Exhumation history and timing of supergene copper mineralisation in an arid climate: New thermochronological data from the Centinela District,Atacama, Chile

Supergene copper mineralisation (SCM) processes occur during the unroofing of porphyry copper deposits. However, the geomorphological stage during which the main mineralisation occurs is still under debate. Here, we present 24 new thermochronological data from Cenozoic intrusives and compare them with the evolution of supergene mineralisation from the Centinela Mining District in the Atacama Desert. Our results indicate a two‐step cooling path: a rapid Late Eocene exhumation followed by a slow denudation. Previously published supergene mineralisation ages cluster after the main Upper Oligocene exhumation period. Ours is the first study that establishes the relationship between exhumation and supergene processes on the scale of a single mining district. It confirms that SCM took place during pediplanation, likely a required condition for efficient SCM under arid climatic conditions, in contrast to wet tropical environments where SCM occurs during rapid relief growth but has limited preservation potential.     

Analysis of water control in an underground mine under strong karst media influence (Vazante mine,Brazil)

This work presents analysis of groundwater flow conditions and groundwater control measures for Vazante underground mine located in the state of Minas Gerais, Brazil. According to field observations, groundwater flow processes in this mine are highly influenced by the presence of karst features located in the near-surface terrain next to Santa Catarina River. The karstic features, such as caves, sinkholes, dolines and conduits, have direct contact with the aquifer and tend to increase water flow into the mine. These effects are more acute in areas under the influence of groundwater-level drawdown by pumping. Numerical analyses of this condition were carried out using the computer program FEFLOW. This program represents karstic features as one-dimensional discrete flow conduits inside a three-dimensional finite element structure representing the geologic medium following a combined discrete-continuum approach for representing the karst system. These features create preferential flow paths between the river and mine; their incorporation into the model is able to more realistically represent the hydrogeological environment of the mine surroundings. In order to mitigate the water-inflow problems, impermeabilization of the river through construction of a reinforced concrete channel was incorporated in the developed hydrogeological model. Different scenarios for channelization lengths for the most critical zones along the river were studied. Obtained results were able to compare effectiveness of different river channelization scenarios. It was also possible to determine whether the use of these impermeabilization measures would be able to reduce, in large part, the elevated costs of pumping inside the mine.     

Rapid tidal marsh development in anthropogenic backwaters

Tidal marsh restoration and creation is growing in popularity due to the many and diverse sets of services these important ecosystems provide. However, it is unclear what conditions within constructed settings will lead to the successful establishment of tidal marsh. Here we provide documentation for widespread and rapid development of tidal freshwater wetlands for a major urban estuary as an unintended result of early industrial development. Anthropogenic backwater areas established behind railroad berms, jetties, and dredge spoil islands resulted in the rapid accumulation of clastic material and the subsequent initiation of emergent marshes. In one case, historical aerial photos document this transition occurring in less than 18 years, offering a timeframe for marsh development. Accretion rates for anthropogenic tidal marshes and mudflats average 0.8–1.1 and 0.6–0.7 cm year⁻¹, respectively, equivalent to two to three times the rate of relative sea level rise as well as the observed accretion rate at a 6000+ year-old reference marsh in the study area. Paired historical and geospatial analysis revealed that more than half of all the tidal wetlands on the Hudson River were likely triggered by anthropogenic development since the onset of the industrial era, including two-thirds of the emergent cattail marsh. These inadvertently constructed tidal wetlands currently trap roughly 6% of the Hudson River's sediment load. Results indicate that when sediment is readily available, freshwater tidal wetlands can develop relatively rapidly in sheltered settings. The study sites serve as useful examples to help guide future tidal marsh creation and restoration efforts.     

