Modelling The Mean Velocity Profile In The Urban Canopy Layer

A simple model originally derived for meanwind speed profiles in vegetative canopy flows ismodified for application to arrays ofthree-dimensional surface obstacles (cubes), whichcould be representative of a simple urban-typesurface. It is shown that for cube arrays that arenot too densely packed, the predicted exponentialvelocity profile provides an adequate fit to thespatially averaged velocity profile (u(z))within the obstacle canopy. Application of the model to a set of wind-tunnel dataallows for the evaluation of an empirical fittingparameter called the attenuation coefficient. This isrelated to the turbulence length scale, which can befound by manipulating the results of thegradient-diffusion model used to derive the velocityprofile. The results show a reduction of theturbulence length scale with increasing obstaclepacking density. By assuming a linear transition fromthis length scale at the top of the canopy to theclassical Prandtl length scale in the overlyinginertial sublayer, an acceptable model is obtained forthe full velocity profile within simple obstaclearrays, from the ground up to the overlyingsemi-logarithmic region.     

Pantelleritic obsidians from the volcano Chabbi (Ethiopia)

Chabbi, a Quaternary volcano in the Ethiopian Rift, appears to be unique in having erupted only non-porphyritic pantelleritic obsidians showing a very restricted range in composition. Petrogenetic schemes for deriving these lavas are discussed, and it is suggested that some degree of effective superheating, followed by failure of the magmas to crystallise because of their dryness (and hence high viscosity) can account at least for the absence of phenocrysts.     

Inertinite-rich Tertiary coals from the Zeya–Bureya Basin, Far Eastern Russia

Selected Tertiary coals from the Zeya–Buryea Basin, Far Eastern Russia, were investigated for aspects of their coal type, rank, depositional environment and post-depositional history. The coals have been examined in outcrop (lithotype logging), microscopically (maceral, reflectance and fluorescence), and geochemically (proximate analysis).Two laterally extensive coal-bearing horizons occur: one of Palaeocene age and the other of early Miocene age. The Palaeocene coals were investigated in active open-cut mines at Raichikhinsk and Yerkovtsi and the early Miocene deposit in an abandoned open-cut mine at Cergeyevka.Palaeocene coals at Raichikhinsk and Yerkovtsi were indistinguishable from each other macroscopically, microscopically, and geochemically. The deposits were sufficiently coalified that brightness logging could be undertaken. Dull coals, with numerous fusainous wisps, were dominant. Four dulling-up sequences, which represent stacked peat deposits, were observed at Raichikhinsk. At Yerkovtsi, only a small section of the middle of the seam, which was mostly dull and muddy coal, was investigated. Petrographically, these coals were dominated by inertinite group macerals, which is unusual in non-Gondwanan coals and rare in the Tertiary. Rank classification was problematic with volatile matter (VM) content of vitrain (daf), macroscopic appearance, and microscopic textures suggesting subbituminous B rank, but carbon content, moisture content and specific energy indicating a lignite rank.Notwithstanding complications of rank, estimates of the maximum-range burial depths were calculated. Taking the VM (daf) content of vitrain as 48%, burial depth estimates range from 900 m for a high geothermal gradient and long heating time to a maximum of 3300 m for a low geothermal gradient and short heating time. These estimates are maxima as the coal rank may be lower than implied by the VM.The Cergeyevka deposit is a soft brown coal. Limited sampling of the upper-most portion indicated a high moisture content (75% daf) and an unusual, hydrogen-rich geochemistry. Lack of identifiable liptinites using either reflected light or fluorescence microscopy suggested a significant bituminite component. Otherwise, the coals appear to be typical for the Tertiary. An estimate of 125 m maximum burial depth was obtained using the bed-moisture content of the coal, which is around the present burial depth.Comparison of present-day thicknesses with inferred burial depths suggests that at least 500 m of section is missing between the Palaeocene coals and the early Miocene coals.Palaeoenvironmental considerations suggest that fire played a significant role in the accumulation of the peats at Raichikhinsk and Yerkovtsi. At Cergeyevka, peat accumulation ended by drowning of the mire.Two tuff beds were recognised within the seam at Raichikhinsk and one in the seam at Yerkovtsi. Correlation of the tuff beds is uncertain but they should prove useful in regional coal seam correlation and interpreting coal depositional environments. Geochemical analysis by XRF was complicated by high loss-on-ignition (LOI) values. Despite extensive alteration, an acid igneous source is implied from the presence of free quartz and TiO₂/Al₂O₃ ratios of 0.02 to 0.05.     

