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151.
Fredric L. Prikle Thomas R. Bement Jo Ann Howell Charles D. Koch Newton K. Stablein Richard J. Beckman Gary L. Tietjen 《Journal of Geochemical Exploration》1983,18(3):175-187
Throughout the aerial radiometric reconnaissance survey portion of the U.S. Department of Energy's National Uranium Resource Evaluation (NURE) program, the identification of outliers (anomalies) was an important approach to locating regions with radio-element concentrations that are either higher or lower than expected. The method introduced herein to locate such regions involves three steps: selection of a high (or low) threshold for the variate of interest; use of the sample percentile to identify all points of interest; and movement of a window over the selected data to locate significant clusters of observations. These steps, applied to aerial radiometric 214Bi (equivalent uranium) data collected over the Copper Mountain area in Wyoming, resulted in the identification of areas enriched in that variate. 相似文献
152.
Charles A. Geiger Edgar Dachs Gilberto Artioli 《Geochimica et cosmochimica acta》2010,74(18):5202-5215
Armenite, ideal formula BaCa2Al6Si9O30·2H2O, and its dehydrated analog BaCa2Al6Si9O30 and epididymite, ideal formula Na2Be2Si6O15·H2O, and its dehydrated analog Na2Be2Si6O15 were studied by low-temperature relaxation calorimetry between 5 and 300 K to determine the heat capacity, Cp, behavior of their confined H2O. Differential thermal analysis and thermogravimetry measurements, FTIR spectroscopy, electron microprobe analysis and powder Rietveld refinements were undertaken to characterize the phases and the local environment around the H2O molecule.The determined structural formula for armenite is Ba0.88(0.01)Ca1.99(0.02)Na0.04(0.01)Al5.89(0.03)Si9.12(0.02)O30·2H2O and for epididymite Na1.88(0.03)K0.05(0.004)Na0.01(0.004)Be2.02(0.008)Si6.00(0.01)O15·H2O. The infrared (IR) spectra give information on the nature of the H2O molecules in the natural phases via their H2O stretching and bending vibrations, which in the case of epididymite only could be assigned. The powder X-ray diffraction data show that armenite and its dehydrated analog have similar structures, whereas in the case of epididymite there are structural differences between the natural and dehydrated phases. This is also reflected in the lattice IR mode behavior, as observed for the natural phases and the H2O-free phases. The standard entropy at 298 K for armenite is S° = 795.7 ± 6.2 J/mol K and its dehydrated analog is S° = 737.0 ± 6.2 J/mol K. For epididymite S° = 425.7 ± 4.1 J/mol K was obtained and its dehydrated analog has S° = 372.5 ± 5.0 J/mol K. The heat capacity and entropy of dehydration at 298 K are Δ = 3.4 J/mol K and ΔSrxn = 319.1 J/mol K and Δ = −14.3 J/mol K and ΔSrxn = 135.7 J/mol K for armenite and epididymite, respectively. The H2O molecules in both phases appear to be ordered. They are held in place via an ion-dipole interaction between the H2O molecule and a Ca cation in the case of armenite and a Na cation in epididymite and through hydrogen-bonding between the H2O molecule and oxygen atoms of the respective silicate frameworks. Of the three different H2O phases ice, liquid water and steam, the Cp behavior of confined H2O in both armenite and epididymite is most similar to that of ice, but there are differences between the two silicates and from the Cp behavior of ice. Hydrogen-bonding behavior and its relation to the entropy of confined H2O at 298 K is analyzed for various microporous silicates.The entropy of confined H2O at 298 K in various silicates increases approximately linearly with increasing average wavenumber of the OH-stretching vibrations. The interpretation is that decreased hydrogen-bonding strength between a H2O molecule and the silicate framework, as well as weak ion-dipole interactions, results in increased entropy of H2O. This results in increased amplitudes of external H2O vibrations, especially translations of the molecule, and they contribute strongly to the entropy of confined H2O at T < 298 K. 相似文献
153.
Pascale?A.?L.?GoertlerEmail author Charles?A.?Simenstad Daniel?L.?Bottom Susan?Hinton Lia?Stamatiou 《Estuaries and Coasts》2016,39(2):542-559
Estuarine rearing has been shown to enhance within watershed biocomplexity and support growth and survival for juvenile salmon (Oncorhynchus sp.). However, less is known about how growth varies across different types of wetland habitats and what explains this variability in growth. We focused on the estuarine habitat use of Columbia River Chinook salmon (Oncorhynchus tshawytscha), which are listed under the Endangered Species Act. We employed a generalized linear model (GLM) to test three hypotheses: (1) juvenile Chinook growth was best explained by temporal factors, (2) habitat, or (3) demographic characteristics, such as stock of origin. This study examined estuarine growth rate, incorporating otolith microstructure, individual assignment to stock of origin, GIS habitat mapping, and diet composition along ~130 km of the upper Columbia River estuary. Juvenile Chinook grew on average 0.23 mm/day in the freshwater tidal estuary. When compared to other studies in the basin our growth estimates from the freshwater tidal estuary were similar to estimates in the brackish estuary, but ~4 times slower than those in the plume and upstream reservoirs. However, previous survival studies elucidated a possible tradeoff between growth and survival in the Columbia River basin. Our GLM analysis found that variation in growth was best explained by habitat and an interaction between fork length and month of capture. Juvenile Chinook salmon captured in backwater channel habitats and later in the summer (mid-summer and late summer/fall subyearlings) grew faster than salmon from other habitats and time periods. These findings present a unique example of the complexity of understanding the influences of the many processes that generate variation in growth rate for juvenile anadromous fish inhabiting estuaries. 相似文献
154.
