Carbon and oxygen isotopes of Maastrichtian–Danian shallow marine carbonates: Yacoraite Formation, northwestern Argentina

The Maastrichtian–Danian limestones of the Yacoraite Formation (northwestern Argentina) show carbon and oxygen isotopic values consistent with shallow marine conditions. The members of the formation respond to different sedimentary environments and are characterised by distinctive stable isotopes and geochemistry. The basal Amblayo Member is composed of high-energy dolomitic limestones and limestones with positive isotopic values (+2‰ δ¹³C, +2‰ δ¹⁸O). The top of the member reveals an isotopic shift of δ¹³C (−5‰) and δ¹⁸O (−10‰), probably related to a descent in the sea level. The sandy Güemes Member has isotopically negative (−2‰ δ¹³C, −1‰ δ¹⁸O) limestones, principally controlled by water mixing, decreased organic productivity, and compositional changes in the carbonates. The isotopically lighter limestones are calcitic, with a greater terrigenous contribution and different geochemical composition (high Si–Mn–Fe–Na, low Ca–Mg–Sr). These isotopic and lithological changes relate to the Cretaceous–Palaeogene transition. The Alemanía Member, composed of dolomitic limestones and pelites, represents a return to marine conditions and shows a gradual increase in isotopic values, reaching values similar to those of the Amblayo Member. The Juramento Member, composed of stromatolite limestones, shows isotopic variations that can be correlated with the two well-defined, shallowing-upward sequences of the member.     

The Mediterranean intercalibration exercise on soft‐bottom benthic invertebrates with special emphasis on the Italian situation

The intercalibration exercise is an important step in the building process of the surface water ecological quality assessment, which is required by the Water Framework Directive (WFD). Its aim is to apply the water quality classification in a uniform manner to all the Member States belonging to the same eco‐region. Cyprus, France, Greece, Italy, Slovenia and Spain participated in the soft‐bottom benthic invertebrate subgroup for the Mediterranean coastal region. The methodologies proposed by Member States were applied and tested; the results were compared and harmonized to establish agreed and comparable boundaries for the benthic invertebrate ecological status classes. The national methods used in the intercalibration process were: for Cyprus and Greece, the Bentix Index; for Slovenia, a combination of AZTI Marine Biotic Index (AMBI), richness and diversity with the use of factor and discriminant analysis (Multimetric AMBI); for Spain, a new index, named MEDOCC, which is an adaptation of the AMBI index to the Western Mediterranean area. Italy and France tested different methods, none of which have been officially adopted. Final class boundary values for the different official classification systems were obtained and compared. Besides describing methods and results obtained by the different countries, the Italian situation is examined in more detail. All the above methods have been applied to Italian data, but the results were not conclusive. Major causes for concern are related to insufficient sites and data, to the lack of real non‐impacted reference sites, and to the difficulties in validating the ecological status classification in sites not showing a pollution gradient.     

On the dimensioning of viscous dampers for the mitigation of the earthquake-induced effects in moment-resisting frame structures

The effectiveness of viscous dampers in mitigating the seismic excitation impacts upon building structures has been widely proved. Recently, with reference to the specific case of equal mass, equal stiffness, shear-type structures, the authors developed a direct practical procedure which gives the mechanical characteristics of the manufactured viscous dampers capable of providing the frame structure with a prescribed value of the first damping ratio. In this paper, a comprehensive rational framework is presented, which allows to formally extend the validity of the proposed procedure to the more realistic case of a generic moment-resisting frame structure. Also the influence of various lateral stiffness distributions is investigated.     

The influence of the 3D morphology and cavity network on the seismic response of Castelnuovo hill to the 2009 Abruzzo earthquake

During the Abruzzo earthquake (6.IV.2009, M_W = 6.3), the village of Castelnuovo, lying on an elliptical hill about 60 m high, underwent an intensive damage (I_MCS = 9–10), that could be partly ascribed to the topographic amplification and to the presence of an underground cavity network. To verify these hypotheses, the seismic response of the hill was carefully investigated adopting both 2D and 3D finite difference numerical models. Analyses were carried out using a detailed geotechnical model, defined on the basis of a comprehensive field investigation (boreholes, DH, HVSR, ERT) and accurate laboratory tests (RC-TS). The reference input motion was reproduced considering the time history of the mainshock recorded at an accelerometric station close to the epicenter, conveniently deconvoluted to the bedrock and scaled in amplitude to the site of Castelnuovo. The results of the numerical analyses, expressed in terms of distribution of the amplification factor of peak acceleration and Housner intensity, proved that the topographic effects significantly influenced the ground motion at surface, whereas the role of cavities seemed to be negligible.     

Force reduction factor for building structures equipped with added viscous dampers

This research work focuses on the analysis of the hysteretic seismic behaviour of inelastic SDOF systems equipped with viscous dampers. In detail, it is aimed at obtaining a practical tool useful for the seismic design of building structures with added dampers, within the framework of the traditional seismic design based on ductility. The objective is to evaluate the appropriate force reduction factor for highly damped (i.e. damping ratio greater than 5 %) SDOF systems able to guarantee a prescribed level of structural safety.     

PCBs and chlorinated pesticides in the atmosphere and aquatic organisms of Ross Island, Antarctica

PCBs, p,p′-DDT, p,p′-DDE and lindane (γ-hexachlorocyclohexane) were monitored in the lower atmosphere of Ross Island, in Antarctica for 2 yr. Geometrical means were 15.2 pg m⁻³ for PCBs, 2.0 pg m⁻³ for p,p′-DDT, 1.0 pg m⁻³ for p,p′-DDE and 25.8 pg m⁻³ for lindane. Atmospheric levels of lindane were positively correlated with temperature, and a significant difference was found between spring-summer and summer-winter concentrations. No season related differences were found for the other chlorinated hydrocarbons, possibly owing to their lower vapour pressure and the cold climate. Periods with increased atmospheric levels of PCBs and DDT compounds were recorded. Lindane, p,p′-DDE and PCBs were present in fish and zooplankton sampled close to Ross Island. Pollutant levels in the zooplankton (on an extractable fat basis) were highest during the Antarctic spring and autumn and were inversely correlated to their fat content.     

Melting and cataclastic features in shatter cones in basalt from the Vista Alegre impact structure,Brazil

Shatter cones are one of the most widely recognized pieces of evidence for meteorite impact events on Earth, but the process responsible for their formation is still debated. Evidence of melting on shatter cone surfaces has been rarely reported in the literature from terrestrial impact craters but has been recently observed in impact experiments. Although several models for shatter cones formation have been proposed, so far, no one can explain all the observed features. Shatter cones' from the Vista Alegre impact structure, Brazil, formed in fine‐grained basalt of the Jurassic‐Cretaceous Serra Geral Formation (Paraná large igneous province). A continuous quenched melt film, consisting of a crystalline phase, mica, and amorphous material, decorates the striated surface. Ultracataclasites, containing subrounded pyroxene clasts in an ultrafine‐grained matrix, occur subparallel to the striated surface. Several techniques were applied to characterize the crystalline phase in the melt, including Raman spectroscopy and transmission electron microscopy. Results are not consistent with any known mineral, but they do suggest a possible rare or new type of clinopyroxene. This peculiar evidence of melting and cataclasis in relation with shatter cone surfaces is interpreted as the result of tensile fracturing at the tip of a fast propagating shock‐induced rupture, which led to the formation of shatter cones at the tail of the shock front, likely during the early stage of the impact events.