Lifespan mercury accumulation pattern in Liza aurata: Evidence from two southern European estuaries

Mercury accumulation throughout the lifespan of Liza aurata (Risso, 1810) was analysed in four tissues (muscle, gills, liver and brain) in two southern European coastal ecosystems with distinct mercury contamination. Specimens from four to five age classes were captured in two sampling sites in the Ria de Aveiro (Laranjo bay and Mira), a system historically contaminated by industrial mercury, and in one site in the Mondego estuary, assumed as a mercury-free ecosystem. Mercury concentration in all tissues was found to be significantly higher in the Ria de Aveiro (Laranjo bay) compared to the Mondego, in accordance with the environmental contamination (water, sediments and suspended particulate matter). Significant differences inside the Ria de Aveiro (between the Mira and Laranjo bay) were only detected in the liver. This tissue registered the highest levels of mercury (ranging from 0.11 to 4.2 μg g⁻¹) in all sampling sites, followed by muscle, brain, and gills. In all sampling sites and tissues was denoted a mercury dilution pattern along the lifecycle (except in liver at the Mondego, the reference area where the concentrations are always very low). An exponential trend was found in the metal age variation patterns in Laranjo (the most contaminated area) and a linear trend in the Mira and the Mondego (the least contaminated areas). Organic mercury concentration in muscle generally accounted for over 95% of total mercury concentration, and followed the same accumulation pattern of total mercury. This fish species is of lesser importance in mercury transfer to adjacent coastal areas and although the consumption of fish from Laranjo may present some risk for the humans, this risk decreases with fish age/size.     

A methodology for structural analysis and optimization of riser connection joints

In riser structural systems, the region where the riser is connected to the platform is critical due to the development of high stress levels. To reduce the stress concentration in this region, bend stiffeners and stress joints are used in order to provide a gradual stiffness transition between the riser and the platform. The present paper presents an optimization design approach for bend stiffeners and stress joints, using a slender beam procedure for the connection joint analysis and an evolution strategies multi-objective optimization algorithm. This approach produces similar results when compared to a finite element analysis of the complete riser, but with significant reduction of computational costs. Numerical examples are presented, showing the efficiency and robustness of the suggested methodology.     

Investigation of equilibria of a satellite subjected to gravitational and aerodynamic torques

Attitude motion of a satellite subjected to gravitational and aerodynamic torques in a circular orbit is investigated. In special case, when the center of pressure of aerodynamic forces is located on one of the principal central axes of inertia of the satellite, all equilibrium orientations are determined. Necessary and (or) sufficient conditions of stability are obtained for each equilibrium orientation. Evolution of domains where stability conditions take place is investigated. All bifurcation values of parameters corresponding to qualitative change of domains of stability are determined.     

Electronic Sputtering Analysis of Astrophysical Ices

Experimental results on fast ion collision with icy surfaces having astrophysical interest are presented. ²⁵²Cf fission fragments projectiles were used to induce ejection of ionized material from H₂O, CO₂, CO, NH₃, N₂, O₂ and Ar ices; the secondary ions were identified by time-of-flight mass spectrometry. It is observed that all the bombarded frozen gas targets emit cluster ions which have the structure X_nR^±, where X is the neutral ice molecule and R^± is either an atomic or a molecular ion. The shape of the positive or negative ion mass spectra is characterized by a decreasing yield as the emitted ion mass increases and is generally described by the sum of two exponential functions. The positive ion water ice spectrum is dominated by the series (H₂O)_nH₃O⁺ and the negative ion spectrum by the series (H₂O)_nOH⁻ and (H₂O)_nO⁻. The positive ion CO₂ ice spectrum is characterized by R⁺ = C⁺, O⁺, CO⁺, O₂⁺ or CO₂⁺ and the negative one by R⁻ = CO₃⁻. The dominant series for ammonia ice correspond to R⁺ = NH₄⁺ and to R⁻ = NH₂⁻. The oxygen series are better described by (O₃)_nO_m⁺ secondary ions where m = 1, 2 or 3. Two positive ion series exist for N₂ ice: (N₂)_nN₂⁺ and (N₂)_nN⁺. For argon positive secondary ions, only the (Ar)_nAr⁺ series was observed. Most of the detected molecular ions were formed by one-step reactions. Ice temperature was varied from ∼20 K to complete sublimation.     

Vessel biofouling as an inadvertent vector of benthic invertebrates occurring in Brazil

This article reviews the literature involving benthic invertebrates that are cited in association with hull fouling, reporting the species that occur on the Brazilian coast and evaluating the importance of this vector for the introduction of nonindigenous and cryptogenic invertebrates in Brazil. It discusses some of the strategies that were used by the species that allowed for their overseas transport and made it easier to cross natural barriers that otherwise would have been obstacles to their dispersion. The compiled data list 343 species (65% nonindigenous and 35% cryptogenic), mainly from the northwestern Atlantic Ocean. The traveling fauna, composed mostly of cosmopolitan species (70.3%), is primarily euryhaline and marine stenohaline, with sessile and sedentary habits. After delineating the shipborne species’ ecological profiles and traveling strategies and evaluating their overlapping vectors, we concluded that hull vessels were the main vector of introduction to the Brazilian coast for 89.8% of the compiled species.     