155.
Stress mobilisation and deformation of a slope are important for engineers to carry out reliable design of retaining systems. However, most case histories reported mainly on the response of pore water pressure (PWP), whereas knowledge about the stress deformation characteristics of slope is limited. In this study, a saprolitic soil slope was instrumented to monitor not only the responses of PWP but also horizontal stress and horizontal displacement. To assist in the interpretation of field data, a series of laboratory tests was conducted to characterise volume change behaviour of the soil taken from the site, under the effects of both net stress and suction. During a rainstorm event when positive PWP built up, a remarkably large displacement of 20 mm was recorded between 5.5- and 6-m depths, and the top 5 m of the slope exhibited translational downslope movement. This caused an increase in Bishop’s effective horizontal stress by 350 %, which reached a peak value close to 40 % of a Bishop’s effective passive stress. During the subsequent dry season when suction was recovered, an upslope rebound of 10 mm was recorded. Comparison of field and laboratory data reveals that the rebound was attributed to suction-induced soil shrinkage. This rebound led to a decrease in the Bishop’s effective horizontal stress previously built up during the storm event. 相似文献
156.
Charles?R.?SternEmail author Julien?M.?Allaz Markus?B.?Raschke G.?Lang?Farmer M.?Alexandra?Skewes Jeremy?T.?Ross 《Contributions to Mineralogy and Petrology》2018,173(8):65
Aplite dikes intruding the Proterozoic 1.42(±?3) Ga Longs Peak-St. Vrain Silver Plume-type peraluminous granite near Jamestown, Colorado, contain F, P, and rare earth element (REE)-rich globular segregations, with 40–46% REE, 3.7–4.8 wt% P2O5, and 5–8 wt% F. A combination of textural features and geochemical data suggest that the aplite and REE-rich globular segregations co-existed as two co-genetic liquids prior to their crystallization, and we propose that they are formed by silicate–fluoride?+?phosphate (+?S?+?CO2) melt immiscibility following ascent, cooling, and decompression of what was initially a single homogeneous magma that intruded the granite. The REE distribution coefficients between the silica-rich aplites and REE-rich segregations are in good agreement with experimentally determined distribution coefficients for immiscible silicate–fluoride?+?phosphate melts. Although monazite-(Ce) and uraninite U–Th–Pb microprobe ages for the segregations yield 1.420(±?25) and 1.442(±?8) Ga, respectively, thus suggesting a co-genetic relationship with their host granite, εNd1.42Ga values for the granites and related granitic pegmatites range from ??3.3 to ??4.7 (average ??3.9), and differ from the values for both the aplites and REE-rich segregations, which range from ??1.0 to ??2.2 (average ??1.6). Furthermore, the granites and pegmatites have (La/Yb)N <50 with significant negative Eu anomalies, which contrast with higher (La/Yb)N >100 and absence of an Eu anomaly in both the aplites and segregations. These data are consistent with the aplite dikes and the REE-rich segregations they contain being co-genetic, but derived from a source different from that of the granite. The higher εNd1.42Ga values for the aplites and REE-rich segregations suggest that the magma from which they separated had a more mafic and deeper, dryer and hotter source in the lower crust or upper mantle compared to the quartzo-feldspathic upper crustal source proposed for the Longs Peak-St. Vrain granite. 相似文献
157.
