Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

Microorganisms in Lianxian lateritic gold deposit in Guangdong and their effects on leaching of heavy metals

Microorganisms in the lateritic profiles of the Lianxian gold deposit in Guangdong were cultured, isolated and identified. The microorganisms include bacteria such as Bacillus, Enterobacter, Pseudomonas, Lactobacillus, Actinetobacter, Aeromona, Listeria, Agrobacteriura, Cotyttebacteriurn, and Moraxella, fungi such as Penicillium, Alter naria, Cladosporium, Saccharcornyces, Mucor, and the chemoautotrophic Thiobacillu.~. It is shown in a leaching experiment that the microorganisms can accelerate the leaching of Cu, Cd, Zn, and that the G- bacteria are most efficient for leaching Cu, Zn and the G^ bacteria are better for leaching Cd.     

The effects of land use on runoff and soil nutrient losses in a gully catchment of the hilly areas： implications for erosion control

1 Introduction Soiland waterlossisoneofthe worldwide environm entalissuesthreatening sustainable land use in semiarid areas.However,soiland water loss is highly variable in space and time,and its variability resultsfrom m any factorsoperating ata wide ran…     

Climatic response of thick leaf spruce (Picea crassifolia) tree-ring width at different elevations over Qilian Mountains, northwestern China

Tree-ring cores of thick leaf spruce (Picea crassifolia) taken from four sites at different elevations, in the middle of the Qilian Mountains, in the arid and semi-arid region of northwestern China, were used to develop four tree-ring width chronologies using standard dendrochronological methods. Results indicate that with increasing altitude the chronologies’ year-to-year variations decreased. Hence, the sensitivity of the tree-ring chronologies to climate decreases with altitude. Further analysis showed that the significant limiting factor on tree growth is spring precipitation. Measurements of stomata density and leaf dry weight suggest the species’ ecological adaptation strategy changes with elevation. At high elevation the metabolic rate of thick leaf spruce decreases, thus showing the effect of the climate.     

Gas accumulation from oil cracking in the eastern Tarim Basin: A case study of the YN2 gas field

Oil and gas exploration in eastern Tarim Basin, NW China has been successful in recent years, with several commercial gas accumulations being discovered in a thermally mature to over-mature region. The Yingnan2 (YN2) gas field, situated in the Yingnan structure of the Yingjisu Depression, produces gases that are relatively enriched in nitrogen and C₂₊ alkanes. The δ¹³C₁ (−38.6‰ to −36.2‰) and δ¹³C₂ values (−30.9‰ to −34.7‰) of these gases are characteristic of marine sourced gases with relatively high maturity levels. The distributions of biomarkers in the associated condensates suggest close affinities with the Cambrian–Lower Ordovician source rocks which, in the Yingjisu Sag, are currently over-mature (with 3–4%Ro). Burial and thermal maturity modeling results indicate that paleo-temperatures of the Cambrian–Lower Ordovician source rocks had increased from 90 to 210 °C during the late Caledonian orogeny (458–438 Ma), due to rapid subsidence and sediment loading. By the end of Ordovician, hydrocarbon potential in these source rocks had been largely exhausted. The homogenization temperatures of hydrocarbon fluid inclusions identified from the Jurassic reservoirs of the YN2 gas field suggest a hydrocarbon emplacement time as recent as about 10 Ma, when the maturity levels of Middle–Lower Jurassic source rocks in the study area were too low (<0.7%Ro) to form a large quantity of oil and gas. The presence of abundant diamondoid hydrocarbons in the associated condensates and the relatively heavy isotopic values of the oils indicate that the gases were derived from thermal cracking of early-formed oils. Estimation from the stable carbon isotope ratios of gaseous alkanes suggests that the gases may have been formed at temperatures well above 190 °C. Thus, the oil and gas accumulation history in the study area can be reconstructed as follows: (1) during the late Caledonian orogeny, the Cambrian–Lower Ordovician marine source rocks had gone through the peak oil, wet gas and dry gas generation stages, with the generated oil and gas migrating upwards along faults and fractures to form early oil and gas accumulations in the Middle–Upper Ordovician and Silurian sandstone reservoirs; (2) since the late Yanshanian orogeny, the early oil accumulations have been buried deeper and oil has undergone thermal cracking to form gas; (3) during the late Himalayan orogeny, the seals for the deep reservoirs were breached; and the gas and condensates migrated upward and eventually accumulating in the relatively shallow Jurassic reservoirs.     