Methodology and Application of Hafnium Isotopes in Ilmenite and Rutile by MC‐ICP‐MS

The high abundances of the high field‐strength elements in ilmenite and rutile make these minerals particularly suitable for hafnium isotopic investigations. We present a technique for separating Hf by ion exchange chemistry from high‐TiO₂ (> 40% m/m) minerals to achieve precise Hf isotopic composition analyses by MC (multiple collector)‐ICP‐MS. Following digestion and conversion to chlorides, the first elution column is used to separate iron and the rare earth elements, the second column is designed to separate most of the titanium from Hf, an evaporation step using HClO₄ is then performed to remove any trace of HF in preparation for the third column, which is needed to eliminate any remaining trace of titanium. The modified chemistry helped to improve the yields from < 10 to > 78% as well as the analytical precision of the processed samples (e.g., sample 2033‐A1, ¹⁷⁶Hf/¹⁷⁷Hf = 0.282251 ± 25 before vs. 0.282225 ± 6 after). The technique was tested on a case study in which the Hf isotopic ratios of ilmenite and rutile (analysed prior to the chemistry improvement) were determined and permitted to evaluate that the origin of rutile‐bearing ilmenite deposits is from the same or similar magma than their, respectively, associated Proterozoic anorthosite massifs (Saint‐Urbain and Lac Allard) of the Grenville Province in Québec, Canada.     

Spatial Variability of Stable Isotope Ratios in Oysters (Crassostrea gigas) and Primary Producers Along an Estuarine Gradient (Bay of Brest, France)

This study aimed at characterizing the diet of the oyster Crassostrea gigas along an estuarine gradient in the Bay of Brest (France), through stable isotope (δ¹³C and δ¹⁵N) measurements in primary producers and wild oysters. The contribution of different potential food sources to the diet of C. gigas was estimated at high spatial resolution (over a gradient of 40 km with samplings every 2 km) to identify ecological transition zones and highlighted the dominance of resuspended biofilm in oysters diet. Although the different primary producers did not display any obvious pattern along the estuarine gradient, the stable isotope signatures of C. gigas differed among estuarine, inner Bay, and open sea sites. In particular, a striking ¹⁵N depletion pattern was found along the gradient which allowed to identify seven homogeneous groups. Moreover, some unexpected values found at two stations within the estuary revealed localized anthropogenic disturbances. Overall, our results suggest that suspension feeders might be better indicators of ecosystem functioning than primary producers and reflect the different ecological processes occurring along estuarine gradients, including localized anthropogenic inputs. We suggest that the usefulness of suspension feeders as indicators of ecosystem functional typology lies in the dominance of benthic material in their diet, which results in locally occurring processes being reflected in oysters’ stable isotope ratios.     

The atomic physics underlying the spectroscopic analysis of massive stars and supernovae

We have developed a radiative transfer code, cmfgen, which allows us to model the spectra of massive stars and supernovae. Using cmfgen we can derive fundamental parameters such as effective temperatures and surface gravities, derive abundances, and place constraints on stellar wind properties. The last of these is important since all massive stars are losing mass via a stellar wind that is driven from the star by radiation pressure, and this mass loss can substantially influence the spectral appearance and evolution of the star. Recently we have extended cmfgen to allow us to undertake time-dependent radiative transfer calculations of supernovae. Such calculations will be used to place constraints on the supernova progenitor, to place constraints on the supernova explosion and nucleosynthesis, and to derive distances using a physical approach called the “Expanding Photosphere Method”. We describe the assumptions underlying the code and the atomic processes involved. A crucial ingredient in the code is the atomic data. For the modeling we require accurate transition wavelengths, oscillator strengths, photoionization cross-sections, collision strengths, autoionization rates, and charge exchange rates for virtually all species up to, and including, cobalt. Presently, the available atomic data varies substantially in both quantity and quality.     

Photometric modeling of Asteroid 5535 Annefrank from Stardust observations

In this paper the Stardust disk-integrated phase curve at phase 47.2-134.6° of the Asteroid 5535 Annefrank, combined with groundbased observations (at phase 2.3-18.3°), are fit with Hapke’s photometric model. We confirm Newburn et al.’s (Newburn, R.L. et al. [2003]. J. Geophys. Res. 108 (E11), 5117. doi:10.1029/2003JE002106) observation that Annefrank exhibits a steep phase curve. This manifests itself in an unusually high fit surface roughness parameter of 49°. The single particle scattering albedo is 0.62, also high for an S-asteroid, while the fit phase function is more forward scattering than the typical S-asteroid being nearly isotropic with an asymmetry parameter of −0.09. The fit opposition surge width (h = 0.015) is typical of S-asteroids. However these fits assume a spherical shape to the asteroid. Li et al. (Li, J., A’Hearn, M.F., McFadden, L.A. [2004]. Icarus, 415-431) have shown that this assumption may lead to significant errors particularly at high phase angles leading to higher modeled single particle scattering albedos, macroscopic roughnesses and more forward scattering phase functions than actually exhibited. Our results confirm this finding—fitting only the data below 90° phase yields lower particle albedos (0.41) and roughnesses (20°) and more backscattering particles (−0.19) than the fit including the high phase angle data. Overall Annefrank appears to be on the bright side but otherwise is typical for an S-type asteroid suggesting that it may be a recent collisional fragment with a relatively immature surface which has had relatively little time to be weathered.     