Gomez-Tuena Arturo; Langmuir Charles H.; Goldstein Steven L.; Straub Susanne M.; Ortega-Gutierrez Fernando 《Journal of Petrology》2007,48(3):537-562
Geochemical studies of Plio-Quaternary volcanic rocks from theValle de BravoZitácuaro volcanic field (VBZ) incentral Mexico indicate that slab melting plays a key role inthe petrogenesis of the Trans-Mexican Volcanic Belt. Rocks fromthe VBZ are typical arc-related high-Mg andesites, but two differentrock suites with distinct trace element patterns and isotopiccompositions erupted concurrently in the area, with a traceelement character that is also distinct from that of other Mexicanvolcanoes. The geochemical differences between the VBZ suitescannot be explained by simple crystal fractionation and/or crustalassimilation of a common primitive magma, but can be reconciledby the participation of different proportions of melts derivedfrom the subducted basalt and sediments interacting with themantle wedge. Sr/Y and Sr/Pb ratios of the VBZ rocks correlateinversely with Pb and Sr isotopic compositions, indicating thatthe Sr and Pb budgets are strongly controlled by melt additionsfrom the subducted slab. In contrast, an inverse correlationbetween Pb(Th)/Nd and 143Nd/144Nd ratios, which extend to lowerisotopic values than those for Pacific mid-ocean ridge basalts,indicates the participation of an enriched mantle wedge thatis similar to the source of Mexican intraplate basalts. In addition,a systematic decrease in middle and heavy rare earth concentrationsand Nb/Ta ratios with increasing SiO2 contents in the VBZ rocksis best explained if these elements are mobilized to some extentin the subduction flux, and suggests that slab partial fusionoccurred under garnet amphibolite-facies conditions. KEY WORDS: arcs; mantle; Mexico; sediment melting; slab melting 相似文献
158.
Landslides - Due to climate change, extreme rainfalls happen more frequently with different patterns. Biochar and plant roots can affect soil water retention curve (SWRC) and hence slope stability.... 相似文献
159.
This study documents the detailed facies and sequence stratigraphic architecture of a multi-cyclic patch-reef and its associated ramp interior facies that formed during Oceanic Anoxic Event 1b in the Mural Limestone, Arizona, USA. Ramp interior facies are comprised of bedded wackestone/packstone, rudist build-up and coral–algal patch-reef facies located north of Bisbee, Arizona, at the Grassy Hill locality. The larger multi-cyclic patch-reef that developed coevally ca 5 km to the south of Grassy Hill consists of a high-angle windward margin with a narrow ca 70 m long reef frame containing vertically zonated Microsolena, Actinastrea, diverse branching coral and rudist assemblages, and an 870 m long low-angle leeward margin comprised of reef debris rudstone and grainstone shoal facies. Similar reef geomorphology and orientation is documented across the Gulf of Mexico and reflects the shelf-wide north to north-east-trending prevailing wind and current energies. Controls affecting reef formation and growth patterns include changes in accommodation space associated with low-amplitude global sea-level rise and regional thermotectonic subsidence, local accommodation space and nutrient fluctuations associated with the inner shelf depositional setting within a humid and siliciclastic-rich environment. Four aggradational to retrogradational high-frequency sequences are documented in Arizona: High-frequency sequences 1 and 2 represent the first pulse of patch-reef development in an overall second-order marine transgression over the Sonora/Bisbee Shelf. These sequences correlate to δ13C signatures associated with Oceanic Anoxic Event 1b across the Gulf of Mexico and suggest that carbonate reefs persisted on the ramp interior during this time. High-frequency sequences 3 and 4 record a second brief transgression and backstepping of reef facies followed by the final regression of shallow shelf carbonates that correlates to more robust patch-reef development in Sonora, Mexico. The patch-reef at Paul Spur is an excellent outcrop analogue for productive patch-reefs in the Maverick Basin (Comanche Shelf) of Texas. Detailed facies mapping of this outcrop analogue shows that the greatest reservoir potential is contained within the backreef grainstone shoals where primary porosity of up to 15% is observed. 相似文献
160.
Suraj Dhungana Charles R. Anthony III Larry E. Hersman 《Geochimica et cosmochimica acta》2007,71(23):5651-5660
Pyridine-2,6-bis(monothiocarboxylate) (pdtc), a metabolic product of microorganisms, including Pseudomonas putida and Pseudomonas stutzeri was investigated for its ability of dissolve Fe(III)(hydr)oxides at pH 7.5. Concentration dependent dissolution of ferrihydrite under anaerobic environment showed saturation of the dissolution rate at the higher concentration of pdtc. The surface controlled ferrihydrite dissolution rate was determined to be 1.2 × 10−6 mol m−2 h−1. Anaerobic dissolution of ferrihydrite by pyridine-2,6-dicarboxylic acid or dipicolinic acid (dpa), a hydrolysis product of pdtc, was investigated to study the mechanism(s) involved in the pdtc facilitated ferrihydrite dissolution. These studies suggest that pdtc dissolved ferrihydrite using a reduction step, where dpa chelates the Fe reduced by a second hydrolysis product, H2S. Dpa facilitated dissolution of ferrihydrite showed very small increase in the Fe dissolution when the concentration of external reductant, ascorbate, was doubled, suggesting the surface dynamics being dominated by the interactions between dpa and ferrihydrite. Greater than stoichiometric amounts of Fe were mobilized during dpa dissolution of ferrihydrite assisted by ascorbate and cysteine. This is attributed to the catalytic dissolution of Fe(III)(hydr)oxides by the in situ generated Fe(II) in the presence of a complex former, dpa. 相似文献