Triton: stratospheric molecules and organic sediments

Hydrocarbons and nitriles are produced in Triton's stratosphere by energetic electrons from Neptune's magnetosphere and other charged particle sources. Laboratory plasma experiments reported here show a substantial yield of molecules from low pressure flows of 10(-3) CH4 in N2 appropriate to Triton if both CH4 and N2 are saturated at the surface. An active magnetosphere similar to that of Uranus would result in a flux approximately 0.3 erg cm-2 s-1 of 0.1-1 MeV electrons in Triton's stratosphere; molecular production rates are then 10(6)-10(8) cm-2 s-1 for NH3, C2H2, HCN, and NCCN; tens of hundreds of gm cm-2 of these compounds per 10(9) yr (and lesser quantities of at least eight other molecules experimentally detected) would freeze to fine-grained white condensates in the lower stratosphere and sediment to the surface. Along with dark/colored organic haze produced in the stratosphere and other heteropolymers produced at the surface, these condensates are subjects to redistribution by aeolian processes and may appear as lag deposits and/or sediment layers. A simple eddy diffusion model indicates abundances approximately 10(19) molec cm-2 for HCN and C2H2, and > 10(17) molec cm-2 for NCCN, CH3CCH, CH2CCH2, and CH3CN in the stratosphere; these and other organic molecules will be detectable by IRIS if the stratosphere is (as expected) heated through ultraviolet and visible light absorption by the haze.     

Noble gases in the earth's mantle

The abundances and isotopic compositions of noble gases in two samples from ultramafic xenoliths in alkali basalt, a young kaersutitic amphibole separated from a peridotite xenolith from Dish Hill, California and an ancient whole-rock lherzolite xenolith from Baja California, are reported and compared with the results of analyses on other mantle samples. In addition to previously recognized excesses of ³He and ¹²⁹Xe, our results indicate that ambient gases in the mantle show a general enrichment of the lighter-mass nonradiogenic isotopes of Ar, Kr and Xe, and Ar with ⁴⁰Ar/³⁶Ar = 3 · 10².     

Cumulate gabbros from the Southwest Indian Ridge, 54°S-7° 16′ E: implications for magmatic processes at a slow spreading ridge

A diverse volcanic and plutonic rock suite was recovered from the center of the 80 km long ridge segment of the Southwest Indian Ridge (54°S, 7°16 E) between the Islas Orcadas and Shaka Fracture Zones. The cumulus nature of the gabbroic rocks in the suite is indicated by phase, modal and cryptic layering, igneous lamination, and low incompatible element abundances. We present a mass-balance model for calculating the proportions and compositions of cumulus phases and crystallized intercumulus liquid from bulk-rock major element compositions. The model is based on the ability to define a compositional array of basaltic liquids and on the assumption that cumulus minerals are initially in equilibrium with trapped liquid. Calculated proportions of trapped liquid range from 3%–15%; values that are characteristic of adcumulates to mesocumulates. Models of postcumulus crystallization indicate significant enrichments of incompatible elements and buffering of compatible elements in residual trapped liquids, thus explaining the high TiO₂ contents observed in magnesian clinopyroxenes. Cumulus phase assemblages and compositions suggest solidification in shallow level magma chambers, but disequilibrium plagioclase compositions suggest some crystallization at greater depth. Furthermore, basalt compositions projected onto the olivine-clinopyroxenequartz pseudoternary suggest magma generation over a range of pressures (from less than 10 to greater than 20 kb) as well as polybaric fractional crystallization. We suggest that the Southwest Indian Ridge is characterized by low magma supply with small batches of melt that either ascend directly to the surface having undergone limited polybaric crystallization or are trapped in shallow crustal magma chambers where they evolve and solidify to form cumulate gabbros. The adcumulus nature of the gabbros investigated here suggests slow cooling rates typical of large intrusions implying relatively large, but ephemeral magma chambers below segments of the Southwest Indian Ridge.     

Transforming local natural resource conflicts to cooperation in a changing climate: Bangladesh and Nepal lessons

ABSTRACT

Since the 1990s, climate change impact discourse has highlighted potential for large scale violent conflicts. However, the role of climate stresses on local conflicts over natural resources, the role of policies and adaptation in these conflicts, and opportunities to enhance cooperation have been neglected. These gaps are addressed in this paper using evidence from participatory action research on 79 cases of local collective action over natural resources that experience conflicts in Bangladesh and Nepal. Climate trends and stresses contributed to just under half of these conflict cases. Nine factors that enable greater cooperation and transformation of conflict are identified. Participatory dialogue and negotiation processes, while not sufficient, changed understanding, attitudes and positions of actors. Many of the communities innovated physical measures to overcome natural resource constraints, underlying conflict, and/or institutional reforms. These changes were informed by improving understanding of resource limitations and indigenous knowledge. Learning networks among community organizations encouraged collective action by sharing successes and creating peer pressure. Incentives for cooperation were important. For example, when community organizations formally permitted excluded traditional resource users to access resources, those actors complied with rules and paid towards management costs. However, elites were able to use policy gaps to capture resources with changed characteristics due to climate change. In most of the cases where conflict persisted, power, policy and institutional barriers prevented community-based organizations from taking up potential adaptations and innovations. Policy frameworks recognizing collective action and supporting flexible innovation in governance and adaptation would enable wider transformation of natural resource conflicts into cooperation.

