Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

The Mg Ⅱ absorption line systems in quasar spectra from the Large Sky Area Multi-Object Fiber Spectroscopic Telescope

Making use of quasar spectra from LAMOST,in the spectral data around the Mg Ⅱ emission lines,research described in this paper has detected 217 Mg Ⅱ narrow absorption lines(NALs) with W_r ~(λ2796)≥3σ_w and W_r~(λ2803)≥ 2σ_w in a redshift range of 0.4554≤z_(abs)≤2.1110.For quasars observed by both LAMOST and SDSS,we find that 135 Mg Ⅱ NALs were obviously observed in the LAMOST spectra,347 Mg Ⅱ NALs were were apparent in the SDSS spectra,and 132 Mg Ⅱ NALs were clearly present in both the SDSS and LAMOST spectra.The missed Mg Ⅱ NALs are likely ascribed to low signal-to-noise ratios of corresponding spectra.Among the Mg 11 NALs obviously observed in SDSS or LAMOST spectra,eight Mg 11 NALs were significantly changed with |ΔW_r ~(λ2796)|≥3σ_w in time intervals of ΔMJD/(1+z_(em))=359-2819 d.     

基于POGIL理论的地理研学旅行设计研究——以山东省沂河滨河湿地研学为例

研学旅行是中小学开展综合实践活动的重要方式,本文以山东省沂河滨河湿地研学为例,使用“过程取向-指导式探究学习”理论,以问题为导向,提高学生发现问题、解决问题的能力,提高地理实践力。     

Effect of nano-MgO on mechanical performance of cement stabilized silty clay

Abstract

A series of direct shear tests were performed on cement-admixed silty clay to investigate the effect of cement content and nano-magnesia (MgO) on its shear strength properties. For each normal stress, shear strength increased with cement content. However, an obvious increment in shear strength was achieved when the cement content was adjusted from 13% to 17%. Both cohesion and friction angle of cemented soil increased with cement content, and exponential function was adopted to correlate both the factors with cement content. For cement content of 10% investigated in this study, the optimum nano-MgO content was 10‰, wherein the cohesion could reach the peak value. The microstructure of the mixture revealed that the structure of the mixture was compacted for the optimum nano-MgO content. However, micro-cracks were formed when the amount of nano-MgO exceeded its optimum content.     

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性,属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高,α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高,且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸,并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示,α螺旋和β片层围成了蛋白酶的催化腔,EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体,且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性,并有助于其催化功能的发挥,为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。     

Base cation concentrations in forest litter and topsoil have different responses to climate and tree species along elevational gradients

The forest litter is an essential reservoir of nutrients in forests, supplying a large part of absorbable base cations(BC) to topsoil, and facilitating plant growth within litter-soil system. To characterize elevational patterns of base cation concentrations in the forest litter and topsoil, and explore the effects of climate and tree species, we measured microclimate and collected the forest litter and topsoil(0-10 cm) samples across an elevational range of more than 2000 m(1243 ～ 3316 m a.s.l.),and analyzed the concentrations of BC in laboratory. Results showed that: 1) litter Ca concentration displayed a hump-shaped pattern along the elevational gradients, but litter K and Mg showed saddle-shaped patterns. Soil Ca concentration increased with elevation, while soil K and Mg had no significant changes. 2) Ca concentration in the forest litter under aspen(Populus davidiana) was significantly higher than that in all other species, but in topsoil, Ca concentration was higher under coniferous larch and fir(Larix chinensis and Abies fargesii). Litter K and Mg concentrations was higher under coniferous larch and fir, whereas there were nosignificant differences among tree species in the concentrations of K and Mg in topsoil. 3) Climatic factors including mean annual temperature(MAT), growing season precipitation(GSP) and non-growing season precipitation(NGSP) determined BC concentrations in the forest litter and topsoil. Soil C/N and C/P also influenced BC cycling between litter and soil. Observation along elevations within different tree species implies that above-ground tree species can redistribute below-ground cations, and this process is profoundly impacted by climate. Litter and soil Ca, K and Mg with different responses to environmental variables depend on their soluble capacity and mobile ability.     

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素

城市经济脆弱性作为当前脆弱性研究中的重要领域,为人-地系统耦合研究提供了新的视角,并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵,基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系,运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性,并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年,河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）;（2）河西走廊地区的城市经济脆弱性具有明显的空间特征,经历了东西高、中部低到整体较高的演变过程;（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子,提出针对性优化措施。     

Effect of polysaccharide from Enteromorpha prolifera on maize seedlings under NaCl stress

In this study, a polysaccharide from Enteromorpha prolifera (EP) was extracted and its effect on maize seedlings under NaCl stress was investigated. Firstly, the components and structure of the EP were determined. We found that EP is a sulfated polysaccharide of high-molecular weight (Mw, 1 840 KDa) heteropolysaccharides and the main monosaccharide is rhamnose. The polysaccharide was applied to explore its effect on the growth of maize seedlings and its defense response under a salt stress. The results show that EP could promote the growth of maize seedlings under the salt stress. In addition, EP was shown able to significantly regulate membrane permeability and adjustment of osmotic substances such as soluble protein, soluble sugar, and proline, antioxidant enzymes containing superoxide dismutase, catalase, peroxidase, and ascorbate peroxidase. Therefore, EP is an effective salt-resistant substance for the growth of maize seedlings under NaCl stress.     

海洋环境对猎雷声呐探测识别的影响及对策建议

猎雷是各海军强国重点发展方向,猎雷作战中首要的就是探测识别水雷。从传播损失、混响、 目标强度以及海流、潮汐等多个方面分析了海洋环境对猎雷声呐探测识别的影响,并从猎雷作战角度提出了有关参数设置、作战方式、数据处理等对策建议,可为部队探测识别水雷等目标提供有效参考。