to questions focusing on spatial understandings of risk. In doing so, fishers’ perceptions of socioenvironmental stimuli are spatially represented, with sketch mapping as a window into the perception–environment interactions that produce risk. This methodology opens new possibilities for understanding human–environment systems that typically overlook how, where, and for how long risky human–environment interactions are perceived in space, if at all. Key Words: qualitative GIS, relational, risk, risk perception, space.