The solar hafnium abundance

The solar Hf abundance is determined using nine Hf ii lines in the photospheric spectrum. The transition probabilities were obtained from lifetime measurements performed by the beam-foil technique. The abundance derived from synthetic spectrum calculations is A(Hf) = 0.88 ± 0.08 in the logarithmic A(H) = 12.00 scale.     

Sensitivity analysis of seismic hazard for the northwestern portion of the state of Gujarat, India

We test the sensitivity of seismic hazard to three fault source models for the northwestern portion of Gujarat, India. The models incorporate different characteristic earthquake magnitudes on three faults with individual recurrence intervals of either 800 or 1600 years. These recurrence intervals imply that large earthquakes occur on one of these faults every 266–533 years, similar to the rate of historic large earthquakes in this region during the past two centuries and for earthquakes in intraplate environments like the New Madrid region in the central United States. If one assumes a recurrence interval of 800 years for large earthquakes on each of three local faults, the peak ground accelerations (PGA; horizontal) and 1-Hz spectral acceleration ground motions (5% damping) are greater than 1 g over a broad region for a 2% probability of exceedance in 50 years' hazard level. These probabilistic PGAs at this hazard level are similar to median deterministic ground motions. The PGAs for 10% in 50 years' hazard level are considerably lower, generally ranging between 0.2 g and 0.7 g across northwestern Gujarat. Ground motions calculated from our models that consider fault interevent times of 800 years are considerably higher than other published models even though they imply similar recurrence intervals. These higher ground motions are mainly caused by the application of intraplate attenuation relations, which account for less severe attenuation of seismic waves when compared to the crustal interplate relations used in these previous studies. For sites in Bhuj and Ahmedabad, magnitude (M) 7 3/4 earthquakes contribute most to the PGA and the 0.2- and 1-s spectral acceleration ground motion maps at the two considered hazard levels.     

Inverse kinematic problem for a random gradient medium in geometric optics approximation

Scattering at random inhomogeneities in a gradient medium results in systematic deviations of the rays and travel times of refracted body waves from those corresponding to the deterministic velocity component. The character of the difference depends on the parameters of the deterministic and random velocity component. However, at great distances to the source, independently of the velocity parameters (weakly or strongly inhomogeneous medium), the most probable depth of the ray turning point is smaller than that corresponding to the deterministic velocity component, the most probable travel times also being lower. The relative uncertainty in the deterministic velocity component, derived from the mean travel times using methods developed for laterally homogeneous media (for instance, the Herglotz-Wiechert method), is systematic in character, but does not exceed the contrast of velocity inhomogeneities by magnitude. The gradient of the deterministic velocity component has a significant effect on the travel-time fluctuations. The variance at great distances to the source is mainly controlled by shallow inhomogeneities. The travel-time flucutations are studied only for weakly inhomogeneous media.     

A warm and wet little climatic optimum and a cold and dry little ice age in the southern rocky mountains,U.S.A.

The zenith of Anasazi Pueblo Indian occupation in the northern Colorado Plateau region of the southwestern U.S.A. coincides with the Little Climatic Optimum or Medieval Warm Period (A.D. 900–1300), and its demise coincides with the commencement of the Little Ice Age. Indexes of winter (jet-stream derived) and summer (monsoon derived) precipitation and growing season length were developed for the La Plata Mountains region of southwestern Colorado. The results show that during the height of the Little Climatic Optimum (A.D. 1000–1100) the region was characterized by a relatively long growing season and by a potential dry farming zone or elevational belt (currently located between 2,000 m and 2,300 m elevation) that was twice as wide as present and could support Anasazi upland dry farming down to at least 1,600 m, an elevation that is quite impossible to dry farm today because of insufficient soil moisture. This expanded dry-farm belt is attributable to a more vigorous circulation regime characterized by both greater winter and summer precipitation than that of today. Between A.D. 1100 and 1300 the potential dry-farm belt narrowed and finally disappeared with the onset of a period of markedly colder and drier conditions than currently exist. Finally, when the Little Ice Age terminated in the mid A.D. 1800s and warmer, wetter conditions returned to the region, another group of farmers (modern Anglos) were able to dry farm the area.The U.S. Government right to retain a non-exclusive, royalty-free license in and to any copyright is acknowledged.     

