Correlation of welded ignimbrites on Pantelleria (Strait of Sicily) using paleomagnetism

Although the oldest volcanic rocks exposed at Pantelleria (Strait of Sicily) are older than 300 ka, most of the island is covered by the 45–50 ka Green Tuff ignimbrite, thought to be related to the Cinque Denti caldera, and younger lavas and scoria cones. Pre-50 ka rocks (predominantly rheomorphic ignimbrites) are exposed at isolated sea cliffs, and their stratigraphy and chronology are not completely resolved. Based on volcanic stratigraphy and K/Ar dating, it has been proposed that the older La Vecchia caldera is related to ignimbrite Q (114 ka), and that ignimbrites F, D, and Z (106, 94, and 79 ka, respectively) were erupted after caldera formation. We report here the paleomagnetic directions obtained from 23 sites in ignimbrite P (133 ka) and four younger ignimbrites, and from an uncorrelated (and loosely dated) welded lithic breccia thought to record a caldera-forming eruption. The paleosecular variation of the geomagnetic field recorded by ignimbrites is used as correlative tool, with an estimated time resolution in the order of 100 years. We find that ignimbrites D and Z correspond, in good agreement with recent Ar/Ar ages constraining the D/Z eruption to 87 ka. The welded lithic breccia correlates with a thinner breccia lying just below ignimbrite P at another locality, implying that collapse of the La Vecchia caldera took place at ~130–160 ka. This caldera was subsequently buried by ignimbrites P, Q, F, and D/Z. Paleomagnetic data also show that the northern caldera margin underwent a ~10° west–northwest (outwards) tilting after emplacement of ignimbrite P, possibly recording magma resurgence in the crust.     

A GIS-based approach for gully erosion susceptibility modelling: a test in Sicily, Italy

The aim of this study is to analyze the susceptibility conditions to gully erosion phenomena in the Magazzolo River basin and to test a method that allows for driving the factors selection. The study area is one of the largest (225 km²) watershed of southern Sicily and it is mostly characterized by gentle slopes carved into clayey and evaporitic sediments, except for the northern sector where carbonatic rocks give rise to steep slopes. In order to obtain a quantitative evaluation of gully erosion susceptibility, statistical relationships between the spatial distributions of gullies affecting the area and a set of twelve environmental variables were analyzed. Stereoscopic analysis of aerial photographs dated 2000, and field surveys carried out in 2006, allowed us to map about a thousand landforms produced by linear water erosion processes, classifiable as ephemeral and permanent gullies. The linear density of the gullies, computed on each of the factors classes, was assumed as the function expressing the susceptibility level of the latter. A 40-m digital elevation model (DEM) prepared from 1:10,000-scale topographic maps was used to compute the values of nine topographic attributes (primary: slope, aspect, plan curvature, profile curvature, general curvature, tangential curvature; secondary: stream power index; topographic wetness index; LS-USLE factor); from available thematic maps and field checks three other physical attributes (lithology, soil texture, land use) were derived. For each of these variables, a 40-m grid layer was generated, reclassifying the topographic variables according to their standard deviation values. In order to evaluate the controlling role of the selected predictive variables, one-variable susceptibility models, based on the spatial relationships between each single factor and gullies, were produced and submitted to a validation procedure. The latter was carried out by evaluating the predictive performance of models trained on one half of the landform archive and tested on the other. Large differences of accuracy were verified by computing geometric indexes of the validation curves (prediction and success rate curves; ROC curves) drawn for each one-variable model; in particular, soil texture, general curvature and aspect demonstrated a weak or a null influence on the spatial distribution of gullies within the studied area, while, on the contrary, tangential curvature, stream power index and plan curvature showed high predictive skills. Hence, predictive models were produced on a multi-variable basis, by variously combining the one-variable models. The validation of the multi-variables models, which generally indicated quite satisfactory results, were used as a sensitivity analysis tool to evaluate differences in the prediction results produced by changing the set of combined physical attributes. The sensitivity analysis pointed out that by increasing the number of combined environmental variables, an improvement of the susceptibility assessment is produced; this is true with the exception of adding to the multi-variables models a variable, as slope aspect, not correlated to the target variable. The addition of this attribute produces effects on the validation curves that are not distinguishable from noise and, as a consequence, the slope aspect was excluded from the final multi-variables model used to draw the gully erosion susceptibility map of the Magazzolo River basin. In conclusion, the research showed that the validation of one-variable models can be used as a tool for selecting factors to be combined to prepare the best performing multi-variables gully erosion susceptibility model.     

