THREE-WAY METHODS FOR THE CALIBRATION OF CHROMATOGRAPHIC SYSTEMS:COMPARING PARAFAC AND THREE-WAY PLS

For the calibration of chromatographic systems,different methods can be used.One class of methodsutilizes three-way approaches.The calibration problem is stated in such a way that the decompositionof a three-way array can serve for the prediction of retention on new stationary phases.Two three-way approaches are presented:the Unfold-PCA and PARAFAC models.The theory ofboth methods is presented and the differences are highlighted,the main difference being that PARAFACis a trilinear decomposition whereas Unfold-PCA is not.Both three-way methods are evaluated on asmall data set consisting of retention measurements of eight solutes at six mobile phase compositions onsix stationary phases.The differences in performance of the two models are minor,For calibration purposes,two variants of the methods are discussed:three-way PLS and an extensionof PARAFAC.Again the theory and differences between the two methods are explained.The predictiveperformance of the two methods is compared using the same data set as earlier.The differences inpredictive performance,however,are minor.Both methods are capable of predicting 98% of thevariation in the test sets.Yet,there are other considerations when comparing methods than predictiveperformance,e.g.the quality of the predictions.     

The development of three-dimensional current system during a magnetospheric substorm

It is suggested that the pattern of three-dimensional substorm current circuit varies significantly even during the lifetime of a single substorm. This gives rise to quite complex time variations of the magnetic field at low latitude stations even for relatively isolated substorms. To verify this, three-dimensional current models with time dependent spatial variations are used to simulate one type of complex low-latitude “substorm signature”. It is shown that the utmost care should be exercised in determining different substorm phases on the basis of such a signature. The results indicate also that, in certain longitudes in the evening sector, one should expect distinct differences in characteristics between positive bays observed on the ground and at the synchronous distance.     

Estimation of sedimentary thickness in the Godavari basin

A major portion of the southern part of the Indian subcontinent is classified as a stable continental region. However, a few segments in this region are punctuated by rifts and shear zones that are seismically active. The Godavari rift that sutures the eastern Dharwar and the Bastar cratons is one such region, prone to seismic hazard. Estimation of the sedimentary thickness in these seismically active regions assumes importance since locales of thick and soft sediments are vulnerable to destruction due to surface waves generated by earthquakes. In the present study, data from five broadband seismological stations are utilized to estimate the average sedimentary thickness of the Godavari region using the difference in travel times of the direct S and converted Sp phases from local earthquakes. The thickness of sediments varies between 0.32 and 4.32 km. Also, the site-specific response in terms of the fundamental resonance frequency and the corresponding amplifications are estimated using the well-established Nakamura technique. The predominant frequencies are in the range of 1.3–4.61 Hz, and the amplifications are higher (>1.5) for the stations inside the Godavari basin. Both the thickness and amplification values clearly indicate that the sediments tend to get thicker toward the center of the basin, in good agreement with the geological distribution of the sedimentary units.     

The Impact of Canyon Geometry on Intra Urban and Urban: Suburban Night Temperature Differences Under Warm Weather Conditions

The present paper investigates the impact of canyon geometry on the temperature regime and nocturnal heat island development in the very dense urban area of Athens, Greece. Detailed measurements of air temperature have been carried out within three deep urban canyons of different aspect ratios (H/W = 3, 2.1 and 1.7) during the night period of the summer and autumn of 2007. An analysis was carried out to investigate the relative impact of the canyon geometry, the undisturbed wind velocity, ambient temperature, and cloud cover on the development of a nocturnal heat island. A clear increase of the median, maximum and minimum values of the cooling rates has been observed for decreasing aspect ratios. Under low ambient temperatures, high wind speeds correspond to a substantial rise of the cooling rate in the urban canyons mainly because of the increased convective losses. On the contrary, cooling rates decrease substantially under high-undisturbed wind speeds and ambient temperatures because of the important convective gains. The impact of cloud cover was found to be important as cloudy skies cause a substantial decrease of the cooling rates in the urban canyons. Comparisons were performed between the temperature data collected in the three studied urban canyons and temperatures recorded in an urban as well as a suburban open space station.     

Soil bentonite wall protects foundation from thrust faulting: analyses and experiment

When seismic thrust faults emerge on the ground surface,they are particularly damaging to buildings,bridges and lifelines that lie on the rupture path.To protect a structure founded on a rigid raft,a thick diaphragm-type soil bentonite wall(SBW) is installed in front of and near the foundation,at sufficient depth to intercept the propagating fault rupture.Extensive numerical analyses,verified against reduced–scale(1 g) split box physical model tests,reveal that such a wall,thanks to its high deformability and low shear resistance,"absorbs" the compressive thrust of the fault and forces the rupture to deviate upwards along its length.As a consequence,the foundation is left essentially intact.The effectiveness of SBW is demonstrated to depend on the exact location of the emerging fault and the magnitude of the fault offset.When the latter is large,the unprotected foundation experiences intolerable rigid-body rotation even if the foundation structural distress is not substantial.     

Anisotropy beneath Hawaii from surface wave particle motion observations

Observed polarization ellipses for fundamental-mode surface waves observed at a digital station in Hawaii deviate from those expected for isotropic models of crust and mantle structure for that region. The anomalous motion occurs as rotations of the ellipse about all three axes in a cartesian corrdinate system. The largest and most consistent deviations occur as anomalous slopes of the ellipse about the horizontal axis transverse to the direction of propagation.The observed orientations and magnitudes of these angles can be explained by models of the upper mantle which contain olivine for which thea-axis dips significantly from the horizontal and which includes a sufficiently thick sedimentary layer (1 km) and a thicker than normal oceanic crust (15 km). The ellipses are also generally inclined from great circle paths about the vertical axis and are tilted about the axis aligned with the propagation direction. Both angles are small and difficult to measure, but the inclination angles are consistent with a model of the upper mantle in which thea-axis of olivine is preferentially oriented in an east-west direction.     

The motion of an emission-line region near the center of the galaxy NGC 4151

Possible orbits for the motion of a region in the gravitational field of the central body of the galaxy NGC 4151 are presented. The region is manifest through its line emission, observed in the red wing of the Hα, Pβ, and other broad lines. We carried out a computer selection of all Keplerian orbits for which the measured radial velocities of the emission-line region could be observed. We used radial-velocity data obtained by us at the Fesenkov Astrophysical Institute, as well as data from the literature. The computation results can be used to determine the mass range for the central body of NGC 4151 that provides the best agreement with the observational data: (61–65)× 10⁶ M _⊙. Suitably designed monitoring of active galactic nuclei can be used to verify these results, and to carry out similar analyses for other Seyfert galaxies.     

Bericht über die Tagung der Meteorologischen Gesellschaft bad Kissingen vom 1. bis 3. Oktober 1949

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