Arsenic attenuation in tailings at a former Cu–W–As mine,SW Finland

Nearly half a century after mine closure, release of As from the Ylöjärvi Cu–W–As mine tailings in groundwater and surface water run-off was observed. Investigations by scanning electron microscopy (SEM), electron microprobe analysis (EMPA), synchrotron-based micro-X-ray diffraction (μ-XRD), micro-X-ray absorption near edge structure (μ-XANES) and micro-extended X-ray absorption fine structure (μ-EXAFS) spectroscopy, and a sequential extraction procedure were performed to assess As attenuation mechanisms in the vadose zone of this tailings deposit. Results of SEM, EMPA, and sequential extractions indicated that the precipitation of As bearing Fe(III) (oxy)hydroxides (up to 18.4 wt.% As₂O₅) and Fe(III) arsenates were important secondary controls on As mobility. The μ-XRD, μ-XANES and μ-EXAFS analyses suggested that these phases correspond to poorly crystalline and disordered As-bearing precipitates, including arsenical ferrihydrite, scorodite, kaňkite, and hydrous ferric arsenate (HFA). The pH within 200 cm of the tailings surface averaged 5.7, conditions which favor the precipitation of ferrihydrite. Poorly crystalline Fe(III) arsenates are potentially unstable over time, and their transformation to ferrihydrite, which contributes to As uptake, has potential to increase the As adsorption capacity of the tailings. Arsenic mobility in tailings pore water at the Ylöjärvi mine will depend on continued arsenopyrite oxidation, dissolution or transformation of secondary Fe(III) arsenates, and the As adsorption capacity of Fe(III) (oxy)hydroxides within this tailings deposit.     

Nonequilibrium models for predicting forms of precipitated manganese oxides

Manganese oxides precipitated by bubbling air through 0.01 molar solutions of MnCl₂, Mn(NO₃)₂, MnSO₄, or Mn(ClO₄)₂ at a constantly maintained pH of 8.5 to 9.5 at temperatures of 25°C or higher consisted mainly of hausmannite, Mn₃O₄. At temperatures near 0°C, but with other conditions the same, the product is feitknechtite, βMnOOH, except that if the initial solution is MnSO₄ and the temperature is near 0°C the product is a mixture of manganite, γMnOOH and groutite, αMnOOH.All these oxides are metastable in aerated solution and alter by irreversible processes to more highly oxidized species during aging. A two-step nonequilibrium thermodynamic model predicts that the least stable species, βMnOOH, should be most readily converted to MnO₂. Some preparations of βMnOOH aged in their native solution at 5°C attained a manganese oxidation state of +3.3 or more after 7 months. Hausmannite aged at 25°C altered to γMnOOH. The latter is more stable than a or βMnOOH, and manganese oxidation states above 3.0 were not reached in hausmannite precipitates during 4 months of aging. Initial precipitation of MnCO₃ rather than a form of oxide is likely only where oxygen availability is very low.Composition of solutions and oxidation state and morphology of solids were determined during the aging process by chemical analyses, X-ray and electron diffraction and transmission electron micrographs.     

XFEM formulation with sub-interpolation,and equivalence to zero-thickness interface elements

This paper describes a particular formulation of the extended finite element method (XFEM) specifically conceived for application to existing discontinuities of fixed location, for instance, in geological media. The formulation is based on two nonstandard assumptions: (1) the use of sub-interpolation functions for each subdomain and (2) the use of fictitious displacement variables on the nodes across the discontinuity (instead of the more traditional jump variables). Thanks to the first of those assumptions, the proposed XFEM formulation may be shown to be equivalent to the standard finite element method with zero-thickness interface elements for the discontinuities (FEM+z). The said equivalence is theoretically proven for the case of quadrangular elements cut in two quadrangles by the discontinuity, and only approximate for other types of intersections of quadrangular or triangular elements, in which the XFEM formulation corresponds to a kinematically restricted version of the corresponding interface plus continuum scheme. The proposed XFEM formulation with sub-interpolation, also helps improving spurious oscillations of the results obtained with natural interpolation functions when the discontinuity runs skew to the mesh. A possible explanation for these oscillations is provided, which also explains the improvement observed with sub-interpolation. The paper also discusses the oscillations observed in the numerical results when some nodes are too close to the discontinuity and proposes the remedy of moving those nodes onto the discontinuity itself. All the aspects discussed are illustrated with some examples of application, the results of which are compared with closed-form analytical solutions or to existing XFEM results from the literature.     

