Element zoning trends in olivine phenocrysts from a supposed primary high-magnesian andesite: an electron- and ion-microprobe study

Electron and ion-probe microanalysis have been used to obtain zoning profiles for major and trace elements in olivine phenocrysts from a high-magnesian andesite from Shodo-Shima island, southwest Japan. This rock was previously thought to represent undifferentiated, primary magma. Some crystals have unzoned cores, while others show cores which are reversely zoned with respect to Mg/ (Mg+Fe), Ni, Mn and Cr. In addition, some Ni profiles show a normally zoned hump at the most central portions of the reversely zoned crystals. All crystals show normally zoned rims. The Li concentrations are constant throughout the cores of all crystals studied, but rise sharply, by a factor of up to at least six, in the rims. The Ca and Co concentrations are essentially constant throughout all the crystals. Mechanisms for producing the observed zoning profiles are discussed, and it is concluded that the reverse zoning was produced by the introduction of crystals into a less differentiated magma than that in which they grew. The reversely zoned crystals could therefore represent xenocrysts which were introduced into an undifferentiated magma, or phenocrysts introduced into a more primitive magma by a magma mixing process. The Ni profiles are used to estimate the residence time of these crystals in the more primitive magma. The following trace element partition co-efficients have been estimated for the olivine-groundmass system in this rock: D ^Ni=16; D ^Mn=1.1; D ^Co=4.2; D ^Ca =0.02; D ^Ti=0.005; D ^V=0.05; D ^Sc=0.2; D ^Na=0.0002. Studies of trace element zoning will become increasingly important as the new generation of trace element microprobes become available but a larger database of experimentally determined values for trace element partition coefficients and diffusion coefficients in crystals and magmas, and a better understanding of other disequilibrium processes are required to fully exploit the new data.     

The measurements of the artificial atmospheric radioactivity

Summary There are some methods and types of instrument for measuring the specific artificial atmospheric radioactivity. In order to compare the simultaneous daily measurements, as made at different stations of a network, or to know the representativeness of a point measurement, it is necessary to consider the random and systematic errors, which are characteristic for the measuring method or the instrument. After having explained the meaning of these quantities, a method of calculation is developed, being illustrated by a numerical example. It is hoped that these considerations may be useful in analogous problems wherever and whenever one and the same quantity is measured with different methods or instruments.

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Zusammenfassung Es gibt verschiedene Methoden und Typen von Instrumenten zur Messung der spezifischen künstlichen atmosphärischen Radioaktivität. Um die gleichzeitigen täglichen Messungen verschiedener Stationen des Beobachtungsnetzes vergleichen zu können und ein Urteil über die Repräsentativität einer Punktmessung zu gewinnen, müssen die zufälligen und die systematischen Fehler der Meßmethode und des Meßinstrumentes berücksichtigt werden. Es wird eine Methode zur Berechnung dieser Fehler entwickelt und ein numerisches Beispiel wiedergegeben. Die Ergebnisse dieser Untersuchung sind auch bei anderen Problemen anwendbar, wo ein und dieselbe Größe auf Verschiedene Weise oder mit verschiedenen Instrumenten gemessen wird.

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Résumé On connaît quelques méthodes et types d'instrument à mesurer la valeur spécifique de la radioactivité artificielle dans l'air. Afin de comparer les mesures quotidiennes simultanées, faites aux diverses stations du réseau d'observation, ou pour d'étudier la représentativité, il faut considérer les erreurs aléatoires et systématiques qui sont caractéristiques pour la méthode ou pour l'instrument de mesure. On développe une méthode pour calculer ces erreurs; elle est illustrée par un exemple numérique. On a quelque espoir que les considérations présentées pourraient être utiles à des problèmes analogues partout et toujours si l'on mesure une même grandeur au moyen de méthodes différentes ou d'instruments différents.

     

Geochemistry of suspended matter from the Baltic Sea 2. Results of bulk trace metal analysis by AAS