Denitrification capacity in a subterranean estuary below a Rhode Island fringing salt marsh

Coastal waters are severely threatened by nitrogen (N) loading from direct groundwater discharge. The subterranean estuary, the mixing zone of fresh groundwater and sea water in a coastal aquifer, has a high potential to remove substantial N. A network of piezometers was used to characterize the denitrification capacity and groundwater flow paths in the subterranean estuary below a Rhode Island fringing salt marsh.¹⁵N-enriched nitrate was injected into the subterranean estuary (in situ push-pull method) to evaluate the denitrification capacity of the saturated zone at multiple depths (125–300 cm) below different zones (upland-marsh transition zone, high marsh, and low marsh). From the upland to low marsh, the water table became shallower, groundwater dissolved oxygen decreased, and groundwater pH, soil organic carbon, and total root biomass increased. As groundwater approached the high and low marsh, the hydraulic gradient increased and deep groundwater upwelled. In the warm season (groundwater temperature >12 °C), elevated groundwater denitrification capacity within each zone was observed. The warm season low marsh groundwater denitrification capacity was significantly higher than all other zones and depths. In the cool season (groundwater temperature <10.5 °C), elevated groundwater denitrification capacity was only found in the low marsh. Additions of dissolved organic carbon did not alter groundwater denitrification capacity suggesting that an alternative electron donor, possibly transported by tidal inundation from the root zone, may be limiting. Combining flow paths with denitrification capacity and saturated porewater residence time, we estimated that as much as 29–60 mg N could be removed from 11 of water flowing through the subterranean estuary below the low marsh, arguing for the significance of subterranean estuaries in annual watershed scale N budgets.     

福建省水氡观测资料变化规律与质量分析

本文对福建省水氡观测资料变化规律进行分析,并试图利用相对均方差、拟合噪声水平和相对年变幅等三项指标,对福建省8个水氡点的观测资料质量进行初步探索。     

浅析福建地倾斜潮汐因子γ及其组合动态特征

本文计算了福建自1992年至2004年以来的地倾斜EW和NS两分量的固体潮潮汐因子,并进行动态组合,绘制组合动态三种特征量:ΔγEW ΔγNS(表征扩容)、ΔγEW-ΔγNS(表征剪切应变)、ΔγEW/ΔγNS(表征介质各向异性)的时序曲线图,并进行固体潮特征分析,寻找中、强地震发生前远场块体和近场块体地倾斜突变性形变异常与之对应关系。结果表明:在福建沿海,海潮是决定倾斜固体潮特征的主要因素;福建发生5级上的中强地震、台湾发生7级以上强烈地震时,福建地倾斜固体潮潮汐因子及其动态组合特征存在明显的渐进式突变性形变异常现象,异常量和异常持续时间与震级和震中距有较好的对应关系。     

北黄海盆地构造几何学研究新进展

北黄海盆地是发育于隆起背景之上的中、新生代沉积盆地。新一轮资源调查研究表明，北黄海中、新生代沉积盆地的基底由古生界沉积岩层和前寒武纪变质岩系等组成，盆地不同程度地发育下构造层（J3-K1）、中构造层（E2-E3）和上构造层（N）；从油气资源和中、新生代地层发育情况出发，将北黄海海域划分为辽东-海洋岛隆起区、北黄海盆地和胶北．刘公岛隆起区等3个一级构造单元，其中北黄海盆地包括6个二级构造单元和24个三级构造单元；盆地褶皱、断裂构造十分发育，褶皱构造可划分为区域挤压型、局部伴生型和披盖型等三类，断裂构造主要可见近EW—NE向、NW向和NNE向三组，其中近EW—NE向和NNE向断裂比较发育，控制着盆地隆、坳分布格局和沉积特征。