Drastic shift in lava geochemistry in the volcanic-front to rear-arc region of the Southern Kamchatkan subduction zone: Evidence for the transition from slab surface dehydration to sediment melting

The shift of lava geochemistry between volcanic front to rear-arc volcanoes in active subduction zones is a widespread phenomenon. It is somehow linked to an increase of the slab surface depth of the subducting oceanic lithosphere and increasing thickness of the mantle wedge and new constraints for its causes may improve our understanding of magma generation and element recycling in subduction zones in general. As a case study, this paper focuses on the geochemical composition of lavas from two adjacent volcanic centres from the volcanic front (VF) to rear-arc (RA) transition of the Southern Kamchatkan subduction zone, with the aim to examine whether the shift in lava geochemistry is associated with processes in the mantle wedge or in the subducted oceanic lithosphere or both. The trace element and O-Sr-Nd-Hf-Pb (double-spike)-isotopic composition of the mafic Mutnovsky (VF) and Gorely (RA) lavas in conjunction with geochemical modelling provides constraints for the degree of partial melting in the mantle wedge and the nature of their slab components. Degrees of partial melting are inferred to be significantly higher beneath Mutnovsky (∼18%) than Gorely (∼10%). The Mutnovsky (VF) slab component is dominated by hydrous fluids, derived from subducted sediments and altered oceanic crust, eventually containing minor but variable amounts of sediment melts. The composition of the Gorely slab component strongly points to a hydrous silicate melt, most likely mainly stemming from subducted sediments, although additional fluid-contribution from the underlying altered oceanic crust (AOC) is likely. Moreover, the Hf-Nd-isotope data combined with geochemical modelling suggest progressive break-down of accessory zircon in the melting metasediments. Therefore, the drastic VF to RA shift in basalt chemistry mainly arises from the transition of the nature of the slab component (from hydrous fluid to melt) in conjunction with decreasing degrees of partial melting within ∼15 km across-arc. Finally, systematic variations of key inter-element with high-precision Pb-isotope ratios provide geochemical evidence for a pollution of the Mutnovsky mantle source with Gorely melt components but not vice versa, most likely resulting from trench-ward mantle wedge corner flow. We also present a geodynamic model integrating the location of the Mutnovsky and Gorely volcanic centres and their lava geochemistry with the recently proposed thermal structure of the southern Kamchatkan arc and constraints about phase equilibria in subducted sediments and AOC. Herein, the slab surface hosting the subducted sediments suffers a transition from dehydration to melting above a continuously dehydrating layer of AOC. Wider implications of this study are that an onset of (flush-) sediment melting may ultimately be the main trigger for the VF to RA transition of lava geochemistry in subduction zones.     

Jebel al Abyad: A recent alkalic volcanic complex in western Saudi Arabia

Arabia, a supposedly aseismic plate, has been the site of extensive alkalic volcanism during the past 10 m.y. The products of this activity, which extend intermittently from Syria to south central Saudi Arabia, are strongly alkalic and primarily basic in composition. Examination of specimens from the Jebel al Abyad area in Saudi Arabia, which displays a particularly wide variety of rock types, suggests the parental melt moved rapidly from depth to high level chambers where most of the chemical variation was produced by crystal fractionation. N-S dilational fissures of regional extent seem to have allowed the melt easy and rapid egress and a low degree of partial melting in the mantle could account for the high total alkalis content. The high K/Rb ratio, which also characterizes the granitic rocks of the underlying Precambrian basement, is thought to reflect a source mantle particularly low in rubidium.     

Radiocarbon redating of contaminated samples from a tropical volcano: the Mansion ‘Series’ of St Kitts,West Indies

Heavy rainfall and dense vegetation on tropical volcanoes produce abundant carbonized wood in pyroclastic deposits, in addition to easy contamination of this wood by root systems and soluble humic material. Because the physical nature of the charcoal varies, some samples are more prone to contamination. Two independent studies of the same volcano, Mt Liamuiga on St Kitts in the Lesser Antilles, sometimes using samples from the same carbonized tree, yielded a systematic difference in radiocarbon ages. An exchange of samples and a re-investigation of three physically distinct types of charcoal yielded the following results. Rare, hard, dense charcoal, lacking contamination, which had yielded a spurious age of 2860 years bp, was redated at 1845±58 years bp. Common soft, friable charcoal with good cellular structure proved to be susceptible to contamination. A field decontamination technique utilized by one group seems significant as it yields older ages than when only routine laboratory pre-treatment was used, indicating that the latter technique only partly removes the dried and hard residue produced by the decomposition of modern plant rootlets. A previous date of 24870 years bp obtained from powdery charcoal in a horizon beneath the Mansion Series contradicted ages older than 41000 years bp from common friable charcoal in the lower Mansion Series. The soft powdery charcoal was re-investigated using a sample collected a few centimeters from the original, although field decontamination of this sample was not possible, more extensive laboratory treatment yielded an age of ca. 43000 years bp, again proving that routine laboratory pretreatments are inadequate. A revised geochronology for the Mansion Series is described and a cautionary discussion is presented for the benefit of investigators using radiocarbon ages to date volcanic deposits.     