Photometry of Triton 1992-2004: Surface volatile transport and discovery of a remarkable opposition surge

Triton, the large satellite of Neptune, was imaged by the Voyager 2 spacecraft in 1989 with dark plumes originating in its volatile-rich south polar region. Southern summer solstice, a time when seasonal volatile transport should be at a maximum, occurred in 2001. Ground-based observations of Triton’s rotational light curve obtained from Table Mountain Observatory in 2000-2004 reveal volatile transport on its surface. When compared with a static frost model constructed from Voyager images, the light curve shows an increase in total amplitude. An earlier light curve obtained in 1992 from Mauna Kea Observatory is consistent with the static frost model. This movement of volatiles on the surface agrees with recent imaging results from the Hubble Space Telescope (Bauer, J.M., Buratti, B.J., Li, J.-Y., Mosher, J.A., Hicks, M.D., Schmidt, B.E., Goguen, J.D. [2010]. Astrophys. J. 723, L49-L52). The changes in the light curve can be explained by the transport of nitrogen frost on the surface or by the uncovering of bedrock of less volatile methane. We also find that Triton exhibits a large opposition surge at solar phase angles less than 0.1°. This surge cannot be entirely explained by the effects of coherent backscatter.     

Southern Exceptionalism and the Perils of Region

Contemporary political trends associated with the rise of Donald Trump seem to confound traditional regional designations in the United States. Yet the concept of region remains salient in popular discourse. This is especially true with respect to “the South,” which appears in several recent nonacademic works as the source of troubling social and political currents. More surprising, given decades of critique of “Southern exceptionalism,” has been the reappearance of the South as a focus of analysis in the scholarly literature on immigration. This scholarly literature works to deessentialize the South by highlighting the vagaries and instabilities of Southern identities, institutions, and landscapes. It can, however, subtly and inadvertently reinforce Southern exceptionalism by identifying the South as a place marked by uniquely fraught histories of racial exclusion. This article critically assesses how the South as a regional concept has located the problem of race in the United States in a specific time and place. This leads to a broader discussion of the persistence of regional imaginaries in the discipline of geography and the need for more deliberate consideration of the geographical concepts that guide our analyses of societal change.     

Long-Term Changes in Population Dynamics of the Shrimp Palaemon longirostris in the Gironde Estuary

Spanning 20?years (1979?C2007), this study is the longest time series pertaining to the resident shrimp species Palaemon longirostris in a European estuary. Data from monthly faunal surveys undertaken across the middle part of the Gironde estuary from April 1979 along with data from a statistical analysis of the commercial catches throughout the entire estuary and river were considered in order to explore their inter and intra-annual variability and long-term trends. Long-term densities series as well as environmental series (salinity, discharge, temperature and NAO) were decomposed and the effects of environmental variables were also examined using statistical models (GAMs). This revealed important spatio-temporal variability and a significant overall decrease in abundance of this species in the Gironde estuary since the beginning of the 1980s. This long-term decrease in abundance corresponded significantly to long-term decreases in both discharge and the NAO index, as well a long-term increase in temperature and salinity in the middle part of the estuary. However, models showed that environmental factors explained only a small part of the variability. The upstream shift of the population highlighted in this study, probably due to the intrusion of marine waters into the middle section of the estuary, may also have contributed to its decrease in abundance. Inter-annual variability of densities was also significantly linked with inter-annual fecundity fluctuations, and a significant decrease in both mean female size and fecundity was shown for preserved samples from 1992. Moreover, the breeding period has been temporally stretched out and began earlier in more recent years, potentially due to the increase in spring temperature.