Key policy insights

• Climate stresses, policy gaps and interventions can all worsen local natural resource conflicts.

• Sectoral knowledge and technical approaches to adaptation are open to elite capture and can foster conflicts.

• Many local natural resource conflicts can be resolved but this requires an enabling environment for participatory dialogue, external facilitation, flexible responses to context, and recognition of disadvantaged stakeholder interests.

• Transforming conflict to greater cooperation mostly involves social and institutional changes, so adaptation policies should focus less on physical works and more on enabling factors such as negotiation, local institutions, knowledge, and incentives.

     

Geochemistry and provenance of the Turquoise Bluff Slate,northeastern Tasmania: tectonic significance

The Ordovician Turquoise Bluff Slate in northeastern Tasmania is a 2?km-thick sequence of deep-marine siliceous black slates. It is dominated by meta-siltstones with bimodal grainsize distributions typical of turbidite T_E-1 and T_E-2 facies. The slates have high SiO₂ indicating they are hemipelagites. The high Ba and V indicate they were deposited in an anoxic environment associated with high oceanic productivity. All these features are common in muddy turbidites. U–Th–Pb dating of detrital monazite and authigenic xenotime in the slates supports previous evidence that the dominant cleavage, in this unit, formed during the Benambran Orogeny. The whole-rock composition of the slates is similar to black slates in the Adaminaby Group, NSW. A review of Paleozoic whole-rock compositions from the Lachlan Orogen confirms they all have trace element contents similar to average Australian shale. However, there are subtle differences in composition. The Turquoise Bluff Slate and other Mathinna Supergroup rocks from the Eastern Tasmania Terrane have higher average Cr content than similar age turbidites from Victoria and NSW. This probably reflects a small contribution from Tasmania Cambrian ultramafic rocks in the provenance. If this were correct, northeastern Tasmania was closer to western Tasmania in the Paleozoic than other provinces of the Lachlan Orogen, southeastern Australia. Other subtle features of the whole-rock composition of Paleozoic sedimentary rocks from the Lachlan Orogen indicate it may be possible to recognise provincial variations in composition that will provide new constraints on tectonic models of southeastern Australia.     

Associated terrestrial and marine fossils in the late-glacial Presumpscot Formation, southern Maine, USA, and the marine reservoir effect on radiocarbon ages

Excavations in the late-glacial Presumpscot Formation at Portland, Maine, uncovered tree remains and other terrestrial organics associated with marine invertebrate shells in a landslide deposit. Buds of Populus balsamifera (balsam poplar) occurred with twigs of Picea glauca (white spruce) in the Presumpscot clay. Tree rings in Picea logs indicate that the trees all died during winter dormancy in the same year. Ring widths show patterns of variation indicating responses to environmental changes. Fossil mosses and insects represent a variety of species and wet to dry microsites. The late-glacial environment at the site was similar to that of today's Maine coast. Radiocarbon ages of 14 tree samples are 11,907 ± 31 to 11,650 ± 50 ¹⁴C yr BP. Wiggle matching of dated tree-ring segments to radiocarbon calibration data sets dates the landslide occurrence at ca. 13,520 + 95/−20 cal yr BP. Ages of shells juxtaposed with the logs are 12,850 ± 65 ¹⁴C yr BP (Mytilus edulis) and 12,800 ± 55 ¹⁴C yr BP (Balanus sp.), indicating a marine reservoir age of about 1000 yr. Using this value to correct previously published radiocarbon ages reduces the discrepancy between the Maine deglaciation chronology and the varve-based chronology elsewhere in New England.     

Arsenic and antimony in geothermal waters of Yellowstone National Park,Wyoming, USA

