Talc-Phengite: a Widespread Assemblage in High-Grade Pelitic Blueschists of the Western Alps

Talc-phengite, an assemblage hitherto believed to be rare, isfound in regional distribution in the Gran Paradiso area, whereit occurs in the characteristic mineral association chloritoid-talc-phengite(Si_3·4–_3·5). Talc contains up to 15 moleper cent minnesotaite, and chloritoid up to 45 mole per centof the magnesium end member. The talc-phengite stability resultsbasically from the disappearance of chlorite + quartz in rockswith low and moderate MgO/FeO ratios through the divariant reactionsfirst recognized here: Fe-Mg-Chlorite+quartz talc + garnet + H₂O and Fe-Mg-chlorite + quartz talc + Chloritoid + H₂O These reactions imply the disappearance of the join biotite-chloritein the presence of quartz and thus open a talc-phengite stabilityfield (±garnet or chloritoid or Mg-chlorite) which extends,with increasing P and T, toward Mg-richer compositions. Whetheror not it reaches the magnesian subsystem in the Gran Paradisoarea cannot be ascertained. However, the sporadic occurrenceof the high-pressure assemblage talc-kyanite-chloritoid 50 to70 km further northeast in the vicinity of the Monte Rosa massifwithin the same lithological unit (Zermatt-Saas Fee zone s.l.)indicates the instability of any chlorite in quartz-bearingrocks, and implies that talc-phengite must also be stable forpurely magnesian compositions in that area. This progressivestabilization of talc-phengite with increasing metamorphic gradesupports Abraham & Schreyer's (1976) hypothesis of a high-pressurefield for this assemblage, and rules out Chernosky's construction(1978) implying a low-pressure field. The following paragenetic sequence is proposed for pelitic compositionswith intermediate Mg/Fe ratios and excess quartz subjected tohigh-pressure metamorphism with maximum temperatures near 400–500°C: chlorite-illite chlorite-phengite chloritoid-talc-phengite.The absence of biotite is a compositional effect due to thehigh degree of phengite substitution in the white mica. ^*Present address: Institut fr Mineralogic, Ruhr-Universitt, Postfach 10 21 48, D-4630 Bochum 1, Federal Republic of Germany.     

A scanning system for measuring the age-related luminescence of split sediment cores

This article describes the development and performance of an integrated optical sensor system that has been designed for rapid analysis of split sediment cores. The primary aim of the system is to obtain information based on optically stimulated luminescence (OSL) techniques; these provide a record of the accrued radiation dose of material since deposition. Particularly after suitable normalization, the luminescence signal recorded along the length of the core will provide information on the relative age of the sediment. Two wavelengths of stimulation are used (infra-red and green) and these probe the feldspar, and combined feldspar and quartz components of the sediment respectively; the ratio of the two signals can thus provide some indication of relative changes in the silicate mineralogy. A secondary use of the system is for optical reflectance measurements. With the addition of a monochromator, optical reflectance spectroscopy can be applied to obtain additional information on down-core mineralogical changes. In this article we describe technical aspects of the sensor system, discuss measurement techniques and consider the relevance of data obtained. Two examples of sediment cores are presented, which demonstrate the applicability of the instrument.     

The last glacial cycles in East Greenland, an overview

Marine, fluvial and glacigene sediments exposed in coastal cliffs and stream-cut sections in East Greenland between latitudes 69° and 78° N display a record of Quaternary climatic and environmental change going back to pre-Saalian times (> 240 ka), but with main emphasis on the last interglacial/glacial cycle. The stratigraphical scheme is based on studies on the Jameson Land peninsula, and contains five glacial stages and stades with the Greenland ice sheet or its outlets reaching the outer coasts. Individual sites are correlated and dated by a combination of biostratigraphy, luminescence dating, amino acid analyses, as well as ¹⁴C- and uranium series dating. The pre-Weichselian Lollandselv and Scoresby Sund glaciations were the most extensive. During the Weichselian the Inland Ice margin in this part of East Greenland was apparently very stable. The Aucellaelv, Jyllandselv and Flakkerhuk stades mark the advance and subsequent retreat of outlet glaciers from the Inland Ice which advanced through the wide Scoresby Sund basin and reached the inner shelf. In-between the glacier advances, three interglacial or interstadial periods have been recognized. During the Langelandselv interglacia-tion (≅ Eemian) the advection of warm Atlantic water was higher than during the Holocene, and the terrestrial flora and insect faunas show that summer temperatures were 3–4°C higher than during the Holocene optimum. There is no unambiguous evidence for cooling in the sediments from this interval. Later, in isotope stage 5, there were apparently two ice-free periods. During the Hugin Sø interstade, stable Polar water dominated Scoresby Sund, and the terrestrial flora suggests summer temperatures 2° -3° lower than the present. The marine and fluvial sediments from the second ice-free period, the Mønselv interstade, are devoid of organic remains.     