Partial melting of ultrahigh-pressure metamorphic rocks at convergent continental margins: Evidences,melt compositions and physical effects

Ultrahigh-pressure(UHP) metamorphic rocks are distinctive products of crustal deep subduction,and are mainly exposed in continental subduction-collision terranes. UHP slices of continental crust are usually involved in multistage exhumation and partial melting, which has obvious influence on the rheological features of the rocks, and thus significantly affect the dynamic behavior of subducted slices. Moreover,partial melting of UHP rocks have significant influence on element mobility and related isotope behavior within continental subduction zones, which is in turn crucial to chemical differentiation of the continental crust and to crust-mantle interaction.Partial melting can occur before, during or after the peak metamorphism of UHP rocks. Post-peak decompression melting has been better constrained by remelting experiments; however, because of multiple stages of decompression, retrogression and deformation, evidence of former melts in UHP rocks is often erased. Field evidence is among the most reliable criteria to infer partial melting. Glass and nanogranitoid inclusions are generally considered conclusive petrographic evidence. The residual assemblages after melt extraction are also significant to indicate partial melting in some cases. Besides field and petrographic evidence, bulk-rock and zircon trace-element geochemical features are also effective tools for recognizing partial melting of UHP rocks. Phase equilibrium modeling is an important petrological tool that is becoming more and more popular in P-T estimation of the evolution of metamorphic rocks; by taking into account the activity model of silicate melt, it can predict when partial melting occurred if the P-T path of a given rock is provided.UHP silicate melt is commonly leucogranitic and peraluminous in composition with high SiO_2,low MgO, FeO, MnO, TiO_2 and CaO, and variable K_2 O and Na_2 O contents. Mineralogy of nanogranites found in UHP rocks mainly consists of plagioclase + K-feldspar + quartz, plagioclase being commonly albite-rich.Trace element pattern of the melt is characterized by significant enrichment of large ion lithophile elements(LILE), depletion of heavy rare earth elements(HREE) and high field strength elements(HFSE),indicating garnet and rutile stability in the residual assemblage. In eclogites, significant Mg-isotope fractionation occurs between garnet and phengite; therefore, Mg isotopes may become an effective indicator for partial melting of eclogites.     

Petrogenesis and geodynamic significance of silicic volcanism in the western Trans-Mexican Volcanic Belt: role of gabbroic cumulates

In the western Trans-Mexican Volcanic Belt voluminous silicic volcanism has been associated with the rifting of the Jalisco block from mainland Mexico. Rhyolitic volcanism started at 7.5 Ma after a major pulse of basaltic volcanism aged 11–8.5 Ma associated with slab detachment. This was followed by a second period, between 4.9 and 2.9 Ma, associated with rhyolitic domes and ignimbrite coexisting with basaltic volcanism. The similarity in rare earth element contents between basalts and rhyolites excludes a simple liquid line of descent. The low Ba and Sr contents and the ferroan character of the rhyolites suggest extensive fractional crystallization. Late Miocene–early Pliocene rhyolite Sr isotope values are only slightly more radiogenic than the basalts, whereas Nd isotope ratios are indistinguishable. We successfully modelled the 7.5–3 Ma silicic magmatism as a result of partial melting of crustal gabbroic complexes that we infer to have formed in the mid-lower crust due to the high-density Fe-enriched composition of the late Miocene basaltic volcanism. Slab rollback since ~7.5 Ma favoured decompression melting and arrival of additional mafic magmas that intruded in the lower crust. These basalts heated and melted the gabbroic complexes forming the silicic magmas, which subsequently underwent assimilation and fractional crystallization processes. The first silicic pulse was emplaced during a period of low tectonic activity. Extensional faulting since the Pliocene favours the eruption of both silicic magma and lesser amount of mafic lavas.     

