Influence of Mediterranean sea-level changes on the Dacic Basin (Eastern Paratethys) during the late Neogene: the Mediterranean Lago Mare facies deciphered

A recently published scenario viewing the Messinian salinity crisis as two evaporitic steps rather than one has led to a search for new indices of the crisis in the Eastern Paratethys. Fluvial processes characterized the southwestern Dacic Basin (Southern Romania, i.e. the Carpathian foredeep) whereas brackish sediments were continuously deposited in its northern part. This is consistent with previously evidenced responses of the Black Sea to the Messinian salinity crisis. High sea‐level exchanges between the Mediterranean Sea and Eastern Paratethys are considered to have occurred just before and just after desiccation of the Mediterranean. This accounts for two successive Mediterranean nannoplankton‐dinocyst influxes into the Eastern Paratethys that, respectively, belong to zones NN 11 and NN 12. Meanwhile, two separate events that gave rise to Lago Mare facies (with Paratethyan Congeria, ostracods and/or dinoflagellate cysts) arose in the Mediterranean Basin in response to these high sea‐level exchanges and located 5.52 and 5.33 Ma (isotopic stages TG 11 and TG 5, respectively), i.e. just before and just after the almost complete desiccation of the Mediterranean). These Lago Mare facies formed independently of lakes with ostracods of the Cyprideis group that developed in the central basins during the final stages of desiccation. The gateway faciliting these water exchanges is not completely identified. A proto‐Bosphorus strait seems unlikely. A plausible alternative route extends from the northern part of the Thessaloniki region up to the Dacic Basin and through Macedonia and the Sofia Basin. The expression ‘Lago Mare’ is chronostratigraphically ambiguous and should be discontinued for this purpose, although it might remain useful as a palaeoenvironmental term.     

Sporadic breakdowns of stability in the PBL over simple and complex terrain

Breakdowns of stability in the PBL are examined using one-minute average horizontal wind speeds and temperatures observed over many nights at stations located in simple and complex terrain. The analysis is based on the temporal behavior of the wind speed-temperature covariance, which is obtained by digital bandpass filtering. It is shown that breakdowns are a common feature of the stable PBL over both simple and complex environments. Vertical fluxes of heat during breakdowns are estimated to be a significant fraction of the nighttime average heat flux. It is hypothesized that a major portion of the nighttime vertical transfer of heat, momentum, and atmospheric pollutants occurs during periods of stability breakdowns.     

Using the Fisher–Shannon method to characterize continuous seismic signal during volcanic eruptions: application to 2011–2012 El Hierro (Canary Islands) eruption

We investigated the dynamics of the continuous seismic signal recorded before and during the 2011–2012 El Hierro eruption (Canary Islands) using the innovative approach of the Fisher–Shannon method, a suitable statistical tool for detecting dynamic changes in complex systems. Our findings identify dynamic changes in the seismic signal that can be correlated with different stress states of the magmatic setting and the plumbing system in the volcano at El Hierro. The results contribute to the understanding of the fracturing pattern in the crust during a new intrusion and eruption of an overpressurized batch of magma.     

Jurassic cooling ages in Paleozoic to early Mesozoic granitoids of northeastern Patagonia: 40Ar/39Ar, 40K–40Ar mica and U–Pb zircon evidence

International Journal of Earth Sciences - U–Pb SHRIMP zircon crystallization ages and Ar–Ar and K–Ar mica cooling ages for basement rocks of the Yaminué and Nahuel Niyeu...     

Latest Jurassic to earliest Cretaceous paleoenvironmental changes in the Southern Carpathians, Romania: regional record of the late Valanginian nutrification event