Structure and chemistry in the hot molecular core G34.3+0.15

New multifrequency spatial and spectral studies of the hot molecular core associated with the ultracompact HII region G34.3+0.15 have demonstrated an extremely rich chemistry in this archetypal hot core and revealed differing spatial structure between certain species which may be a dynamical effect of chemical evolution. The structure of the hot core has been studied with the JCMT in the high excitation J=19-18 and J=18-17 lines of CH₃CN and with the Nobeyama Millimetre Array at 4 arc resolution in the J=6-5 transition. Comparison with a VLA NH₃(3,3) map shows a displacement between peak emission in the two chemical species which is consistent with chemical processing on a time scale comparable to the dynamical time scale of 10⁵ yrs.A 330-360 GHz spectral survey of the hot core with the JCMT has detected 358 spectral lines from at least 46 distinct chemical species, including many typical of shocked chemistry while other species indicate abundances that reflect the chemistry of a previous cold phase. The first unambiguous detection of ethanol in hot gas has been made. Observations of 14 rotational transitions of this molecule yield a temperature of 125 K and column density 2×10¹⁵ cm^–2. This large abundance cannot be made by purely gas-phase processes and it is concluded that ethanol must have formed by grain surface chemistry.     

Climate variability and physical forcing of the food webs and the carbon budget on panarctic shelves

Brief overviews of the Arctic’s atmosphere, ice cover, circulation, primary production and sediment regime are given to provide a conceptual framework for considering panarctic shelves under scenarios of climate variability. We draw on past ‘regional’ studies to scale-up to the panarctic perspective. Within each discipline a synthesis of salient distributions and processes is given, and then functions are noted that are critically poised and/or near transition and thereby sensitive to climate variability and change. The various shelf regions are described and distinguished among three types: inflow shelves, interior shelves and outflow shelves. Emphasis is on projected climate changes that will likely have the greatest impact on shelf-basin exchange, productivity and sediment processes including (a) changes in wind fields (e.g. currents, ice drift, upwelling and downwelling); (b) changes in sea ice distribution (e.g. radiation and wind regimes, enhanced upwelling and mixing, ice transport and scour resuspension, primary production); and (c) changes in hydrology (e.g. sediment and organic carbon delivery, nutrient supplies). A discussion is given of the key rate-controlling processes, which differ for different properties and shelf types, as do the likely responses; that is, the distributions of nutrients, organic carbon, freshwater, sediments, and trace minerals will all respond differently to climate forcing.A fundamental conclusion is that the changes associated with light, nutrients, productivity and ice cover likely will be greatest at the shelf-break and margins, and that this forms a natural focus for a coordinated international effort. Recognizing that the real value of climate research is to prepare society for possible futures, and that such research must be based both on an understanding of the past (e.g. the palaeo-record) as well as an ability to reliably predict future scenarios (e.g. validated models), two recommendations emerge: firstly, a comprehensive survey of circumpolar shelf-break and slope sediments would provide long-term synchronous records of shelf-interior ocean exchange and primary production at the shelf edge; secondly, a synoptic panarctic ice and ocean survey using heavy icebreakers, aircraft, moorings and satellites would provide the validation data and knowledge required to properly model key forcing processes at the margins.     

Indications of P450 monooxygenase activities in beluga (Delphinapterus leucas) and narwhal (Monodon monoceros) from patterns of PCB, PCDD and PCDF accumulation

Selective accumulation of PCDDs, PCDFs and PCB congeners was investigated in beluga (Delphinapterus leucas), narwhal (Monodon monoceros) and several species at the same trophic level in two areas of Canada. There was a much higher relative abundance of meta-para-unsubstituted PCBs in the cetaceans compared with other species. This suggests that activity of cytochrome P450 monooxygenase enzymes causing CYP2B-type metabolism was relatively low in beluga and narwhal. Lower relative levels of 2,3,7,8-TCDD occurred in beluga from both areas, and selective reduction of toxic non-ortho PCBs occurred in the highly PCB-contaminated St Lawrence beluga. These compounds are potent inducers of cytochrome P450 CYP 1A-type enzymes, suggesting that such an enzyme with the capability of metabolizing TCDD-like substrates is present in beluga and narwhal. SIMCA principal components analysis of PCB congener patterns showed that the two cetaceans were in a statistically significant different class than the other species. Variables (congeners) with the greatest separation power between classes were mainly those defined by the selective metabolism rules.     

High inside corners at ridge-transform intersections

A large topographic high commonly occurs near the intersection of a rifted spreading center and a transform fault. The high occurs at the inside of the 90° bend in the plate boundary, and is called the high inside corner, while the area across the spreading center, the outside corner, is often anomalously low. To better understand the origin of this topographic asymmetry, we examine topographic maps of 53 ridge-transform intersections. We conclude the following: (1) High inside corners occur at 41 out of 42 ridge-transform intersections at slow spreading ridges, and thus should be considered characteristic and persistent features of rifted slow spreading ridges. They are conspicuously absent at fast spreading ridges or at spreading centers that lack a rift valley. (2) High inside corners occur wherever an axial rift valley is present, and an approximate 1:1 correlation exists between the relief of the rift valley and the magnitude of the asymmetry. (3) Large high inside corners occur at both long and short transform offsets. (4) High inside corners at long offsets decay off-axis faster than predicted by the square root of age cooling model, precluding a thermalisostatic origin, but consistent with dynamic or flexural uplift models.These observations support the existing hypothesis that the asymmetry is due to the contrast in lithospheric coupling that occurs in the active transform versus the inactive fracture zone. Active faulting in the transform breaks the lithosphere along a high angle fault, permitting vertical movement of the inside corner block, whereas the inactive fracture zone forms a weld that couples the outside corner to the adjacent block, preventing it from rising. Large asymmetry at very short transform offsets appears to be caused by the added effect of a second uplift mechanism. Young lithosphere in the rift valley couples to the older plate, and when it leaves the rift valley it lifts the older plate with it. At very short offsets, this coupled uplift acts upon the high inside corner; at long offsets, it may upwarp the older plate or its expression may be muted.     

