Atmospheric Disturbances that Generate Intermittent Turbulence in Nocturnal Boundary Layers

Using the unprecedented observational facilities deployed duringthe 1999 Cooperative Atmosphere-Surface Exchange Study (CASES-99),we found three distinct turbulent events on the night of 18October 1999. These events resulted from a density current,solitary wave, and internal gravity wave, respectively. Our studyfocuses on the turbulence intermittency generated by the solitarywave and internal gravity wave, and intermittent turbulenceepisodes associated with pressure change and wind direction shiftsadjacent to the ground. Both the solitary and internal gravitywaves propagated horizontally and downward. During the passage ofboth the solitary and internal gravity waves, local thermal andshear instabilities were generated as cold air was pushed abovewarm air and wind gusts reached to the ground. These thermal andshear instabilities triggered turbulent mixing events. Inaddition, strong vertical acceleration associated with thesolitary wave led to large non-hydrostatic pressure perturbationsthat were positively correlated with temperature. The directionaldifference between the propagation of the internal gravity waveand the ambient flow led to lateral rolls. These episodic studiesdemonstrate that non-local disturbances are responsible for localthermal and shear instabilities, leading to intermittentturbulence in nocturnal boundary layers. The origin of thesenon-local disturbances needs to be understood to improve mesoscalenumerical model performance.     

Creating usable science: Opportunities and constraints for climate knowledge use and their implications for science policy

In the past several decades, decision makers in the United States have increasingly called upon publicly funded science to provide “usable” information for policy making, whether in the case of acid rain, famine prevention or climate change policy. As demands for usability become more prevalent for publicly accountable scientific programs, there is a need to better understand opportunities and constraints to science use in order to inform policy design and implementation. Motivated by recent critique of the decision support function of the US Global Change Research Program, this paper seeks to address this issue by specifically examining the production and use of climate science. It reviews empirical evidence from the rich scholarship focused on climate science use, particularly seasonal climate forecasts, to identify factors that constrain or foster usability. It finds, first, that climate science usability is a function both of the context of potential use and of the process of scientific knowledge production itself. Second, nearly every case of successful use of climate knowledge involved some kind of iteration between knowledge producers and users. The paper argues that, rather than an automatic outcome of the call for the production of usable science, iterativity is the result of the action of specific actors and organizations who ‘own’ the task of building the conditions and mechanisms fostering its creation. Several different types of institutional arrangements can accomplish this task, depending on the needs and resources available. While not all of the factors that enhance usability of science for decision making are within the realm of the scientific enterprise itself, many do offer opportunities for improvement. Science policy mechanisms such as the level of flexibility afforded to research projects and the metrics used to evaluate the outcomes of research investment can be critical to providing the necessary foundation for iterativity and production of usable science to occur.     

Mantle derived crystal-poor rhyolitic ignimbrites: Eruptive mechanism from geochemical and geochronological data of the Piedra Parada caldera,Southern Argentina

Trace elements, isotopic modeling and U-Th-Pb SHRIMP zircon age constraints are used to reconstruct the eruption history and magmatic processes of the Piedra Parada Caldera. In the early Eocene, the crystal-poor Barda Colorada ignimbrite(BCI), having 15% micro-porphyritic crystals with respect to magmatic components, erupted a volume estimated in more than 300 km~3. The Piedra Parada caldera is located in the Patagonian Andes foreland, at the southern end of the calderas field of the Pilcaniyeu Volcanic Belt(PVB). This belt is related to an extensional tectonic setting as a result of the collision of the Farallon-Aluk ridge with South America, which enabled the development of a transform ocean/continental plate margin followed by the detachment of the Aluk plate and the opening of a slab window. The BCI extra-caldera Plateau is a 100 m thick deposit, having a lower unit with high silica(Si O_2 76 wt.%),potassium poor rhyolitic composition(trondhjemitic like magma), and an upper unit with normal to high potassium rhyolitic composition(granitic like magma). A trace elements modeling of the BCI units shows that the BCI lower and upper units did not evolve from fractionation or immiscibility in the shallow magma reservoir. The BCI also have a primitive isotopic signature(initial87 Sr/86 Sr =0.7031-0.7049 and ε_(Nd)= +3.4 to +3.65). Thus, tectonic, compositional and isotopic constraints suggest the fast ascent of high silica magmas to a shallow reservoir, and point to an upper mantle origin for these rhyolitic magmas in a transitional(Orogenic-Anorogenic) tectono-magmatic setting. U-Th-Pb SHRIMP zircon crystallization ages of the Syn-caldera stage BCI units(56 -51.5 Ma) show a protracted life of 5 Ma for this caldera reservoir. The age of 52.9 ± 0.3 Ma is considered the best fit for the possible maximum age for the caldera collapse. The Late-caldera magmatism has trachyandesitic and rhyolitic compositions.The trace element modeling suggests that these rhyolites evolve from the trachyandesites and do not evolve from the BCI residual magma. The trachyandesites have U-Th-Pb SHRIMP zircon crystallization ages of 52 ± 1 Ma, suggesting that the caldera eruption was triggered by the arrival of the trachyandesitic magma.     

Determination of Carbon,Hydrogen, Nitrogen and Sulfur in Geological Materials Using Elemental Analysers

This article describes a series of methods developed for the determination of total carbon (C_Total), organic carbon (C_org), hydrogen, nitrogen and sulfur. The following elemental analysers were used: LECO model RC‐412 for the determination of organic carbon, total carbon and hydrogen; LECO model CS‐200 for the determination of total carbon and sulfur; LECO model TN‐400 for the determination of nitrogen; and LECO model TruSpec CHNS for the determination of organic carbon, total carbon, hydrogen, nitrogen and sulfur. Uncertainty and limits of detection and quantification were calculated for each method, as well as the running costs to define the most effective instrument for each material and each analyte. Accuracy was checked by the application of the Sutarno–Steger test. Finally, a compilation of the results obtained in the determination of C_Total, C_org, H, N and S in forty‐nine reference materials is presented.     

