Mudrocks from the Siberian Hypostratotype of the Riphean and Vendian: Chemistry,Sm–Nd Isotope Systematics of Sources,and Formation Stages

Lithology and Mineral Resources - The chemical composition and Nd isotope systematics were obtained for mudrocks (mudstones) from sections of the Siberian hypostratotype of the Riphean and Vendian...     

Experimental study on reduction of U (Ⅵ) by an anaerobic bacterium, Shewanella putrefaciens: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits, China

An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores.     

Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...     

Cloud measurements on day 245 of gate

Abstract

On day 245 of GATE (2 September 1974) two lines of convection ‐ north (N) and south (S) ‐ were studied by aircraft stacked vertically, patrolling a north‐south line at longitude 22.85° W of length about 200 km. These lines were part of a complex of convection related to an easterly wave. Photogrammetry shows that the northern line consisted at first of a dense aggregate of small clouds, of width roughly 50 m at cloud base. There were a few tall clouds. No line organization was apparent from the aircraft at 1208 GMT. Fifteen minutes later there was line organization, readily apparent from the DC‐6 aircraft. From study of Electra and DC‐6 records, it appears that a vigorous cold northeasterly surface current initiated line N, and that this was a downdraft originating at altitude about 2.5 km in a mesoscale cloud feature to the north. It appears further that penetrative convection to 14 km followed after the first rain, which moistened air near the surface, and thus lowered cloud bases from about 500 to 350 m.

In overhangs of cloud, anvils to the north of line S, active cloud towers only about 2 km wide were found. The anvils were roughly 2 km thick. Patterns of clouds corresponded to a profile of A/B‐scale divergence; active towers at low levels corresponded to convergence up to the 60 kPa level, and stratus coincided with A/B‐scale divergence aloft at about 50 and 26 kPa.

Statistical analyses from the aircraft films indicated that the area covered by clouds of dark base ‐ signifying concentrated updrafts ‐ was ～5%, much less than that covered by rain at cloud base, ～ 18%. Cloud cover at altitude 4 km was ～ 10%.     

Possible representation for discovery observations of stellar flares

It is shown that the chronology of flare star discoveries in the Pleiades cluster and the Orion association can be described satisfactorily by various distribution functions (gamma, binomial, decreasing exponential, and delta) for the mean frequencies of stellar flares. However, it has been found that this is due to the uncertainty in the observationally derived distribution function for the mean frequency of stellar flares. The most likely function is that derived by Ambartsumian, which has a physical basis.Translated fromAstrofizika, Vol. 38, No. 1, pp. 25–32, January–March, 1995.