溴素的有机化学──I．2，4，6－三溴苯甲酸溴代和非溴代芳酯的合成

用ｍ－氨基苯甲酸作原料，经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤，合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯，即；双（２，４，６－三溴苯甲酸）－２＇，３＇，５＇，６＇－四溴－１＇，４＇－苯二酯，２，４，６－三溴苯甲酸－２＇，３＇，４＇，５＇，６＇－五溴苯酯，２，４，６－三溴苯甲酸－２＇，４＇，６＇－三溴苯酯，２，４，６－三溴苯甲酸－４＇－溴苯酯，２，４，６－三溴苯甲酸－４＇－甲基苯酯和２，４，６－三溴苯甲酸苯酯．通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究，验证了合成产物的结构。     

Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.     

Distribution and number change of the Littorinidae (Gastropoda) on intertidal hard bed in the Jiulong River Estuary

There are 4 species of Littorinidae on the intertidal hard bed in the Jiulong River Estu-ary. They are Littorina scabra, L. brevicula, Nodilittorina pyramidalis pyramidalis and N.millegrana. Of these species, L. scabra is a dominant species. According to the results of in-vestigation, we find distribution patterns of the Littorinidae on intertidal hard bed in theestuary as follows: (1)There is no Littorinid species at Haicheng Station. (2)There is only Lit-     

Dinoflagellate cysts in recent marine sediment from Guangxi, China

Total of 33 species of dinoflagellate cysts were discovered from surface sediment in the searegion of Guangxi, among them 12 cyst types (Diplopsalopsis sp.1, D. sp. 2, D. sp. 3, Cochlodinium sp., Protoperidinium sp. 1, P. sp. 2, P. compressum , Scrippsiella sp. 1, S. sp. 2, Alexandrium sp. 1, A. sp. 2, A. sp. 3) were first reported from the South China Sea. And one cyst type (Cochlodinium sp.) was first reported in the world. Scrippsiella trochoidea is the dominant species in this area, accounting for 45% of all the cysts. There are 2 cysts of toxic dinoflagellate (Alexandrium tamarensis and Gymnodinium catenatum). But there is no relationship between cyst number and grain size distribution.     

厦门港岩石岸潮间带软体动物的生态

本文根据１９８２年２月至１９８３年２月在厦门港岩石岩潮间带采集的软体动物，论述了其种类组成，数量分布，生活型及影响软件动物分布的主要环境因子，厦门港岩石岸潮间带共发现软动物５４种。其中，多板类６种，腹足类３３种，双壳类１５种，优势种有僧帽牡蛎，黑荞麦蛤，复瓦小蛇螺，粗糙滨螺等。与６０年代初调查结果比较得出，厦门港岩石岸潮间带的软体动物群落是相对稳定的，潮汐是决定河口结果比较得出，厦门港岩石岩潮间带     

厦门港湾蟹类的分布

本文根据我所1980年8月至1981年10月厦门港湾海洋环境综合调查,选取其季度月(11,2,5,8月)资料,研究该港湾蟹类的种类组成、数量分布与季节变化。     

福建沿海沉积物中硫化物的分布

测定了福建沿海１７９个表层沉积物样品中硫化物的含量，潮间带含量范围为２．５０—１５２．０３ｍｇ·ｋｇ－１，浅海含量范围为２．５０—２９１．９７ｍｇ·ｋｇ－１。     

A study on benthic community structure in west of the Taiwan Strait and near the Taiwan Shoals

ＡｓｔｕｄｙｏｎｂｅｎｔｈｉｃｃｏｍｍｕｎｉｔｙｓｔｒｕｃｔｕｒｅｉｎｗｅｓｔｏｆｔｈｅＴａｉｗａｎＳｔｒａｉｔａｎｄｎｅａｒｔｈｅＴａｉｗａｎＳｈｏａｌｓ￥ＷｕＱｉｑｕａｎ；ＪｉａｎｇＪｉｎｘｉａｎｇ；ＸｕＨｕｉｚｈｏｕ；ＣａｉＥｒｘｉａｎｄＬｉｎ...     

VR-GIS技术在高压输电线选线中的应用研究——以康定-崇州500kv送电线路为例

VR-GIS技术是一门新兴技术,已经在很多领域得到广泛应用。本文基于ERDAS、ArcGIS、MapGIS等遥感和GIS专业软件,将VR-GIS技术应用到高压输电线选线中,制作康定-崇州500kv送电线路(大杠～沙坪段)走廊带的三维景观飞行模拟系统,再现研究区真实地形、地貌,使工作人员沉浸于虚拟环境中,为其分析和处理问题提供方便,解决因自然环境恶劣造成的外业调查困难等问题。     

Main Controlling Factors on Hydrocarbon Accumulation and Distribution in Marine Sedimentary Sequences in South China

Multiple source rock assemblages were deposited in the sedimentary provinces in South China in geologic history,and some of them were destructed by and some survived against multiple tectonic movements.Therefore,multiple sources,mixed sources,and uneven distribution of sources occurred in the marine sedimentary basins in South China during the late stage of hydrocarbon pooling.Epidiagenesis of the marine carbonate reservoirs and its modification to reservoir poroperm characteristics determined the formation and the scale of natural gas pools.The exploration practices show that the large to medium gas fields mainly occur in areas with high-quality reservoirs.Detailed study of the paleo-oil accumulations and typical oil and gas reservoirs reveals that the basins experienced multiphase superimposition and modification,leading to the distribution of the Paleozoic paleo-oil accumulations and bitumen in the peripheral areas.The phenomenon that oil and gas production concentrates in the Sichuan basin indicates that the overall sealing conditions of a basin determine the oil/gas potentials and the scale of oil and gas production.This is a critical factor controlling the accumulation and distribution of gas in the marine sequences in South China.The early oil and gas pools in the Yangtze platform left billions of bitumen in the peripheral areas due to the destruction of seals.Since the Himalayan,"late-generation and late-accumulation" gas pools represented by the gas pools in the Sichuan (四川) basin were formed in the marine sedimentary sequences in South China as a result of the change of the sealing conditions.Current gas discoveries appear to be "paleo-generation and paleo-accumulation" gas pools but actually are "late-generation and late-accumulation" gas pools.These patterns of hydrocarbon pooling clearly depict themselves in western Sichuan basin and Weiyuan (威远)gas field.It is revealed that the gas pools in the Sichuan basin were mainly formed as a result of hydrocarbon phase change (thermal cracking of oil to gas),miscible migration,and dynamic equilibration since the Himalayan.A large number of gas pools were formed in the Himalayan and the gas pools in the marine sequences are characterized by late pooling; this kind of gas fields/pools are controlled by:(1) effectiveness of modification and superimposition of the marine basins,(2) effectiveness of the source rocks,(3) effectiveness of the overall preservation conditions,and (4) effectiveness of plays.