The Role of a Macroalgal Covering Event on the Microphytobenthos Community in Intertidal Sediment (Marano Lagoon, Northern Adriatic Sea)

Abstract. This study examines the variation in microphytobenthos structure and functioning in an intertidal lagoon during a macroalgal covering event. Multivariate techniques, applied on the recorded data, highlighted a clear seasonal pattern except for the July sample. The sudden macroalgae ( Cladophora sp.) development, which occurred in that month, enabled us to identify the massive covering as a disturbance factor on the benthic ecosystem. This biotic anomaly affected benthic microalgal production and community respiration, shifting the ecosystem from a highly photoautotrophic to an heterotrophic condition as shown by the BTS Index. This trophic index is therefore a useful tool for identifying episodic stress events mainly in intertidal habitats.     

Multistage Metamorphic Evolution and P-T-t Path of High-T Eclogite from the North Dabie Complex Zone during Continental Subduction and Exhumation

正Objective High-T eclogites from the North Dabie complex zone(NDZ),central China underwent a complex metamorphic evolution involved in ultrahigh-pressure(UHP)and highpressure eclogite-facies metamorphism,and subsequent     

Quaternary adakite—Nb-enriched basalt association in the western Trans-Mexican Volcanic Belt: is there any slab melt evidence?

A spatial and temporal association between adakitic rocks and Nb-enriched basalts (NEB) is recognised for the first time in the western sector of the Trans-Mexican Volcanic Belt in the San Pedro–Cerro Grande Volcanic Complex (SCVC). The SCVC is composed of subalkalic intermediate to felsic rocks, spanning in composition from high-silica andesites to rhyolites, and by the young transitional hawaiite and mugearite lavas of Amado Nervo shield volcano. Intermediate to felsic rocks of the SCVC show many geochemical characteristics of typical adakites, such as high Sr/Y ratios (up to 180) and low Y (<18 ppm) and Yb contents. Mafic Amado Nervo rocks have high TiO₂ (1.5–2.3 wt%), Nb (14–27 ppm), Nb/La (0.5–0.9) and high absolute abundances of HFSE similar to those shown by NEB. However, the Sr and Nd isotopic signature of SCVC rocks is different from that shown by typical adakites and NEB. Although the adakites–NEB association has been traditionally considered as a strong evidence of slab-melting, we suggest that other processes can lead to its generation. Here, we show that parental magmas of adakitic rocks of the SCVC derive their adakitic characteristic from high-pressure crystal fractionation processes of garnet, amphibole and pyroxene of a normal arc basalt. On the other hand, Amado Nervo Na-alkaline parental magmas have been generated by sediment melting plus MORB-fluid flux melting of a heterogeneous mantle wedge, consisting of a mixture of depleted and an enriched mantle sources (90DM + 10EM). We cannot exclude a contribution to the subduction component of slab melts, because the component signature is dominated by sediment melt, but we argue that caution is needed in interpreting the adakites–NEB association in a genetic sense.     

Ontology‐supported Querying of Geographical Databases

Querying geographical information systems has been recognized as a difficult task for non‐expert users. Furthermore, user queries are often characterized by semantic aspects not directly managed by traditional spatial databases or GIS. Examples of such semantic geospatial queries are the use of implicit spatial relations between objects, or the reference of domain concepts not explicitly represented in data. To handle such queries, we envisage a system that translates natural language queries into spatial SQL statements on a database, thus improving standard GIS with new semantic capabilities. Within this general objective, the contribution of this article is to introduce a methodology to handle semantic geospatial queries issued over a spatial database. This approach captures semantics from an ontology built upon the spatial database and enriched by domain concepts and properties specifically defined to represent the localization of objects. Some examples of the use of the methodology in the urban domain are presented.     

