Facies character and geochemical signature in the late Quaternary meteoric diagenetic carbonate succession at the Xisha Islands,South China Sea

The late Quaternary shallow-water carbonates have been altered by a variety of diagenetic processes, and further influenced by high-amplitude global and regional sea level changes. This study utilizes a new borehole drilled on the Yongxing Island, Xisha Islands to investigate meteoric diagenetic alteration in the late Quaternary shallowwater carbonates. Petrographic, mineralogical, stable isotopic and elemental data provide new insights into the meteoric diagenetic processes of the reef limestone. The results show the variation in the distribution of aragonite,high-Mg calcite(HMC) and low-Mg calcite(LMC) divides the shallow-water carbonates in Core SSZK1 into three intervals, which are Unit I(31.20–55.92 m, LMC), Unit II(18.39–31.20 m, aragonite and LMC) and Unit III(upper 18.39 m of core, aragonite, LMC and HMC). Various degrees of meteoric diagenesis exist in the identified three units. The lowermost Unit I has suffered almost complete freshwater diagenesis, whereas the overlying Units II and III have undergone incompletely meteoric diagenesis. The amount of time that limestone has been in the freshwater diagenetic environment has the largest impact on the degree of meteoric diagenesis. Approximately four intact facies/water depth cycles are recognized. The cumulative depletion of elements such as strontium(Sr),sodium(Na) and sulphur(S) caused by duplicated meteoric diagenesis in the older reef sequences are distinguished from the younger reef sequences. This study provides a new record of meteoric diagenesis, which is well reflected by whole-rock mineralogy and geochemistry.     

藏南错那洞淡色花岗岩中电气石矿物学和地球化学特征

错那洞淡色花岗岩与错那洞穹隆及周边的铅锌和钨锡铍矿床具有时空上的密切关系.含电气石淡色花岗岩是错那洞高分异淡色花岗岩的代表性岩石.岩相学研究表明,错那洞电气石可分为GT型和PT型两类.本次研究利用电子探针以及LA-ICP-MS分析两种类型电气石的化学组成.结果表明,GT型电气石中Fe/(Fe+Mg)原子比值为0.83～...     

商丘近40 a蒸发量变化特征及原因分析

利用商丘1961-2000年小型蒸发皿蒸发量资料,分析了商丘蒸发量的变化趋势及引起蒸发量变化的因子,结果表明,商丘年、季和月蒸发量均存在明显的下降趋势,影响蒸发量变化的因子主要有风速、日照、相对湿度、水汽压等.     

Vision-based tracking with projective mapping for parameter identification of remotely operated vehicles

Parameter identification of a remotely operated vehicle (ROV) is often based on the dynamic responses collected by its onboard sensors. However, for commercial ROVs, the required data for identification may not be available due to the absence of suitable sensors or limitations in accessing onboard sensor data. Therefore, this study proposes a vision-based tracking system to measure the dynamic response of an ROV. The tracking system is independent of the ROV, and is able to localize an ROV to a high degree of precision by means of projective mapping. The validity of the proposed tracking system is demonstrated through identification of a commercial ROV. A simplified nonlinear ROV dynamic model with six degrees of freedom (DOF) is used for identification. Uncoupled motions, including surge, sway, and yaw, are obtained from the ROV dynamic model, and the corresponding experiments are carried out for each DOF. Hydrodynamic parameters are then estimated with numerical optimizations by comparing the measured ROV responses with the output of the mathematical model. The experimental results show that the vision-based tracking system can accurately measure the transient and steady-state responses of an ROV. Additionally, the simulations of the ROV dynamic model, with the optimal parameter estimates, give results in agreement with the measured data.     

The penetration experiment to predict liquefaction resistance of reclaimed soils

The liquefaction resistance of the soils used to be estimated through the in situ tests, such as standard penetration test and cone penetration test; or by means of cyclic triaxial test in laboratory. However, both in situ tests and cyclic triaxial test are time-consuming and costly; this study introduces a quick and cost-effective method to evaluate the liquefaction resistance of soils under certain confining pressure in laboratory. A particular device modified from the conventional triaxial compression test apparatus, namely “Triaxial Cone Penetration Test”, was developed to obtain the peak values of cone resistance in soils so as to correlate the liquefaction resistance of the reclaimed soils evaluated by cyclic triaxial tests. The test result indicates a good correlation between the peak value of cone resistance and the corresponding cyclic stress ratio (CSR) at the state of initial liquefaction, in which the correlation for loose samples is better than that for dense samples. Besides, both peak values of cone resistance and corresponding CSR increase with fine content of soils reaches 10% and decreased with fine content varying between 10% and 50%. By examining the compositions of the soils with scanning electron microscopy and X-ray diffraction, it is found that the proportion and characteristics of the fines plays an important role on the liquefaction resistance of the reclaimed soils.     