Fluctuation in calpionellid, foraminiferal, and nannofossil diversity and abundance are documented in two successions located in the eastern part of the Upper Jurassic–Lower Cretaceous carbonate platform of the Southern Carpathian area, Romania. The lower part of the studied sections consists of upper Tithonian–upper Berriasian bioclastic limestones. This age is supported by the presence of the calpionellid assemblages assigned to the Crassicollaria, Calpionella, and Calpionellopsis Zones. Based on biostratigraphical data, a gap was identified within the uppermost Berriasian–base of the upper Valanginian (the interval encompasses the Boissieri, Pertransiensis, Campylotoxum, and lower part of the Verrucosum ammonite Zones). Hence, the upper Tithonian–upper Berriasian bioclastic limestones are overlain by upper Valanginian–lower Hauterivian pelagic limestones (the interval covered by the NK3B and NC4A nannofossil Subzones). A detailed qualitative and semiquantitative analysis of the nannoflora was carried out over this interval. To estimate the surface water fertility conditions, the nannoplankton-based nutrient index (NI) was calculated. The fluctuation pattern of NI allow us to recognize four phases in the investigated interval, as follows: (1) phase I (covering the lower part of the NK3B nannofossil Subzone and the upper part of the Verrucosum ammonite Zone, respectively) is characterized by low values of the NI (below 20%), by the dominance of the genus Nannoconus in the nannofloral assemblages (between 60–70%), and moderate abundance of Watznaueria barnesae (up to 23%), while the high-fertility nannofossils constitute a minor component of the assemblages; (2) phase II (placed in the NK3B nannofossil Subzone, extending from the top of Verrucosum ammonite Zone, up to the lower part of the Furcillata ammonite Zone) is characterized by increase of NI above 30%, a decrease of nannoconids (up to 50% at the top), while Watznaueria barnesae increases in abundance up to 27%. The fertility proxies (Diazomatolithus lehmanii, Zeugrhabdotus erectus, Discorhabdus rotatorius, and Biscutum constans) represent again a minor component of the recorded nannofloras (less than 7% in both sections), but they have an ascending trend; (3) phase III (which encompasses the boundary interval of the NK3B and NC4A nannofossil Subzones, corresponding to the upper part of the Furcillata ammonite Zone) contains higher NI values (over 35%, and up 52% towards the base of this phase), an abrupt nannoconid decrease (down to 20%), higher abundance of Watznaueria barnesae (over 30%), while the fertility nannofossils became an important nannofloral component, jointly amounting to almost 20%; (4) phase IV (identified within the NC4A Nannofossil Zone and corresponding to the boundary interval of the Furcillata and Radiatus ammonite Zones) is characterized by a decrease of NI to 25%, a recovery of the nannoconids up to 40%, a decline in abundance of Watznaueria barnesae to 25%, together with a pronounced drop of fertility taxa, which make together no more than 8%. We assume that maximum of eutrophication in the studied interval from the Southern Carpathians was in the Furcillata ammonite Zone. Notably, within the phases 2 and 3, the morphological changes identified in the benthic foraminiferal assemblages (the predominance of flattened morphologies, together with the presence of conical and trochospiral inflated forms), as well as the occurrence of the Zoophycos trace fossils and pyrite framboids, indicate dysaerobic conditions. In the Southern Carpathians, the late Valanginian–early Hauterivian biogeographical changes are coeval with the initiation of the carbonate platform drowning.     

Aluminum coprecipitates with Fe (hydr)oxides: Does isomorphous substitution of Al for Fe in goethite occur?

Iron (hydr)oxides are common in natural environments and typically contain large amounts of impurities, presumably the result of coprecipitation processes. Coprecipitation of Al with Fe (hydr)oxides occurs, for example, during alternating reduction-oxidation cycles that promote dissolution of Fe from Fe-containing phases and its re-precipitation as Fe-Al (hydr)oxides. We used chemical and spectroscopic analyses to study the formation and transformation of Al coprecipitates with Fe (hydr)oxides. In addition, periodic density functional theory (DFT) computations were performed to assess the structural and energetic effects of isolated or clustered Al atoms at 8 and 25 mol% Al substitution in the goethite structure. Coprecipitates were synthesized by raising the pH of dilute homogeneous solutions containing a range of Fe and Al concentrations (100% Fe to 100% Al) to 5. The formation of ferrihydrite in initial suspensions with ?20 mol% Al, and of ferrihydrite and gibbsite in initial suspensions with ?25 mol% Al was confirmed by infrared spectroscopic and synchrotron-based X-ray diffraction analyses. While base titrations showed a buffer region that corresponded to the hydrolysis of Fe in initial solutions with ?25 mol% Al, all of the Al present in these solutions was retained by the solid phases at pH 5, thus indicating Al coprecipitation with the primary Fe hydroxide precipitate. In contrast, two buffer regions were observed in solutions with ?30 mol% Al (at pH ∼2.25 for Fe³⁺ and at pH ∼4 for Al³⁺), suggesting the formation of Fe and Al (hydr)oxides as two separate phases. The Al content of initial coprecipitates influenced the extent of ferrihydrite transformation and of its transformation products as indicated by the presence of goethite, hematite and/or ferrihydrite in aged suspensions. DFT experiments showed that: (i) optimized unit cell parameters for Al-substituted goethites (8 and 25 mol% Al) in clustered arrangement (i.e., the formation of diaspore-like clusters) were in good agreement with available experimental data whereas optimized unit cell parameters for isolated Al atoms were not, and (ii) Al-substituted goethites with Al in diaspore-like clusters resulted in more energetically favored structures. Combined experimental and DFT results are consistent with the coprecipitation of Al with Fe (hydr)oxides and with the formation of diaspore-like clusters, whereas DFT results suggest isomorphous Al for Fe substitution within goethite is unlikely at ?8 mol% Al substitution.     