Valorization of olive stone as adsorbent of chromium(VI): comparison between laboratory- and pilot-scale fixed-bed columns

The main aim of this work is to study the effect of scaling in the biosorption of chromium(VI) onto olive stone in two different fixed-bed columns. Firstly, the effect of flow rate, bed depth and inlet concentration of Cr(VI) in both columns was analyzed. The results revealed a better operation for lower flow rates, higher bed heights and lower inlet concentrations of metal. When decreasing flow rate, the operation time of the column increases. Therefore, as the solution flow rate increased the breakthrough and the exhaustion times decreased. An increase in bed depth increases the quantity of chromium eliminated and thus, the higher sorption capacity of the system. A decrease in the inlet concentration of chromium produces a delay in exhaustion time, and larger volumes of solution could be treated. The results were fitted to the BDST model, obtaining that the adsorptive capacity of the bed depth is similar in laboratory- and pilot-scale fixed-bed columns, considering the biosorption capacity as a biosorption-coupled reduction process. Results also could indicate that scaling affects more to the reduction process than properly biosorption process. The experimental data were also fitted to Adams–Bohart, Thomas, Yoon–Nelson and dose–response models. A good fit of the biosorption process of Cr(VI) was found for dose–response and Adams–Bohart models.     

Cold seep communities in the deep eastern Mediterranean Sea: composition, symbiosis and spatial distribution on mud volcanoes

Two mud volcano fields were explored during the French–Dutch MEDINAUT cruise (1998) with the submersible NAUTILE, one south of Crete along the Mediteranean Ridge at about 2000 m depth (Olimpi mud field) and the other south of Turkey between 1700 and 2000 m depth (Anaximander mud field) where high methane concentrations were measured. Chemosynthetic communities were observed and sampled on six mud volcanoes and along a fault scarp. The communities were dominated by bivalves of particularly small size, belonging to families commonly found at seeps (Mytilidae, Vesicomyidae, Thyasiridae) and to Lucinidae mostly encountered in littoral sulfide-rich sediments and at the shallowest seeps. Siboglinid polychaetes including a large vestimentiferan Lamellibrachia sp. were also associated. At least four bivalve species and one siboglinid are associated with symbiotic chemoautotrophic bacteria, as evidenced by Transmission Electronic Microscopy and isotopic ratio measurements. Among the bivalves, a mytilid harbors both methanotrophic and sulfide-oxidizing bacteria. Video spatial analysis of the community distribution on three volcanoes shows that dense bivalve shell accumulations (mainly lucinids) spread over large areas, from 10% to 38% of the explored areas (2500–15000 m²) on the different volcanoes. Lamellibrachia sp. had different spatial distribution and variable density in the two mud volcano fields, apparently related with higher methane fluxes in the Anaximander volcanoes and maybe with the instability due to brines in the Olimpi area. The abundance and richness of the observed chemosynthetic fauna and the size of some of the species contrast with the poverty of the deep eastern Mediterranean. The presence of a specialized fauna, with some mollusk genera and species shared with other reduced environments of the Mediterranean, but not dominated by the large bivalves usually found at seeps, is discussed.     

Water level control on coastal landform distribution and associated processes in a highly fluctuating shallow lake (Gallocanta Lake,NE Spain)

Shallow lakes in semi-arid environments are very sensitive to hydrological alterations associated with climate change. Their shorelines and geometry can change according to water level fluctuations. Gallocanta Lake (NE Spain) is a typical example of such lacustrine conditions because it is exposed to strong winds parallel to its elongation axis and is located in a semi-arid Mediterranean environment. In this work, a high-resolution digital elevation model (DEM) of the area is used to compare the distribution of coastal forms (beaches, barrier islands, deltas, lagoons, etc.) with the frequency at which different water levels are attained. As a result, a clear relationship is obtained between presently active forms and the water levels most frequently reached in the lake. It is deduced that, once formed, the surrounding coastal plains related to these coastal forms control the permanence of water around a given height interval, favouring the development of these morphologies, in a positive feedback mechanism only broken by subsequent climate warming and lake water lowering. The hydrodynamic conditions responsible for activating the coastal forms have been analysed by applying a mathematical model of wind-driven currents in the lake that predicts the present erosional/progradational trends associated with them. The combination of the different results obtained was used to generate a synthetic map of active coastal processes and trends along the lake shore during high water episodes, with two versions according to the two dominant wind scenarios in the region. The distribution of erosion/sedimentation trends along the lake shores has helped to propose the existence of longitudinal littoral cells, each one recording different shoreline trend (retreat, progradation, and stability), depending on the prevailing wind scenario. This synthetic scheme can be useful for predicting the eco-morphological trends of the lake shore and adapting the present management practices in this protected area accordingly.     

Estimation and prediction of a 2D lognormal diffusion random field

This paper describes techniques for estimation and prediction of two-parameter lognormal diffusion random fields. The drift and diffusion coefficients, which characterize a two-parameter lognormal diffusion under certain conditions, are estimated by maximum likelihood. For data on a regular grid, an alternative method is proposed to estimate the diffusion coefficient. Both of these estimates are compared in several situations. The kriging predictors are formulated involving the drift and diffusion coefficients and the predictions are obtained using the estimates of these coefficients.