Fish consumption and risk of contamination by mercury---considerations on the definition of edible parts based on the case study of European sea bass

In the present study, the risk to humans by consuming European sea bass (Dicentrarchus labrax), captured at three sites along a Hg contamination gradient, was evaluated by comparing muscle and kidney total Hg (T-Hg) levels with the European regulations for marketed fish. Moreover, T-Hg and organic Hg (O-Hg) levels in muscle were compared with the Provisional Tolerable Weekly Intake (PTWI) and the Reference Dose (RfD). Although T-Hg levels in muscle were below the European value allowable for marketed fish, kidney’s levels were higher than the set value, stressing the importance of redefining the concept of edible tissue and which tissues should be considered. Mercury weekly ingestion in the contaminated areas was higher than the PTWI, and O-Hg daily ingestion rates were higher than the RfD in all sampling sites. Thus, populations consuming sea bass from the contaminated sites may be at risk, with particular relevance for children and pregnant women.     

Stability of colour-flavour locked quark matter with three massive quark flavours

The Kadomtsev-Petviashvili-Burgers (KPB) equation is derived for coupled drift acoustic shock waves in a partially ionized non-uniform pair-ion-electron (PIE) plasma in the presence of both density and temperature gradients respectively. Both linear and nonlinear studies are presented. The nonlinear KPB equation is derived in the small amplitude approximation method and its solution is found using the tanh method. The numerical calculations also presented for PIE plasmas of fullerene plasma for illustration keeping in view the recent experiments. The effect of density and temperature inhomogeneities on the nature of the shock is also highlighted. The role of the velocity of the nonlinear structure with regard to the density and temperature gradients driven drift velocities is also pointed out and the effect of ion-neutral collision frequency is also investigated. This work may be useful for future laboratory experimental investigations on pair-ion-electron plasmas.     

Stability of the time‐domain analysis method including a frequency‐dependent soil–foundation system

A number of methods have been proposed that utilize the time‐domain transformations of frequency‐dependent dynamic impedance functions to perform a time‐history analysis. Though these methods have been available in literature for a number of years, the methods exhibit stability issues depending on how the model parameters are calibrated. In this study, a novel method is proposed with which the stability of a numerical integration scheme combined with time‐domain representation of a frequency‐dependent dynamic impedance function can be evaluated. The method is verified with three independent recursive parameter models. The proposed method is expected to be a useful tool in evaluating the potential stability issue of a time‐domain analysis before running a full‐fledged nonlinear time‐domain analysis of a soil–structure system in which the dynamic impedance of a soil–foundation system is represented with a recursive parameter model. Copyright © 2015 John Wiley & Sons, Ltd.     

Cryptosporidium and Giardia in tropical recreational marine waters contaminated with domestic sewage: Estimation of bathing-associated disease risks

Sewage is a major contributor to pollution problems involving human pathogens in tropical coastal areas. This study investigated the occurrence of intestinal protozoan parasites (Giardia and Cryptosporidium) in tropical recreational marine waters contaminated with sewage. The potential risks of Cryptosporidium and Giardia infection from recreational water exposure were estimated from the levels of viable (oo) cysts (DIC+, DAPI+, PI−) found in near-shore swimming areas using an exponential dose response model. A Monte Carlo uncertainty analysis was performed in order to determine the probability distribution of risks. Microbial indicators of recreational water quality (enterococci, Clostridium perfringens) and genetic markers of sewage pollution (human-specific Bacteroidales marker [HF183] and Clostridium coccoides) were simultaneously evaluated in order to estimate the extent of water quality deterioration associated with human wastes. The study revealed the potential risk of parasite infections via primary contact with tropical marine waters contaminated with sewage; higher risk estimates for Giardia than for Cryptosporidium were found. Mean risks estimated by Monte Carlo were below the U.S. EPA upper bound on recreational risk of 0.036 for cryptosporidiosis and giardiasis for both children and adults. However, 95th percentile estimates for giardiasis for children exceeded the 0.036 level. Environmental surveillance of microbial pathogens is crucial in order to control and eradicate the effects that increasing anthropogenic impacts have on marine ecosystems and human health.     

Assessing the shear-sheltering theory applied to low-level jets in the nocturnal stable boundary layer

This paper investigates the existence of shear sheltering on turbulence data over a quasi-ideal experimental site in Oklahoma, USA. Originally developed for engineering flows, the shear-sheltering theory is predicated upon the idea of low-level jets blocking large eddies aloft, preventing them from propagating to the surface. In this scenario, suppression of low-frequency turbulence energy and reduction of surface fluxes would be expected. Results from the Oklahoma experiment show instead an enhancement of surface turbulence intensity and of the relative contribution of large scales to total (co)variances for low-level jet cases with strong shear, thus suggesting the absence of shear sheltering at the site. The results underline the complexity of surface-atmosphere interactions in nocturnal stable conditions. Atmospheric modeling of exchange using various scenarios of surface characteristics, flow regimes, and low-level jet properties is suggested to further assess the potential applicability of the shear-sheltering theory to atmospheric flows.