A reappraisal of the significance of obstacle clasts in cluster bedform dispersal

The dispersal of cluster bedforms is examined in a short, partially braided reach of the River Quoich, northeast Scotland, after minor flood events in 1989 and 1990. In all cases, the eventual dispersal of clusters occurred without prior removal of the obstacle clast. Since none of the obstacle clasts was dispersed in 1989 and only two-thirds by 1990, obstacle clasts probably form a less significant delay to sediment entrainment than previously assumed and represent a relatively immobile component of bed sediment.     

The water regime of the Monegros playa-lakes as established from ground and satellite data

The Monegros playa-lakes are isolated saline wetlands, locally named ‘saladas’, situated in a vulnerable semi-arid territory where agricultural expansion threatens the natural hydrologic cycle with regular artificial flooding, risking the survival of a valuable natural resource. This study aims to examine the water regime of these playa-lakes from climate data and available hydrologic records. These records are historical and limited to a series of weekly measurements of depth and of water extent extracted from Landsat imagery. We have characterized the hydrological behavior of the playa-lakes by treating ground and satellite data separately. For this purpose, the playa-lakes are first grouped according to the water occurrence episodes. Then their hydrologic status is related to the previous rainfall and also to ET₀, since there is a lack of local records of wind as well as brine or fresh water evaporation. The northern playa-lakes respond to rain faster than the southern ones. All playa-lakes have a significant relationship between water occurrence and rainfall accumulated within 180 days prior to an observation. A significant relationship between ET₀ and water occurrence was found for a shorter 15-day accumulation period. Quantifying the current water regime now is critical for monitoring the effects of expanding irrigation in adjacent lands. Remote sensing is well-suited to an environmental assessment for regions of difficult access with the added benefit of lowered field measurement cost. The hydrological data from the Monegros playa-lakes could be integrated with other playa environments worldwide to compare regionally specific climate conditions.     

TRACING FLOOD FLOWS USING SEDIMENTARY INDICATORS

LinTRODUCTIONANDAIMSTheaimsofthisStUdyaretointroducenewtechniquesforanalysingfloodflowsfromsedimentarrangementmsapproachincorporatestheeffectsofflotvonthedevelopmentofrouglmessontheriverbed,andnot,asismostlythecase,theeffectsofbedroughnessonflow.Differentacsofflows,includingthemaalmumfloodflowarereconsmictedfromfloworientahonsofparticlesoveranentiregravCIbar.DuetOtheddricultiesinvolvedinobtaininglargeparticlesamples,studiesonpAncleOrientationsintheliteratUrearerare.WhilstmoStanalyse…     

Long-range dependence in the time series of Taiţa River discharges

ABSTRACT

The aim of this article is to offer an insight into the hydrology of southeast Romanian catchments, which have not been studied systematically. The complex behaviour of the Tai?a, one of the most important rivers situated in the northern part of Dobrogea, is demonstrated. Long-range dependence (LRD) in the time series of its streamflow, including the presence of trends, is supported by an estimated Hurst exponent of approximately 0.8, as well as statistical tests.

Editor D. Koutsoyiannis; GUEST editor S. Weijs