Petrology of Karoo volcanic rocks in the southern Lebombo monocline, Mozambique

The Karoo volcanic sequence in the southern Lebombo monocline in Mozambique contains different silicic units in the form of pyroclastic rocks, and two different basalt types. The silicic units in the lower part of the Lebombo sequence are formed by a lower unit of dacites and rhyolites (67–80 wt.% SiO₂) with high Ba (990–2500 ppm), Zr (800–1100 ppm) and Y (130–240 ppm), which are part of the Jozini–Mbuluzi Formation, followed by a second unit, interlayered with the Movene basalts, of high-SiO₂ rhyolites (76–78 wt.%; the Sica Beds Formation), with low Sr (19–54 ppm), Zr (340–480 ppm) and Ba (330–850 ppm) plus rare quartz-trachytes (64–66 wt.% SiO₂), with high Nb and Rb contents (240–250 and 370–381 ppm, respectively), and relatively low Zr (450–460 ppm). The mafic rocks found at the top of the sequence are basalts and ferrobasalts belonging to the Movene Formation. The basalts have roughly flat mantle-normalized incompatible element patterns, with abundances of the most incompatible elements not higher than 25 times primitive mantle. The ferrobasalt has TiO₂  4.7 wt.%, Fe₂O_3t = 16 wt.%, and high Y (100 ppm), Zr (420 ppm) and Ba (1000 ppm). The Movene basalts have initial (at 180 Ma) ⁸⁷Sr/⁸⁶Sr = 0.7052–0.7054 and ¹⁴³Nd/¹⁴⁴Nd = 0.51232, and the Movene ferrobasalt has even lower ⁸⁷Sr/⁸⁶Sr (0.70377) and higher ¹⁴³Nd/¹⁴⁴Nd (0.51259). The silicic rocks show a modest range of initial Sr-(⁸⁷Sr/⁸⁶Sr = 0.70470–0.70648) and Nd-(¹⁴³Nd/¹⁴⁴Nd = 0.51223–0.51243) isotope ratios. The less evolved dacites could have been formed after crystal fractionation of oxide-rich gabbroic cumulates from mafic parental magmas, whereas the most silica-rich rhyolites could have been formed after fractional crystallization of feldspars, pyroxenes, oxides, zircon and apatite from a parental dacite magma. The composition of the Movene basalts imply different feeding systems from those of the underlying Sabie River basalts.     

Natural and anthropogenic forcing of Holocene lake ecosystem development at Lake Uddelermeer (The Netherlands)

Lake Uddelermeer (The Netherlands) is characterized by turbid conditions and annual blooms of toxic cyanobacteria, which are supposed to be the result of increased agricultural activity in the twentieth century AD. We applied a combination of classic palaeoecological proxies and novel geochemical proxies to the Holocene sediment record of Lake Uddelermeer (The Netherlands) in order to reconstruct the natural variability of the lake ecosystem and to identify the drivers of the change to the turbid conditions that currently characterize this lake. We show that the lake ecosystem was characterized by a mix of aquatic macrophytes and abundant phytoplankton between 11,500 and 6000 cal year BP. A transition to a lake ecosystem with clear-water conditions and relatively high abundances of ‘isoetids’ coincides with the first signs of human impact on the landscape around Lake Uddelermeer during the Early Neolithic (ca. 6000 cal year BP). An abrupt and dramatic ecosystem shift can be seen at ca. 1030 cal year BP when increases in the abundance of algal microfossils and concentrations of sedimentary pigments indicate a transition to a turbid phytoplankton-dominated state. Finally, a strong increase in concentrations of plant and faecal biomarkers is observed around 1950 AD. Canonical Correspondence Analysis suggests that reconstructed lake ecosystem changes are best explained by environmental drivers that show long-term gradual changes (sediment age, water depth). These combined results document the long-term anthropogenic impact on the ecosystem of Lake Uddelermeer and provide evidence for pre-Industrial Era signs of eutrophication.