An evaluation of various forms of VAS retrievals in the analysis of a preconvective environment

Summary Quantitative retrievals derived from VISSR Atmospheric Sounder (VAS) radiances are combined with conventional surface and radiosonde data to evaluate the impact of the higher time and space resolution geosynchronous satellite soundings on the diagnosis of a preconvective environment over the central United States on 20 July 1981. Retrievals of temperature, dewpoint temperature, equivalent potential temperature, total column precipitable water, and lifted index, all derived at 60 km resolution over approximately three-hourly intervals, are shown to be physically consistent in space and time and to compare well with available radiosonde data. When VAS fields are used to augment qualitative VAS imagery and analyses from conventional data sources mesoscale regions with convective instability are more clearly delineated prior to the development of convection. The analysis of the VAS retrievals identifies significant spatial gradients and temporal changes in the thermal and moisture fields, especially at times and locations between radiosonde observations. Direct retrievals of vertically integrated bulk precipitable water and lifted index are particularly useful in this case since they correspond well to features in the VAS imagery and provide a strong preconvective signature. The nature of the VAS instrument dictates that these bulk parameters should display more consistency in space and time than the level-specific parameters due to the poor vertical resolution of the VAS instrument. The detailed analyses also point to limitations in using VAS data. Even with nearly optimal conditions for passive remote sounding (generally clear skies, minimal orographic effects, and a rapidly changing moisture field), the VAS retrievals were still degraded in some regions by VAS instrument noise and calibration errors and unresolved cloud contamination. Another problem is the cloud-free nature of the instrument data set, which biases the results toward a drier environment. In spite of these and other limitations, the analyses demonstrate that the geosynchronous VAS can be used in a case study mode to produce high-resolution spatial and temporal measurements which are useful for the quantitative analysis of a cloud-free preconvective environment.With 16 Figures     

The settling behavior and benthic transport of fish feed pellets under steady flows

Settling and erosion experiments were carried out on a size range of fish feed pellets using an annular flume. A strong positive correlation was observed between settling rate and pellet dimension (pellet length, pellet dimeter, and equivalent sedimentation diameter). Erosion thresholds also showed a strong positive correlation with pellet dimensions. Experiments were also carried out to examine the effect of the number of pellets on erosion threshold of two sizes. The results show an asymptotic increase in erosion threshold with increasing number of pellets present, possibly due to sheltering effects. The chemical composition of the pellets was analyzed in terms of water and organic, carbon, and nitrogen contents as well as stable carbon and nitrogen isotopes. The results arising from this study will provide, information regarding potential tracers of waste feed material and help validate model predictions associated with dispersal of waste material.     

Molecular signature and sources of biochemical recalcitrance of organic C in Amazonian Dark Earths

Amazonian Dark Earths (ADE) are a unique type of soils developed through intense anthropogenic activities that transformed the original soils into Anthrosols throughout the Brazilian Amazon Basin. We conducted a comparative molecular-level investigation of soil organic C (SOC) speciation in ADE (ages between 600 and 8700 years B.P.) and adjacent soils using ultraviolet photo-oxidation coupled with ¹³C cross polarization-magic angle spinning nuclear magnetic resonance (CP-MAS NMR), synchrotron-based Fourier transform infrared-attenuated total reflectance (Sr-FTIR-ATR) and C (1s) near edge X-ray absorption fine structure (NEXAFS) spectroscopy to obtain deeper insights into the structural chemistry and sources of refractory organic C compounds in ADE. Our results show that the functional group chemistry of SOC in ADE was considerably different from adjacent soils. The SOC in ADE was enriched with: (i) aromatic-C structures mostly from H- and C-substituted aryl-C, (ii) O-rich organic C forms from carboxylic-C, aldehyde-C, ketonic-C and quinine-C, and (iii) diverse group of refractory aliphatic-C moieties. The SOC in adjacent soils was predominantly composed of O-alkyl-C and methoxyl-C/N-alkyl-C structures and elements of labile aliphatic-C functionalities. Our study suggests that the inherent molecular structures of organic C due to selective accumulation of highly refractory aryl-C structures seems to be the key factor for the biochemical recalcitrance and stability of SOC in ADE. Anthropogenic enrichment with charred carbonaceous residues from biomass-derived black C (BC) is presumed to be the precursor of these recalcitrant polyaromatic structures. Our results also highlight the complementary role that might be played by organic C compounds composed of O-containing organic C moieties and aliphatic-C structures that persisted for millennia in these anthropic soils as additional or secondary sources of chemical recalcitrance of SOC in ADE. These organic C compounds could be the products of: (i) primary recalcitrant biomolecules from non-BC sources or (ii) secondary processes involving microbial mediated oxidative or extracellular neoformation reactions of SOC from BC and non-BC sources; and stabilized through physical inaccessibility to decomposers due to sorption onto the surface or into porous structures of BC particles, selective preservation or through intermolecular interactions involving clay and BC particles.