Comparison of four meteorite penetration funnels in the Campo del Cielo crater field,Argentina

Abstract– More craters may be discovered in the future, but as it is currently known, the Campo del Cielo crater field is 18 km long by 4 km at its widest point. Such a distribution of craters suggests that the parent meteoroid entered and traversed the atmosphere at a very low angle relative to horizontal. The crater field contains at least 20 small craters produced by the larger fragments of the parent meteoroid. Four of these are explosion analog craters and the rest are penetration funnels. During four field seasons, we have constructed topographic and magnetic maps of four of the penetration funnels as found, and then dug trenches across them to learn their original structures and recover meteorites preserved within them. Structures of these penetration funnels indicate very low angles of impact, i.e., 9–16° relative to horizontal. This supports the idea that the parent meteoroid traversed the atmosphere at a low angle. Data given here for the four penetration funnels include projectile masses, lengths, widths, depths, and estimates of impact angles and azimuths. One of the penetration funnels described here (No. 6) can almost be classified as an explosion analog crater.     

Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.     

Goethite surface reactivity: III. Unifying arsenate adsorption behavior through a variable crystal face - Site density model

We developed a model that describes quantitatively the arsenate adsorption behavior for any goethite preparation as a function of pH and ionic strength, by using one basic surface arsenate stoichiometry, with two affinity constants. The model combines a face distribution-crystallographic site density model for goethite with tenets of the Triple Layer and CD-MUSIC surface complexation models, and is self-consistent with its adsorption behavior towards protons, electrolytes, and other ions investigated previously. Five different systems of published arsenate adsorption data were used to calibrate the model spanning a wide range of chemical conditions, which included adsorption isotherms at different pH values, and adsorption pH-edges at different As(V) loadings, both at different ionic strengths and background electrolytes. Four additional goethite-arsenate systems reported with limited characterization and adsorption data were accurately described by the model developed. The adsorption reaction proposed is:

     

Geochemistry and Sm–Nd isotopic systematics of Ediacaran–Ordovician,sedimentary and bimodal igneous rocks in the western Acatlán Complex,southern Mexico: Evidence for rifting on the southern margin of the Rheic Ocean

Ordovician igneous rocks in the western Acatlán Complex (Olinalá area) of southern Mexico include a bimodal igneous suite that intrudes quartzites and gneisses of the Zacango Unit, and all these rocks were polydeformed and metamorphosed in the amphibolite facies during the Devono-Carboniferous. The Ordovician igneous rocks consist of the penecontemporaneous amphibolites, megacrystic granitoids and leucogranite, the latter dated at ca. 464 Ma. Geochemical and Sm–Nd data indicate that the amphibolites have a differentiated tholeiitic signature, and that its mafic protoliths formed in an extensional setting transitional between within-plate and ocean floor. The amphibolites are variably contaminated by a Mesoproterozoic crustal source, inferred to be the Oaxacan basement exposed in the adjacent terrane. The most primitive samples have εNdt (t = 465 Ma) values significantly below that of the contemporary depleted mantle and were probably derived from the sub-continental lithospheric mantle. The megacrystic granites were most probably derived by partial melting of an arc crustal source (similar to the Oaxacan Complex) and triggered by the ascent of mafic magma from the lithospheric mantle. Sm–Nd isotopic signatures suggest that metasedimentary rocks from Zacango Unit were derived from adjacent Oaxacan Complex. Trace elements relationships (e.g. La/Th vs. Hf) and REE patterns suggest provenance in felsic-intermediate igneous rocks with a calc-alkaline signature. The Ordovician bimodal magmatism is inferred to have resulted from rifting on the southern flank of the Rheic Ocean and is an expression of a major rifting event that occurred along much of the northern Gondwanan margin in the Ordovician.     

The Response of Estuarine Macrobenthic Communities to Natural- and Human-Induced Changes: Dynamics and Ecological Quality

Anthropogenic activities are a disturbance factor of coastal systems and can be widely recognized as a major threat to the health of coastal systems. However, natural events cannot be disregarded from management issues because of their significant influence on the communities living in these areas. Based on long-term subtidal data from the Mondego Estuary (Portugal), the effects of natural events (e.g., floods and droughts) on macrobenthic communities were compared with the anthropogenic events. Sampling stations were grouped into characteristic zones (mouth, north arm, south arm) so the community dynamics of each of these estuarine areas could be followed over time. Environmental assessment was performed for stations using the Benthic Assessment Tool (BAT), and compared with the existing pressures. Human impacts persist over a number of years and gradually reduce ecosystem health, as discussed in the European Water Framework Directive. Paradoxically, natural events cause stronger impacts but are of a shorter duration, which allows for a faster recovery of macrobenthic communities. The study showed that caution should be taken when developing and implementing water policies so as not to disregard the importance of the different events (natural and human-caused) on the ecosystem health (e.g., community degradation and water quality and ecological quality status assessment).     

Uncovering spatiotemporal micromobility patterns through the lens of space–time cubes and GIS tools

Journal of Geographical Systems - In the past ten years, cities have experienced a burst of micromobility services as they offer a flexible transport option that allows users to cover short trips...     

