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11.
Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.  相似文献   
12.
This study documents the detailed facies and sequence stratigraphic architecture of a multi-cyclic patch-reef and its associated ramp interior facies that formed during Oceanic Anoxic Event 1b in the Mural Limestone, Arizona, USA. Ramp interior facies are comprised of bedded wackestone/packstone, rudist build-up and coral–algal patch-reef facies located north of Bisbee, Arizona, at the Grassy Hill locality. The larger multi-cyclic patch-reef that developed coevally ca 5 km to the south of Grassy Hill consists of a high-angle windward margin with a narrow ca 70 m long reef frame containing vertically zonated MicrosolenaActinastrea, diverse branching coral and rudist assemblages, and an 870 m long low-angle leeward margin comprised of reef debris rudstone and grainstone shoal facies. Similar reef geomorphology and orientation is documented across the Gulf of Mexico and reflects the shelf-wide north to north-east-trending prevailing wind and current energies. Controls affecting reef formation and growth patterns include changes in accommodation space associated with low-amplitude global sea-level rise and regional thermotectonic subsidence, local accommodation space and nutrient fluctuations associated with the inner shelf depositional setting within a humid and siliciclastic-rich environment. Four aggradational to retrogradational high-frequency sequences are documented in Arizona: High-frequency sequences 1 and 2 represent the first pulse of patch-reef development in an overall second-order marine transgression over the Sonora/Bisbee Shelf. These sequences correlate to δ13C signatures associated with Oceanic Anoxic Event 1b across the Gulf of Mexico and suggest that carbonate reefs persisted on the ramp interior during this time. High-frequency sequences 3 and 4 record a second brief transgression and backstepping of reef facies followed by the final regression of shallow shelf carbonates that correlates to more robust patch-reef development in Sonora, Mexico. The patch-reef at Paul Spur is an excellent outcrop analogue for productive patch-reefs in the Maverick Basin (Comanche Shelf) of Texas. Detailed facies mapping of this outcrop analogue shows that the greatest reservoir potential is contained within the backreef grainstone shoals where primary porosity of up to 15% is observed.  相似文献   
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本文报导了应用纤维素乙酸平板电泳方法,测定采于中国山东省东方红盐场卤虫(Artemia)的同功酶。经测定,8种同功酶其中有6种是多态的,即:苹果酸脱氢酶(MDH)、异柠檬酸酶(IDH)、谷氨酸草醋酸转移酶(GOT)、葡糖-6-磷酸盐脱氢酶(D6PHD)、6-磷酸萄糖脱氢酶(6PGDH)和磷酸葡糖异构酶(PGI)。本文所提供的研究方法,不仅适用于基础研究,而且在水产养殖业上有助于对卤虫的筛选和确证。  相似文献   
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ABSTRACT

Sir Charles Cotton (1964) has pointed out that in an earlier paper (Carlston, 1963) which related drainage density to hydrology, there was insufficient emphasis on the role of climate in its effect on drainage density. Re-examination of the relation of drainage density to base flow in the 15 basins originally described has revealed additional evidence that base flow is affected by precipitation or recharge (a climatic variable), while varying inversely with drainage density.

Within the climatic region studied in the earlier paper (the Humid Subtropical Climate of the eastern U. S.), no evidence could be found that amount or intensity of rainfall affected the intensity of flood runoff or the scale of drainage density. In comparison with other climates, however, such as the Marine West Coast Climate, it is possible that the less intense precipitation of a marine climate may result in lower runoff intensities and lower drainage densities, however the lower mean temperatures of such climates may develop soils of generally higher infiltration capacity which would produce lower drainage densities.