Great Microwave Bursts and hard X-rays from solar flares

The microwave and hard X-ray characteristics of 13 solar flares that produced microwave fluxes greater than 500 solar flux units have been analyzed. These Great Microwave Bursts were observed in the frequency range from 3 to 35 GHz at Bern, and simultaneous hard X-ray observations were made in the energy range from 30 to 500 keV with the Hard X-Ray Burst Spectrometer on the Solar Maximum Mission spacecraft. The principal aim of this analysis is to determine whether or not the same distribution of energetic electrons can explain both emissions. The temporal and spectral behaviors of the microwaves as a function of frequency and the X-rays as a function of energy were tested for correlations, with results suggesting that optically thick microwave emission, at a frequency near the peak frequency, originates in the same electron population that produces the hard X-rays. The microwave emission at lower frequencies, however, is poorly correlated with emission at the frequency which appears to characterize this common source. A single-temperature and a multitemperature model were tested for consistency with the coincident X-ray and microwave spectra at microwave burst maximum. Four events are inconsistent with both of the models tested, and neither of the models attempts to explain the high-frequency part of the microwave spectrum. A source area derived on the basis of the single-temperature model agrees to within the uncertainties with the observed area of the one burst for which spatially resolved X-ray images are available.Swiss National Science Foundation Fellow from the University of Bern.Also Energy/Environmental Research Group, Incorporated, Tucson, Arizona, and Department of Physics and Astronomy, University of North Carolina, Chapel Hill. Present address: Johns Hopkins University Applied Physics Laboratory, Laurel, Maryland.     

Alternative representation of planetary perturbations

An attempt is made to find a representation of planetary perturbations which does not require a Fourier expansion. For the planetary type three body problem a sequence of canonical transformations is given based on Landen transformations coupled with a rescaling of the time. The expansion is carried out to the order 2 in the Hamiltonian.     

Vertical cloud structure of Jupiter's Equitorial Plumes

A model for the vertical cloud structure of Jupiter's Equitorial Plumes is deduced based on an analysis of Voyager images of the equitorial region in the 6190Å methane band and the 6000-Å continuum, and ground-based 8900-Å methane band images of Jupiter. A computer code that represents scattering and absorption from aerosol and gas layers was applied to a heirarchy of increasingly complex model aerosol structures to match the observations in the three wavelengths. The observations are consistent with a model for the vertical cloud structure of the equitorial region that consists of four aerosol layers. A high-altitude haze layer (HAL) with optical depth τ = 1 uniformly blankets the equitorial region at an altitude between 100 and 250 mbar. Below that, a middle-level cloud layer between 400 and 800 mbar contains the well-known Equatorial Plumes. The Plume clouds are optically thick (τ ≥ 12), bright clouds with single scattering albedo $\text{ω}\text{= 0.997}$. They are probably composed of ammonia ice. The darker ($\text{ω}\text{= 0.990}$) interplume regions contain optically thinner clouds (2 ≤ τ ≤ 5) at the same altitude as the Plumes. An opaque cloud deck between 4000 and 6000 mbar, which is probably composed of water, forms the lowest model layer. In addition to these three layers, a thin forward scattering haze layer above 100 mbar was included in the models for consistency with previous work (Tomasko et al., 1978). We conclude that the vertical structure of the Equatorial Plume clouds is consistent with the hypothesis (Hunt et al., 1981) that the Plumes are caused by upwelling at the ammonia condensation level produced by bouyancy due to latent heat release from the condensation of water clouds nearly three scale heights below the Plumes.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.