Field characterization and data integration to define the hydraulic heterogeneity of a shallow granular aquifer at a sub-watershed scale

Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km². The workflow involves characterization and data integration steps that were applied on a 12-km² study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.     

Influence of the spatial resolution of satellite-derived vegetation parameters on the biogenic Volatile Organic Compounds (VOC) emission modeling

Vegetation is a natural source of Volatile Organic Compounds (VOC) that plays an important role in atmospheric chemistry. The main objective of the current study is to implement a model to quantify process-based VOC emissions from plants that focuses on the relationship between the sensitivity of VOC emission estimates to spatial resolution data, based on scientific knowledge and vegetation dynamics derived from satellite observations. The Normalized Difference Vegetation Index (NDVI) and Leaf Area Index (LAI) were elected to examine this issue using different resolutions of satellite-derived products: 22m from the DEIMOS-1 satellite, and 250m and 1000m provided by MODIS. The study is focused on an area of 80×80km² in Portugal for 2011. Detailed land cover and meteorological data are also included in the emission quantification algorithm. The primary outcomes were determined using a multi-scale analysis showing spatial and temporal variations in the vegetation parameters and modeling results. The results confirm that the emissions model is highly sensitive to the spatial resolution of the satellite-derived data, resulting in about a 30% difference in total isoprene emissions for the study area.     

Significance of ancient sulfide PGE and Re–Os signatures in the mantle beneath Calatrava,Central Spain

Spinel lherzolite and wehrlite xenoliths from the Cenozoic Calatrava volcanic field carry the geochemical imprint of metasomatic agents that have affected the subcontinental lithospheric mantle beneath Central Iberia. Some xenoliths (mainly wehrlites) were enriched in REE, Sr, P, and CO₂ by silicic-carbonate-rich metasomatic melts/fluids, while others record the effects of subduction-related hydrous silicate fluids that have precipitated amphibole and induced high Ti/Eu in primary clinopyroxene. The petrographic observations and geochemical data suggest that interstitial glass in the xenoliths represent the quenched products of Si-rich melts that infiltrated the mantle peridotite shortly before the entrainment of the xenoliths in the host magmas that erupted ca 2 million years ago. During their infiltration, the metasomatic melts reacted with peridotite, resulting in silica enrichment, while remobilizing grains of iron-rich monosulfide solid solution (Fe-rich Mss) initially enclosed in, or intergranular to, primary olivine and pyroxenes. In situ laser ablation inductively coupled plasma-mass spectrometry analysis of single sulfide grains reveals that the Fe-rich Mss in glass shows platinum-group element (PGE) patterns and ¹⁸⁷Os/¹⁸⁸Os compositions identical to the Fe-rich Mss occurring as inclusions in, or at grain boundaries of primary silicates. Moreover, independent of its microstructural position, Fe-rich Mss exhibits PGE and ¹⁸⁷Os/¹⁸⁸Os signatures typical of Mss either residual after partial melting or crystallized directly from sulfide melts. Our findings reveal that young metasomatic melt(s)/fluid(s) may carry remobilized sulfides with PGE and Os-isotopic signatures identical to those of texturally older sulfides in the peridotite xenolith. These sulfides thus still provide useful information about the timing and nature of older magmatic events in the subcontinental mantle.     

A Middle Miocene carbonate embankment on an active volcanic slope: Ilhéu de Baixo,Madeira Archipelago,Eastern Atlantic

Carbonate factories on insular oceanic islands in active volcanic settings are poorly explored. This case study illuminates marginal limestone deposits on a steep volcanic flank and their recurring interruption by deposits linked to volcaniclastic processes. Historically known as Ilhéu da Cal (Lime Island), Ilhéu de Baixo was separated from Porto Santo, in the Madeira Archipelago, during the course of the Quaternary. Here, extensive mines were tunnelled in the Miocene carbonate strata for the production of slaked lime. Approximately 10 000 m³ of calcarenite (−1 to 1ø) was removed by hand labour from the Blandy Brothers mine at the south end of the islet. Investigations of two stratigraphic sections at opposite ends of the mine reveal that the quarried material represents an incipient carbonate ramp developed from east to west and embanked against the flank of a volcanic island. A petrographic analysis of limestones from the mine shows that coralline red algae from crushed rhodoliths account for 51% of all identifiable bioclasts. This material was transported shoreward and deposited on the ramp between normal wave base and storm wave base at moderate depths. The mine's roof rocks are formed by Surtseyan deposits from a subsequent volcanic eruption. Volcaniclastic density flows also are a prevalent factor interrupting renewed carbonate deposition. These flows arrived downslope from the north and gradually steepened the debris apron westwards. Slope instability is further shown by a coral rudstone density flow that followed from growth of a coral reef dominated by Pocillopora madreporacea (Lamarck), partial reef collapse, and transport from a more easterly direction into a fore‐reef setting. The uppermost facies represents a soft bottom at moderate depths in a quiet, but shore‐proximal setting. Application of this study to a broader understanding of the relationship between carbonate and volcaniclastic deposition on oceanic islands emphasizes the susceptibility of carbonates to dilution and complete removal by density flows of various kinds, in contrast to the potential for preservation beneath less‐disruptive Surtseyan deposits. Copyright © 2013 John Wiley & Sons, Ltd.