Comparison of ecophysiological characteristics between introduced and indigenous mangrove species in China

Due to its rapid growth, the introduced mangrove species Sonneratia apetala from Bangladesh has been widely used in mangrove restoration in southeastern China since 1985. As an indigenous mangrove species in Hainan, China, Sonneratia caseolaris was also planted in Guangdong Province for afforestation purposes. Both species have developed well in their new habitats, but their ecophysiological differences with the native mangrove species have not been studied. In this study, leaf gas exchange, water and nitrogen use efficiencies of two Sonneratia species were compared with those of selected native mangrove species (Avicennia marina, Aegiceras corniculatum, Kandelia candel, and Excoecaria agallocha) in Hainan and Shenzhen. The introduced S. apetala maintained lower carbon assimilation rate (A) and photosynthetic nitrogen use efficiency (PNUE) than the indigenous S. caseolaris. In Shenzhen, the two introduced Sonneratia had comparable photosynthetic rates and water use efficiency (WUE) with the native mangrove species, except that PNUE in S. caseolaris was significantly higher than in the native mangrove species. The two Sonneratia species showed significant overlap in PNUE and long-term WUE. Photosynthetic parameters derived from leaf photosynthetic light–response curves and A–C_i curves also suggested lower carbon assimilation capacities for the introduced Sonneratia than for the native mangrove species in both study sites. The lower light compensation point (LCP) of two introduced Sonneratia in both study sites also indicated a better adaptation to a low light regime than the native mangrove species. The results of photosynthetic capacities indicated that the introduced mangrove species have little competitive advantage over local native mangrove species in their respective new habitats.     

Petroleum pollution in surface sediments of Daya Bay,South China,revealed by chemical fingerprinting of aliphatic and alicyclic hydrocarbons

Nine surface sediments collected from Daya Bay have been Soxhlet-extracted with 2:1 (v/v) dichloromethane-methanol. The non-aromatic hydrocarbon (NAH) fraction of solvent extractable organic matter (EOM) and some bulk geochemical parameters have been analyzed to determine petroleum pollution of the bay. The NAH content varies from 32 to 276 μg g⁻¹ (average 104 μg g⁻¹) dry sediment and accounts for 5.8–64.1% (average 41.6%) of the EOM. n-Alkanes with carbon number ranging from 15 to 35 are identified to be derived from both biogenic and petrogenic sources in varying proportions. The contribution of marine authigenic input to the sedimentary n-alkanes is lower than the allochthonous input based on the average n-C₃₁/n-C₁₉ alkane ratio. 25.6–46.5% of the n-alkanes, with a mean of 35.6%, are contributed by vascular plant wax. Results of unresolved complex mixture, isoprenoid hydrocarbons, hopanes and steranes also suggest possible petroleum contamination. There is strong evidence of a common petroleum contamination source in the bay.     

Seasonal changes in nitrogen and phosphorus transport in the lower Changjiang River before the construction of the Three Gorges Dam

Water and sediment samples were collected at Datong from June 1998 to March 1999 to examine seasonal changes in the transports of nitrogen (N) and phosphorus (P) from the Changjiang River (Yangtze River) to the East China Sea (ECS). Dissolved inorganic nitrogen (DIN; dominated by nitrate) concentration exhibited small seasonality, and DIN flux was largely controlled by water discharge. Dissolved inorganic phosphorus (DIP) concentration was inversely correlated with water discharge, and DIP was evenly delivered throughout a year. The transports of DIN and DIP from the Changjiang River were consistent with seasonal changes in nutrient distributions and P limitation in the Changjiang Estuary and the adjacent ECS. Dissolved organic and particulate N (DON and PN) and P (DOP and PP) varied parallel to water discharge, and were dominantly transported during a summer flood. The fluxes of DOP and particulate bioavailable P (PBAP) were 2.5 and 4 times that of DIP during this period, respectively. PBAP accounted for 12–16% of total particulate P (PP), and was positively correlated with the summation of adsorbed P, Al–P and Fe–P. Ca–P, the major fraction of PP, increased with increasing percent of CaCO₃. The remobilization of riverine DOP and PBAP likely accounted for the summer elevated primary production in DIP-depleted waters in the Changjiang Estuary and the adjacent ECS. The Changjiang River delivered approximately 6% of DIN (1459 × 10⁶ kg), 1% of DIP (12 × 10⁶ kg), and 2% of dissolved organic and particulate N and P to the totals of global rivers. The construction of the Three Gorges Dam might have substantially reduced the particulate nutrient loads, thereby augmenting P limitation in the Changjiang Estuary and ECS.     

Dissolved inorganic carbon (DIC) and its carbon isotopic composition in sediment pore waters from the Shenhu area,northern South China Sea

The Shenhu area is one of the most favorable places for the occurrence of gas hydrates in the northern continental slope of the South China Sea. Pore water samples were collected in two piston cores (SH-A and SH-B) from this area, and the concentrations of sulfate and dissolved inorganic carbon (DIC) and its carbon isotopic composition were measured. The data revealed large DIC variations and very negative δ ¹³C-DIC values. Two reaction zones, 0–3 mbsf and below 3 mbsf, are identified in the sediment system. At site SH-A, the upper zone (0–3 mbsf) shows relatively constant sulfate and DIC concentrations and δ ¹³C-DIC values, possibly due to bioturbation and fluid advection. The lower zone (below 3 mbsf) displays good linear gradients for sulfate and DIC concentrations, and δ ¹³C-DIC values. At site SH-B, both zones show linear gradients, but the decreasing gradients for δ ¹³C-DIC and SO₄ ²⁻ in the lower zone below 3 mbsf are greater than those from the upper zone, 0–3 mbsf. The calculated sulfate-methane interface (SMI) depths of the two cores are 10.0 m and 11.1 m, respectively. The depth profiles of both DIC and δ ¹³C-DIC showed similar characteristics as those in other gas hydrate locations in the world oceans, such as the Blake Ridge. Overall, our results indicate an anaerobic methane oxidation (AMO) process in the sediments with large methane flux from depth in the studied area, which might be linked to the formation of gas hydrates in this area.