A total of 268 thermal spring samples were analyzed for total soluble As using reduced molybdenum-blue; 27 of these samples were also analyzed for total Sb using flame atomic absorption spectrometry. At Yellowstone the $\text{Cl}\text{As}$ atomic ratio is nearly constant among neutral-alkaline springs with Cl > 100 mg L^?1, and within restricted geographic areas, indicating no differential effects of adiabatic vs. conductive cooling on arsenic. The $\text{Cl}\text{As}$ ratio increases with silica and decreases with decreasing $\text{Cl}\text{ΣCO}{}_3$; the latter relationship is best exemplified for springs along the extensively sampled SE-NW trend within the Lone Star-Upper-Midway Basin region. The relationship between $\text{Cl}\text{As}$ and $\text{Cl}\text{ΣCO}{}_3$ at Yellowstone suggests a possible rock leaching rather than magmatic origin for much of the Park's total As flux. Condensed vapor springs are low in both As and Cl. Very high $\text{Cl}\text{As}$ ratios ( > 1000) are associated exclusively with highly diluted (Cl < 100 mg L^?1) mixed springs in the Norris and Shoshone Basins and in the Upper White Creek and Firehole Lake areas of Lower Basin. The high ratios are associated with acidity and/or oxygen and iron; they indicate precipitation of As following massive dilution of the Asbearing high-Cl parent water.Yellowstone Sb ranged from 0.009 at Mammoth to 0.166 mg L^?1 at Joseph's Coat Spring. Within basins, the $\text{Cl}\text{Sb}$ ratio increases as the $\text{Cl}\text{ΣCO}{}_3$ ratio decreases, in marked contrast to As. Mixed springs also have elevated $\text{Cl}\text{Sb}$ ratios. White (1967) and Weissberg (1969) previously reported stibnite (Sb₂S₃), but not orpiment (As₂S₃), precipitating in the near surface zone of alkaline geothermal systems.     

Denitrification rates measured along a salinity gradient in the eutrophic Neuse River estuary, North Carolina, USA

Denitrification rates along a salinity gradient in the eutrophic Neuse River Estuary, North Carolina, were quantified using membrane inlet mass spectrometry (MIMS) within short-term batch incubations. Denitrification rates within the system were highly variable, ranging from 0 to 275 μmol N m⁻² h⁻¹. Intrasite variability increased with salinity, but no significant differences were observed across the salinity gradient. Denitrification rates were positively correlated with sediment oxygen demand at the upstream sampling site where sediment organic carbon levels were lowest. This relationship was not observed in the more saline sampling sites. Denitrification rates were highest during winter. On an annual basis, denitrification accounted for 26% of the dissolved inorganic nitrogen and 12% of the total nitrogen supplied to the system.     

Urban stormwater thermal gene expression models for protection of sensitive receiving streams

Thermal impact of typical high‐density residential, industrial, and commercial land uses is a major concern for the health of aquatic life in urban watersheds, especially in smaller, cold, and cool‐water streams. This is the first study of its kind that provides simple easy‐to‐use equations, developed using gene expression programming (GEP) that can guide the assessment and the design of urban stormwater management systems to protect thermally sensitive receiving streams. We developed 3 GEP models using data collected during 3 years (2009–2011) from 4 urban catchments; the first GEP model predicts event mean temperature at the inlet of the pond; the second model predicts the stormwater temperature at the outlet of the pond; and the third model predicts the temperature of the stormwater after flowing through a cooling trench and before discharging to the receiving stream. The new models have high correlation coefficients of 0.90–0.94 and low prediction uncertainty of less than 4% of the median value of the predicted runoff temperatures. Sensitivity analysis shows that climatic factors have the highest influence on the thermal enrichment followed by the catchment characteristics and the key design variables of the stormwater pond and the cooling trench. The general method presented here is easily transferable to other regions of the world (but not necessarily the exact equations developed here); also through sensitivity and parametric analysis, we gained insight on the key factors and their relative importance in modelling thermal enrichment of urban stromwater runoff.     

Model systems for anatexis of pelitic rocks

Subsolidus and melting reactions involving calcic plagioclase in pelitic assemblages in the K-Na-Ca model system occur at higher temperatures than their K-Na counterparts. For the most calcic plagioclase compositions observed in high-grade pelitic rocks (An₂₅-An₄₀) the equilibria are rarely extended by more than 30 ° C above those in KA1O₂-NaAlO₂-Al₂O₃-SiO₂-H₂O, although all discontinuities in facies inferred for the K-Na system are continuously displaced when they involve Ca-bearing plagioclase. The maximum pressure-temperature overlap between muscovite dehydration and initial melting reactions occurs in the pressure range of 4–6 kbar between about 640 ° and 720 ° C. This provides optimum conditions for anatectic melt generation in felsic rocks of the appropriate compositions progressively metamorphosed in kyanite-sillimanite facies series. Progressive regional metamorphism at pressures of 2–4 kbar, corresponding to andalusite-sillimanite facies series, shows little overlap between muscovite dehydration and initial melting reactions. Consequently anatectic melt generation in andalusite-sillimanite facies series would require the participation of biotite in dehydration-melting reactions. Felsic intrusive rock in andalusite-sillimanite terranes could have risen upward from their anatectic sites in high grade kyanite-sillimanite facies series at depth. Many andalusite-sillimanite facies series terranes culminating in migmatites could represent upward movement of kyanite-sillimanite facies series rocks to shallower depths with uplift rates faster than cooling rates.