Near bottom magnetic profile across the Red Sea

Results are presented from a high precision geophysical profile made at an altitude of about 100 m above the sea floor with the Deep Two instrument package, crossing the Red Sea at 17°30N. The emphasis is on the analysis and interpretation of the magnetic field, including an inversion which removes the distortions due to bathymetry and the orientation with respect to the earth's main field vector. The spreading rates are determined precisely and found to be highly asymmetric: only 5 mm yr^-1 to the east and up to 10 mm yr^-1 to the west. We conclude that the axis of spreading is located on a volcanic ridge, rather than on the axial graben, based on the presence of a zone of high magnetization. The magnetization high (40 Am^-1) is about twice as great as found on the Mid-Atlantic Ridge with the same instrument and analysis. The quality of the recording of the magnetic anomalies in the oceanic crust is much greater than expected for such a low spreading rate.     

Deep-Tow magnetics near 20°S on the East Pacific Rise: A study of short wavelength anomalies at a very fast spreading center

Six Deep-Tow magnetic profiles across the axis of the East Pacific Rise [EPR] in two small areas between 19°25 and 20°10S were collected during the 1983 Protea 1 cruise of the R/V Melville. These near-bottom profiles are of extremely high resolution allowing the interpretation of very short wavelength features. We have inverted the magnetic field data to determine the rock magnetization distribution near the axis of this ultrafast speading center (162 mm yr^-1). The solutions reveal large amplitude (up to 35 A m^-1) short wavelength (1–3 km) variations in magnetization. Specifically all crossings show a narrow (0.5 to 1.5 km) low in magnetization superimposed on a broader (2.5 to 4 km) high directly over the ridge axis. Four profiles in the northern area (19°25 to 19°33S) also show symmetrical near-axis (within 4 km) lows which are remarkably continuous along strike. Explanations for the short-wavelength variations are discussed which fall into the following categories: (1) variations in the thickness of the magnetized layer, (2) variations in rock chemistry (e.g. alteration due to hydrothermal activity), and (3) paleofield intensity variations. None of the mechanisms discussed alone adequately explain the observed phenomena in the study area or on a world-wide scale. Further sampling and high resolution surveying will be required in order to accurately determine the relative importance of the mechanisms discussed.     

Tracing the inputs and fate of marine and terrigenous organic matter in Arctic Ocean sediments: A multivariate analysis of lipid biomarkers

An understanding of the carbon cycle within arctic sediments requires discrimination between the terrigenous and marine components of organic carbon, insight into the removal mechanisms for labile carbon during burial and appreciation of shelf-to-basin processes. Using a large data set of multiple molecular organic markers (alkanes, alkanols, sterols, saturated and unsaturated fatty acids, dicarboxylic acids), we apply (1) principal components analysis (PCA) to obtain a robust comparison of biomarker compositions in Arctic Ocean sediments, (2) geometric mean (GM) linear regression of the PCA variables to estimate the relative contributions of labile/marine and stable/terrigenous sources to each biomarker and (3) the slope of the GM regression of each biomarker with TOC to provide a novel measure of the removal rate of each biomarker relative to phytol. The PCA- and TOC-based indices generally increase together: biomarkers with very high TOC-based removal rates such as the saturated and unsaturated n-alkanoic acids generally have a high labile/marine content from PCA, while the sterols have low removal rates, but exhibit a range of labile/marine content values and the n-alkanes and n-alkanols have low values for both. A dominant feature of all PCA models examined is a progressive decrease in the autochthonous/marine biomarkers with each increase in sediment core depth, which points to a universal diagenetic alteration of organic carbon with depth in the cores. The PCA model also displays a shelf to basin trend that is non-diagenetic and implies the ongoing (centuries or more) delivery of long-chain n-alkanes, n-alcohols and n-alkanoic acids in a matrix that is pre-formed and well-preserved within the sediments. Terrigenous biomarker distributions within the PCA model suggest that atmospheric transport of plant waxes in aerosols and the water borne transport of very fine plant macerals likely have significant roles in the export of these vascular plant biomarkers to the basins. Biomarker ratios and profiles of the PCA-based labile/marine content with core depth indicate that the PCA model is more strongly influenced by the biomarker lability than the marine content, while increases in the marine content are largely responsible for the shifts in composition for near-surface core sections.