Late Pleistocene stratigraphy and depositional environments of the Fynselv area, Jameson Land, East Greenland

Deposits of Late Pleistocene age were investigated near the Fynselv river on the southwestern coast of Jameson Land. East Greenland. The deposits are of fluvial, deltaic shallow marine and glacigenic origin. Four stratigraphic units are recorded. Unit I consists of deltaic and shallow marine deposits reflecting a relative sea level of at least 20 m above the present. Elevated fluvial deposits represent the subaerial part of the depositional system. The system existed during full interglacial and subarctic conditions as indicated by remains or flora and Fauna and unit I is correlated with the Langelandselv interglaciation (isotopic substage 5e). Unit II consists of a till deposited by a glacier in the Scoresby Sund Fjord during the beginning of the Early Weichselian referred to as the Aucellaelv stade. The glacier probably melted in a marine environment. Unit III represents a marine delta system during the Hugin Sø interstade. and reveals a relative sea level of at least 62 m above the present. Unit IV consists of till and kame deposits assumed to be deposited by a glacier in the Scoresby Sund Fjord during the Flakkerhuk stade. probably a Late Weichselian glacier advance.     

Intraplutonic Quench Zones in the Kap Edvard Holm Layered Gabbro Complex, East Greenland

The Kap Edvard Holm Layered Gabbro Complex is a large layeredgabbro intrusion (>300 km²) situated on the opposite sideof the Kangerdlugssuaq fjord from the Skaergaard Intrusion.It was emplaced in a continental margin ophiolite setting duringearly Tertiary rifting of the North Atlantic. Gabbroic cumulates, covering a total stratigraphic thicknessof >5 km, have a typical four-phase tholeiitic cumulus mineralogy:plagioclase, clinopyroxene, olivine, and Fe–Ti oxides.The cryptic variation is restricted (plagioclase An_81–51,olivine Fo_85–66, clinopyroxene Wo_43–41 En_46–37Fs_20–11) and there are several reversals in mineral chemistry.Crystallization took place in a low-pressure, continuously fractionatingmagma chamber system which was periodically replenished andtapped. Fine-grained (0•2–0•4 mm) equigranular, thin(0•5–3 m), laterally continuous basaltic zones occurwithin an {small tilde}1000 m thick layered sequence in theTaco Point area. Twelve such zones define the bases of individualmacrorhythmic units with an average thickness of {small tilde}80m. The fine-grained basaltic zones grade upwards, over a fewmetres, into medium-grained (>1 mm) poikilitic, olivine gabbrowith smallscale modal layering. Each fine-grained basaltic zoneis interpreted as an intraplutonic quench zone in which magmachilled against the underlying layered gabbros during influxalong the chamber floor. Supercooling by {small tilde}50C isbelieved to have caused nucleation of plagioclase, olivine,and clinopyroxene in the quench zone. The nucleation rate isbelieved to have been enhanced as the result of in situ crystallizationin a continuously flowing magma. The transition to the overlyingpoikilitic olivine gabbro reflects a decreasing degree of supercooling. Compositional variation in the Taco Point sequence is typicalfor an open magma chamber system: olivine (Fo_{77–68 5})and plagioclase cores (An_80–72) show a zig-zag crypticvariation pattern with no overall systematic trend. Olivinehas the most primitive compositions in the quench zones andmore evolved compositions in the olivine gabbro; plagioclasecores show the opposite trend. Although plagioclase cores arebelieved to retain their original compositions, olivines re-equilibratedby reaction with trapped liquid. Some plagioclase cores containrelatively sodic patches which retain quench compositions. Whole-rock compositions of nine different quench zones varyover a range from 10 to 18% MgO although the mg-number remainsconstant at {small tilde}0•78. The average composition(47•7% SiO₂, 13•3%MgO, 1•57% Na₂O+K₂O) is takenas a best estimate of the parental magma composition, and isequivalent to a high-magnesian olivine tholeiite. The compositionalvariation of the quench zones is believed to reflect burstsof nucleation and growth of olivine and plagioclase during quenching. Magma emplacement is believed to have taken place by separatetranquil influxes which flowed along the interface between alargely consolidated cumulus pile and the residual magma. Theresident magma was elevated with little or no mixing. At certainlevels in the layered sequence the magma drained back into thefeeder system; such a mechanism is referred to as a surge-typemagma chamber system.     

GLACIAL VARVE THICKNESS AND 127 YEARS OF INSTRUMENTAL CLIMATE DATA: A COMPARISON

Annually laminated sediments (glacial varves) from Lake Silvaplauna, a High Alpine proglacial lake in the Central Swiss Alps, were compared with glacier monitoring data and instrumental climate data from 1864 to 1990. Long-term and short-term responses to climatic change as well as anthropogenic influence can be traced separately in the varve succession. Economic development in the lake catchment has resulted in higher autochthonous production in recent years. Autochthonous components contribute around 10% to the total amount of sediment accumulated annually since 1960 but their contribution is negligible before this date. Decadal-scale varve thickness trends correlate with glacier size-variations. A stepwise, running multiple regression analysis demonstrates that interannual changes in varve thickness are strongly correlated with changes in mean summer temperatures, but cannot be sufficiently explained without considering summer precipitation and the number of days with snow per year. The wide range of observed correlation coefficients reveals the sensitivity of the archive to temporal variability of the climatic forcing factors and makes the development of transfer functions ambiguous.