Conceptual models for carbonate aquifers. 1969

The very diverse types of ground‐water behavior in carbonate terrains can be classified by relating the flow type to a particular hydrogeologic environment each exhibiting a characteristic cave morphology. The ground water may move by diffuse flow, by retarded flow, or by free flow. Diffuse flow occurs in less soluble rocks such as extremely shaley limestones or crystalline dolomites. Integrated conduits are rare. Caves tend to be small, irregular, and often little more than solutionally widened joints. Retarded flows occur in artesian environments and in situations where unfavorable stratigraphy forces ground water to be confined to relatively thin beds. Network cave patterns are characteristic since hydrodynamic forces are damped by the external controls. Solution occurs along many available joints. Free flowing aquifers are those in which solution has developed a subsurface drainage system logically regarded as an underground extension of surface streams. These streams may have fully developed surface tributaries as well as recharge from sinkholes and general infiltration. Characteristic cave patterns are those of integrated conduit systems which are often truncated into linear, angulate, and branchwork caves. Free Flow aquifers may be further subdivided into Open aquifers lying beneath karst plains and Capped aquifers in which significant parts of the drainage net lie beneath an insoluble cap rock. Other geologic factors such as structure, detailed lithology, relief, and locations of major streams, control the details of cave morphology and orientation of the drainage network.     

Performance assessment of three convective parameterization schemes in WRF for downscaling summer rainfall over South Africa

Austral summer rainfall over the period 1991/1992 to 2010/2011 was dynamically downscaled by the weather research and forecasting (WRF) model at 9 km resolution for South Africa. Lateral boundary conditions for WRF were provided from the European Centre for medium-range weather (ECMWF) reanalysis (ERA) interim data. The model biases for the rainfall were evaluated over the South Africa as a whole and its nine provinces separately by employing three different convective parameterization schemes, namely the (1) Kain–Fritsch (KF), (2) Betts–Miller–Janjic (BMJ) and (3) Grell–Devenyi ensemble (GDE) schemes. All three schemes have generated positive rainfall biases over South Africa, with the KF scheme producing the largest biases and mean absolute errors. Only the BMJ scheme could reproduce the intensity of rainfall anomalies, and also exhibited the highest correlation with observed interannual summer rainfall variability. In the KF scheme, a significantly high amount of moisture was transported from the tropics into South Africa. The vertical thermodynamic profiles show that the KF scheme has caused low level moisture convergence, due to the highly unstable atmosphere, and hence contributed to the widespread positive biases of rainfall. The negative bias in moisture, along with a stable atmosphere and negative biases of vertical velocity simulated by the GDE scheme resulted in negative rainfall biases, especially over the Limpopo Province. In terms of rain rate, the KF scheme generated the lowest number of low rain rates and the maximum number of moderate to high rain rates associated with more convective unstable environment. KF and GDE schemes overestimated the convective rain and underestimated the stratiform rain. However, the simulated convective and stratiform rain with BMJ scheme is in more agreement with the observations. This study also documents the performance of regional model in downscaling the large scale climate mode such as El Niño Southern Oscillation (ENSO) and subtropical dipole modes. The correlations between the simulated area averaged rainfalls over South Africa and Nino3.4 index were ?0.66, ?0.69 and ?0.49 with KF, BMJ and GDE scheme respectively as compared to the observed correlation of ?0.57. The model could reproduce the observed ENSO-South Africa rainfall relationship and could successfully simulate three wet (dry) years that are associated with La Niña (El Niño) and the BMJ scheme is closest to the observed variability. Also, the model showed good skill in simulating the excess rainfall over South Africa that is associated with positive subtropical Indian Ocean Dipole for the DJF season 2005/2006.     

Spectroscopic Characterization of Organic Structures and Organic‐Inorganic Interactions in Paper Mill Sludge

The organic composition and organic‐inorganic interaction in paper mill sludge (PS) solvent extracts (hexane, ethyl acetate, acetone and ethanol) and humic fractions, humic acid (HA) and humin (HU) were studied by electron paramagnetic resonance spectroscopy (EPR), proton and carbon‐13 nuclear magnetic resonance spectroscopy (¹H NMR; ¹³C NMR), Fourier‐transformed infrared spectroscopy (FTIR), and ultraviolet‐visible spectroscopy (UV‐vis). The strategy of fractionating the PS, sequentially, with organic solvents of increasing polarity is a reliable analytical procedure for humic substance sample separation because it results in more purified fractions. FTIR, ¹H NMR and ¹³C NMR results showed that hexane extract consisted mainly of aliphatic hydrocarbon structures. Their contents in the extracts decreased as the polarity of the extracting solvent increased and the content of oxygen functional groups increased. Carboxylic and carboxylate functional groups were found in the acetone extract, and ester and ether functions were predominantly found in the ethanol extract. EPR spectra revealed some Fe³⁺ complexes with rhombic structure (g₁ = 4.3; g₂ = 9.0) in the humic fractions and in all solvent extracts, except hexane. Quasi‐octahedral Fe³⁺ complexes (g = 2.3; ΔH_pp ≤ 400 G) were found in the HU fraction and in the acetone extract. The organic free radical content in the HA fraction was higher than the non‐fractionated PS sample and HU fraction.     