Relationships between lightning activity and various thundercloud parameters: satellite and modelling studies

The lightning frequency model developed by Baker et al. [Baker, M.B., Christian, H.J., Latham, J., 1995. A computational study of the relationships linking lightning frequency and other thundercloud parameters, Q. J. R. Meteorol. Soc., 121, 1525–1548] has been refined and extended, in an effort to provide a more realistic framework from which to examine computationally the relationships that might exist between lightning frequency f (which is now being routinely measured from a satellite, using the NASA/MSFC Optical Transient Detector (OTD)) and a variety of cloud physical parameters. Specifically, superior or more comprehensive representations were utilised of: (1) glaciation via the Hallett–Mossop (H–M) process; (2) the updraught structure of the model cloud; (3) the liquid-water-content structure of the model cloud; (4) the role of the reversal temperature T_rev in influencing lightning characteristics; (5) the critical breakdown field for lightning initiation; and (6) the electrical characteristics of the ice crystal anvil of the model cloud. Although our extended studies yielded some new insights into the problem, the basic pattern of relationships between f and the other parameters was very close to that reported by Baker et al. (1995). The more elaborate treatment of T_rev restricted somewhat the range of conditions under which reverse-polarity lightning could be produced if the cloud glaciated via H–M, but confirmed the earlier conclusion that such lightning would not occur if the glaciation was of the Fletcher type. The computations yielded preliminary support for the hypothesis that satellite measurements of f might be used to determine values of the ice-content of cumulonimbus anvils: a parameter of climatological importance. The successful launch and continuing satisfactory functioning of the OTD [Christian, H.J., Goodman, S., 1992. Global observations of lightning from space, Proc. 9th Int. Conf. on Atmospheric Electricity, St. Petersburg, pp. 316–321; Christian, H.J., Blakesee, R.J., Goodman, S.J., 1992. Lightning imaging sensor (LIS) for the earth observing system. NASA Tech. Memorandum, 4350] make it possible—with a high degree of precision—to measure lightning location, occurrence time and frequency f over extensive areas of the Earth's surface. Measured global distributions of lightning and associated lightning stroke radiance demonstrate that: lightning activity is particularly pronounced over the tropics, much greater over land than over the oceans, and exhibits great seasonal variability; lightning radiance tends to be greater over the oceans, less when lightning activity is high, and greater in the Northern Hemisphere winter than summer.     

Field Comparison of Micropurging vs. Traditional Ground Water Sampling

Micropurge sampling of ground water wells has been suggested as a possible replacement to traditional purge and sample methods. To compare methods, duplicate ground water samples were collected at two field sites using iraditional and micropurge methods. Samples were analyzed for selected organic and inorganic constituents, and the results were compared statistically. Analysis of the data using the nonparametric sign test indicates that within a 95 percent confidence interval, there was no significant difference between the two methods for the site contaminants and the majority of analytes. These analytical results were supported by visual observations with the colloidal borescope, which demonstrated impacts on the flow system in the well when using traditional sampling methods. Under selected circumstances, the results suggest replacing traditional sampling with micropurging based on reliability, cost, and waste minimization.     

Tracking Solar Active Region Outflow Plasma from Its Source to the Near-Earth Environment

Seeking to establish whether active-region upflow material contributes to the slow solar wind, we examine in detail the plasma upflows from Active Region (AR) 10978, which crossed the Sun’s disc in the interval 8 to 16 December 2007 during Carrington rotation (CR) 2064. In previous work, using data from the Hinode/EUV Imaging Spectrometer, upflow velocity evolution was extensively studied as the region crossed the disc, while a linear force-free-field magnetic extrapolation was used to confirm aspects of the velocity evolution and to establish the presence of quasi-separatrix layers at the upflow source areas. The plasma properties, temperature, density, and first ionisation potential bias [FIP-bias] were measured with the spectrometer during the disc passage of the active region. Global potential-field source-surface (PFSS) models showed that AR 10978 was completely covered by the closed field of a helmet streamer that is part of the streamer belt. Therefore it is not clear how any of the upflowing AR-associated plasma could reach the source surface at 2.5 R_⊙ and contribute to the slow solar wind. However, a detailed examination of solar-wind in-situ data obtained by the Advanced Composition Explorer (ACE) spacecraft at the L₁ point shows that increases in O⁷⁺/O⁶⁺, C⁶⁺/C⁵⁺, and Fe/O – a FIP-bias proxy – are present before the heliospheric current-sheet crossing. These increases, along with an accompanying reduction in proton velocity and an increase in density are characteristic of both AR and slow-solar-wind plasma. Finally, we describe a two-step reconnection process by which some of the upflowing plasma from the AR might reach the heliosphere.     