A progressive increase in aridity results in a decrease in soil and vegetal cover which greatly magnifies the range of drainage densities characteristic of semi-arid regions. In such regions, where the land sur-face has a good infiltration capacity rainfall sinks readily into the dry soil (although recharge to ground water may be negligible), and runoff is virtually zero, as is drainage density, Impermeable terranes devoid of vegetal and soil cover reject the rain, runoff is briefly total and drainage density may be greatly magnified, as in the South Dakota Badlands, where drainage density runs into the hundreds. Arid or Desert Climates should produce erosional landforms with generally high drainage densities, though not reaching the magnitudes of drainage density found in the semi-arid badlands where rainfall intensities are much higher.  相似文献   
17.
Lake Jilantai-Hetao, a megalake, was formed some time before 60–50 ka, along the Great North Bend of the Yellow River. The basin is now dry, with most of the area covered by aeolian sand. We are investigating this profound hydrologic change using a number of research approaches. Paleoshorelines of this megalake are best preserved in the Jilantai area in the southwestern portion of the megalake basin. We collected aquatic mollusk shells from littoral sediments at different altitudes around Jilantai and measured their strontium isotope compositions. 87Sr/86Sr ratios in shell carbonates are different between the high lake phase (~1,080–1,050 m altitude) and the low lake phase (~1,044–1,030 m altitude), with a small shift in average strontium ratios to more radiogenic values during the low lake phase. Based on regional hydrology and physical geography, we conclude that water from the Yellow River was the dominant water source supplying this megalake. 87Sr/86Sr ratios of modern water samples suggest the Yellow River was the dominant water source during the high lake phase, but that the relative contribution of Yellow River water to the megalake was reduced, and that the relative contributions of local precipitation and groundwater increased, during the low lake phase.  相似文献   
18.
Six sulfur forms were investigated in profiles of freshwater- and marine-derived peat-forming systems of the Okefenokee Swamp, Georgia and Everglades Swamp, Florida. Total sulfur levels of 0.1–10% were found, thus indicating a major incorporation of sulfur in the very early stages of coal formation. The quantities of hydrogen sulfide and elemental sulfur observed appeared to be indicative of whether marine or freshwater conditions prevailed at the site of deposition. Carbon-bonded sulfur accounted for 70% of the total sulfur in the freshwater peat and 50% of the total sulfur in the marine peat. Over 15% of the total sulfur was in pyritic combination in the marine environment, while levels of pyrite in the freshwater peats were an order of magnitude lower. An ester-sulfate fraction represented 25% of the total sulfur in both freshwater and marine peats. The levels of sulfur forms in the peat profiles are compared to those observed in living plants and to various coals; levels of pyrite and organic sulfur in the peat are similar to those found by other investigators in freshwater-derived and marine-derived coals.  相似文献   
19.
Twenty-two dark inclusions (DIs) from Allende (18), Leoville (2), Vigarano (1) and Efremovka (1) were studied by the I-Xe method. All except two of these DIs (Vigarano 2226 and Leoville LV2) produce well-defined isochrons, and precise I-Xe ages. The Allende DIs formed a tight group about 1.6 Ma older than Shallowater (4.566 ± 0.002 Ga), about 5 Ma older than four previously studied Allende CAIs. Most of the dark inclusions require trapped Xe with less 129Xe (or more 128Xe) than conventional planetary Xe (well restricted in composition by Q-Xe or OC-Xe). Studies of an irradiated/unirradiated DI pair from Allende demonstrate that the 128Xe/132Xe ratio in trapped is normal planetary, so that a 129Xe/132Xe ratio below planetary seems to be required. Yet, this is not possible given constraints on 129Xe evolution in the early solar system. Trends among all of the Allende DIs suggest that an intimate mixture of partially decayed iodine and Xe formed a pseudo trapped Xe component enriched in both 129Xe and 127I, and subsequently in 128Xe after n-capture during reactor irradiation. Enrichment in radiogenic 129Xe, but with a 129Xe/127I ratio less than that observed in the iodine host phase, places closure of this trapped mixture ≥13 Ma after precipitation of the major iodine-bearing phase. Because the I-Xe isochron is a mixing line between iodine-derived and trapped Xe (pseudo or not), I-Xe ages, given by the slope of this mixing line, are not compromised by the presence of pseudo trapped Xe, and the precision of the I-Xe ages is given by the statistics of the line fit.  相似文献   
20.
A field demonstration was performed to evaluate the impacts of bioaugmentation dosage for treatment of chlorinated ethenes in a sandy-to-silty shallow aquifer. Specifically, bioaugmentation using a commercially available Dehalococcoides (DHC)-containing culture was performed in three separate groundwater recirculation loops, with one loop bioaugmented with 3.9 × 1011 DHC, the second loop bioaugmented with 3.9 × 1012 DHC, and the third loop bioaugmented with 3.9 × 1013 DHC. Groundwater monitoring was performed to evaluate DHC growth and migration, dechlorination rates, and aquifer geochemistry. The loop inoculated with 3.9 × 1012 DHC showed slower dechlorination rates and DHC migration/growth compared with the other loops. This relatively poor performance was attributed to low pH conditions. Results for the loops inoculated with 3.9 × 1011 and 3.9 × 1013 DHC showed similar timeframes for dechlorination, as evaluated at a monitoring well approximately 10 feet downgradient of the DHC injection well. Application of a recently developed one-dimensional bioaugmentation fate and transport screening model provided a reasonable prediction of the data in these two loops. Overall, these results suggest that increasing bioaugmentation dosage does not necessarily result in decreased dechlorination timeframes in the field. The ability to predict results suggests that modeling potentially can serve as an effective tool for determining bioaugmentation dosage and predicting overall remedial timeframes.  相似文献   
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