Rockfalls and rockfall inventory data: Some observations from surprise valley,Jasper National Park,Canada

The major controls of rockfall activity are divided into two interacting groups. (a)Climatic factors which, through their control of temperatures and the availability and state of water, are primary controls of rockfall trigger mechanisms. (b) Geologic factors which, via cliff form (plan, profile, dissection etc.) and the character and availability of materials, influence the type, spatial distribution and intensity of rockfall activity. Detailed examination of these controls suggest that both seasonal and daily patterns of rockfall activity can vary markedly over a very small area. The implications of this variability for the design and interpretation of rockfall inventories are discussed using sample data from Surprise Valley, Jasper National Park, for the period from May-October 1969. On a seasonal basis rockfall activity showed a major spring peak with secondary maxima in the fall and associated with major summer storms. Two sites of differing aspect and morphology were studied in more detail revealing marked differences in the mean hourly frequency (0·94:0·20), mean hourly probability (0·40:0·16, hours with rockfall/hours observed) and daily pattern of rockfall activity. The west facing site showed equal hourly probability of rockfalls from 10⁰⁰ to 20⁰⁰ hr whereas the east facing slope had a greater hourly probability when it was in the sun (11⁰⁰ 14⁰⁰hr) than in the shade (14⁰⁰-19⁰⁰hr). The differences in rockfall frequency and probabilities reflect the physical characteristics of the individual sites whereas the daily pattern of rockfalls is related to microclimate. These results suggest that if future inventory studies are to make a significant contribution, they must be carefully designed field experiments in which. (i) Data are restricted to the study or comparison of single continuously observed sites. (ii) Study sites and/or data periods are carefully selected to isolate and investigate specific controls e.g. the influence of cliff form, aspect, periods of rainfall etc. on rockfall patterns. (iii) Good on-site microclimate data are available. Also comparison of frequency measures based on the arithmetic mean should be avoided since the distribution of rockfalls per hour closely follows a Poisson distribution with occasional high values which unduly influence the value of the arithmetic mean. It is suggested that rockfall probabilities, based on the binary decision of whether or not a rockfall occurs in a given period, are a more useful measure for daily patterns of rockfall activity.     

Aerodynamic Parameters of a UK City Derived from Morphological Data

Detailed three-dimensional building data and a morphometric model are used to estimate the aerodynamic roughness length z ₀ and displacement height d over a major UK city (Leeds). Firstly, using an adaptive grid, the city is divided into neighbourhood regions that are each of a relatively consistent geometry throughout. Secondly, for each neighbourhood, a number of geometric parameters are calculated. Finally, these are used as input into a morphometric model that considers the influence of height variability to predict aerodynamic roughness length and displacement height. Predictions are compared with estimations made using standard tables of aerodynamic parameters. The comparison suggests that the accuracy of plan-area-density based tables is likely to be limited, and that height-based tables of aerodynamic parameters may be more accurate for UK cities. The displacement heights in the standard tables are shown to be lower than the current predictions. The importance of geometric details in determining z ₀ and d is then explored. Height variability is observed to greatly increase the predicted values. However, building footprint shape only has a significant influence upon the predictions when height variability is not considered. Finally, we develop simple relations to quantify the influence of height variation upon predicted z ₀ and d via the standard deviation of building heights. The difference in these predictions compared to the more complex approach highlights the importance of considering the specific shape of the building-height distributions. Collectively, these results suggest that to accurately predict aerodynamic parameters of real urban areas, height variability must be considered in detail, but it may be acceptable to make simple assumptions about building layout and footprint shape.     

Fractionation analysis of transport engine-generated soot particles with respect to hygroscopicity

Combustion-derived particles emitted by various transport engines are analyzed with respect to their morphology and composition. Soot particles collected behind an aircraft gas turbine engine combustor, in the diesel engine exhaust pipe, and at the end of ship pipe demonstrate heterogeneous morphological structures and different chemical identities. Individual particle analysis allows the characterization of emitted soot particles into three fractions, namely C-O, C-O-S, and Fe-C-O, with the dominant presence of chain soot agglomerates, irregular internally mixed soot, and particles of distinct morphology, respectively. The influence of oxygen and sulfur concentrations on the ability of soot to uptake water is proposed as a method for categorizing transport engine-generated particles. Categories of hydrophobic and hydrophilic particles within non-hygroscopic soots can be defined based on the amount of water uptake relative to several reference laboratory-made soots comparable to transport engine emissions. This method of characterizing hydrophobic/hydrophilic and hygroscopic soots in combustion emissions will help to determine the potential impacts of the combustion emissions on CCN/IN formation in the atmosphere.     

Isotopic signatures of deposition and transformation of Lower Cambrian saliferous rocks in the Irkutsk amphitheater: Communication 1. Sulfur isotopic composition

New isotope data on Lower Cambrian rocks of the Irkutsk amphitheater are reported in three communications. The first communication is devoted to the sulfur isotopic composition, which is most sensitive to ostsedimentary geochemical transformations of sulfate rocks in saliferous formations. It is shown that δ³⁴S values in Bel’sk and Zhigalovo boreholes are within 22–35‰ The lowest values are close to the sulfur isotopic composition of a halogenic basin, while the highest values are related to epigenetic sulfate reduction. This process was responsible for the elimination of 100 m of anhydrites from the Lower Cambrian section.