Evidence for interchange reconnection between a coronal hole and an adjacent emerging flux region

Coronal holes are regions of dominantly monopolar magnetic field on the Sun where the field is considered to be ‘open’ towards interplanetary space. Magnetic bipoles emerging in proximity to a coronal hole boundary naturally interact with this surrounding open magnetic field. In the case of oppositely aligned polarities between the active region and the coronal hole, we expect interchange reconnection to take place, driven by the coronal expansion of the emerging bipole as well as occasional eruptive events. Using SOHO/EIT and SOHO/MDI data, we present observational evidence of such interchange reconnection by studying AR 10869 which emerged close to a coronal hole. We find closed loops forming between the active region and the coronal hole leading to the retreat of the hole. At the same time, on the far side of the active region, we see dimming of the corona which we interpret as a signature of field line ‘opening’ there, as a consequence of a topological displacement of the ‘open’ field lines of the coronal hole. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Climate change and coral reef bleaching: An ecological assessment of long-term impacts,recovery trends and future outlook

Since the early 1980s, episodes of coral reef bleaching and mortality, due primarily to climate-induced ocean warming, have occurred almost annually in one or more of the world's tropical or subtropical seas. Bleaching is episodic, with the most severe events typically accompanying coupled ocean–atmosphere phenomena, such as the El Niño-Southern Oscillation (ENSO), which result in sustained regional elevations of ocean temperature. Using this extended dataset (25+ years), we review the short- and long-term ecological impacts of coral bleaching on reef ecosystems, and quantitatively synthesize recovery data worldwide. Bleaching episodes have resulted in catastrophic loss of coral cover in some locations, and have changed coral community structure in many others, with a potentially critical influence on the maintenance of biodiversity in the marine tropics. Bleaching has also set the stage for other declines in reef health, such as increases in coral diseases, the breakdown of reef framework by bioeroders, and the loss of critical habitat for associated reef fishes and other biota. Secondary ecological effects, such as the concentration of predators on remnant surviving coral populations, have also accelerated the pace of decline in some areas. Although bleaching severity and recovery have been variable across all spatial scales, some reefs have experienced relatively rapid recovery from severe bleaching impacts. There has been a significant overall recovery of coral cover in the Indian Ocean, where many reefs were devastated by a single large bleaching event in 1998. In contrast, coral cover on western Atlantic reefs has generally continued to decline in response to multiple smaller bleaching events and a diverse set of chronic secondary stressors. No clear trends are apparent in the eastern Pacific, the central-southern-western Pacific or the Arabian Gulf, where some reefs are recovering and others are not. The majority of survivors and new recruits on regenerating and recovering coral reefs have originated from broadcast spawning taxa with a potential for asexual growth, relatively long distance dispersal, successful settlement, rapid growth and a capacity for framework construction. Whether or not affected reefs can continue to function as before will depend on: (1) how much coral cover is lost, and which species are locally extirpated; (2) the ability of remnant and recovering coral communities to adapt or acclimatize to higher temperatures and other climatic factors such as reductions in aragonite saturation state; (3) the changing balance between reef accumulation and bioerosion; and (4) our ability to maintain ecosystem resilience by restoring healthy levels of herbivory, macroalgal cover, and coral recruitment. Bleaching disturbances are likely to become a chronic stress in many reef areas in the coming decades, and coral communities, if they cannot recover quickly enough, are likely to be reduced to their most hardy or adaptable constituents. Some degraded reefs may already be approaching this ecological asymptote, although to date there have not been any global extinctions of individual coral species as a result of bleaching events. Since human populations inhabiting tropical coastal areas derive great value from coral reefs, the degradation of these ecosystems as a result of coral bleaching and its associated impacts is of considerable societal, as well as biological concern. Coral reef conservation strategies now recognize climate change as a principal threat, and are engaged in efforts to allocate conservation activity according to geographic-, taxonomic-, and habitat-specific priorities to maximize coral reef survival. Efforts to forecast and monitor bleaching, involving both remote sensed observations and coupled ocean–atmosphere climate models, are also underway. In addition to these efforts, attempts to minimize and mitigate bleaching impacts on reefs are immediately required. If significant reductions in greenhouse gas emissions can be achieved within the next two to three decades, maximizing coral survivorship during this time may be critical to ensuring healthy reefs can recover in the long term.     

AN EVALUATION OF SAS/GRAPH SOFTWARE FOR COMPUTER CARTOGRAPHY1

The SAS® computer software system, widely used and respected for its capabilities in statistical analysis and data base management, now includes a new set of graphic and cartographic procedures called SAS GRAPH?. We have used these cartographic procedures in research on mapping ethno-cultural census data from metropolitan areas in Ontario and in undergraduate and graduate courses in computer cartography. On the basis of that experience, we describe and evaluate SAS/GRAPH'S cartographic capabilities and illustrate with maps drawn by various devices.