In 1984, on a transect covering the whole Baltic Sea and parts of the adjacent North Sea, 160 water samples were taken and analysed for their concentrations of particulate and dissolved metals. In addition, the suspended materials were investigated for their elemental bulk composition.The particulate fractions represented from about 5% (Cd, Cu and Ni) to 50% (Fe and Pb) of the total (particulate plus dissolved) concentrations. For some elements (Ba, Cd, Cu, Pb and Zn), the particulate matter from the surface microlayer was enriched with respect to those suspended materials taken from 0.2 m depth. This could reflect the atmospheric input of metal-rich aerosols. In anoxic deep waters, maximum contents of Zn (6400 μg g⁻¹), Cu (1330 μg g⁻¹) and Cd (12 μg g⁻¹) were observed in the particulate matter, indicating sulphidic forms. On the other hand, under oxic conditions the distribution coefficients (K_d) decreased with the water depth (Cd, Fe and Pb).Relative to global background levels, the particulate matter contained metal “excesses” amounting to more than 90% of the total contents (Cd, Mn, Pb and Zn). Automated electron probe X-ray microanalysis (EPXMA) revealed that the elemental composition of sediments is mainly governed by post-depositional processes of early diagenesis and is only weakly related to the composition of suspended matter in the overlying water body. For instance, in relation to surface mud sediments of the central Baltic net-sedimentation basins, Zn, Cd, Cu and Mn had 30–100% higher levels in the suspended materials. The general pattern of metal contents of particulate matter taken from 10 m depth on a transect between the Bothnian Bay and the North Sea were—possibly as a result of anthropogenic inputs—rather similar for Pb, Zn and Cu. For Fe and Mn, the distribution patterns along the transect were probably governed by the natural loading characteristics and by the biogeochemistry of those elements.     

A climatological data set of temperature and salinity for the Baltic Sea and the North Sea

Ocean Dynamics - A climatological monthly mean data set for temperature and salinity in the area of the North Sea and Baltic Sea is presented. More than 3.1 million temperature observations (2.9...     

Estimates of total radiation and albedo in Sub-Arctic Canada

Summary Maps have recently been prepared of the physiography and plant cover of Labrador-Ungava, in the Canadian Sub-Arctic. These enable detailed studies of representative localities to be extended over wider areas. Methods of estimating the average total insolation from sun and sky received at the surface are discussed, together with aerial measurements of albedo and thus a method of calculating the insolation absorbed by the surface is demonstrated. The limitations of the technique are stressed.

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Zusammenfassung Es wurden Karten der Physiographie und Pflanzenbedeckung von Labrador-Ungava im sub-arktischen Klimagebiet Kanadas bearbeitet; an Hand dieser Karten kann von einzelnen, repräsentativen Orten auf die Verhältnisse in größeren Gebieten geschlossen werden. Die Methoden zur Abschätzung der Globalstrahlung an der Erdoberfläche werden diskutiert. Zusammen mit Messungen der Albedo vom Flugzeug aus ergibt sich eine Möglichkeit, die vom Erdboden absorbierte Strahlungsenergie zu berechnen. Die Grenzen der Leistungsfähigkeit dieser Methode werden betont.

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Résumé On a dressé des cartes de la physiographie et de la couverture végétale du Labrador-Ungava soumis au climat subarctique du Canada. Elles permettent d'étendre les conclusions relatives à certains lieux représentatifs à de plus grands territoires. Discussion des méthodes d'estimation du rayonnement global à la surface du sol. En tentant compte de mesures de l'albédo faites depuis l'avion, on peut calculer l'énergie de rayonnement absorbée par le sol. Les limites d'application de la méthode sont discutées.

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The research described in this paper was sponsored jointly by the Carnegie Arctic Programme of McGill University and the Defence Research Board of Canada.     

∼3,850 Ma tonalites in the Nuuk region,Greenland: geochemistry and their reworking within an Eoarchaean gneiss complex

The Eoarchaean (>3,600 Ma) Itsaq Gneiss Complex of southern West Greenland is dominated by polyphase orthogneisses with a complex Archaean tectonothermal history. Some of the orthogneisses have c. 3,850 Ma zircons, and they vary from rare single phase metatonalites to more common complexly banded migmatites. This is due to heterogeneous strain, in situ anatexis and granitic veining superimposed during younger tectonothermal events. In the single-phase tonalites with c. 3,850 Ma zircon, oscillatory-zoned prismatic zircon is all 3,850 Ma old, but shows patchy ancient loss of radiogenic Pb. SHRIMP spot analyses and laser ablation ICP-MS depth profiling show that thin (usually < 10 μm) younger (3,660–3,590 Ma and Neoarchaean) shells of lower Th/U metamorphic zircon are present on these 3,850 Ma zircons. Several samples with this simple zircon population occur on islands near Akilia. In contrast, migmatites usually contain more complex zircon populations, with often more than one generation of igneous zircon present. Additional zircon dating of banded gneisses across the Complex shows that samples with c. 3,850 Ma igneous zircon are not just a phenomenon restricted to Akilia and adjacent islands. For example, migmatites from Itilleq (c. 65 km from Akilia) contain variable amounts of oscillatory-zoned 3,850 Ma and 3,650 Ma zircon, interpreted, respectively, as the rock age and the time of crustal melting under Eoarchaean metamorphism. With only 110–140 ppm Zr in the tonalites and likely magmatic temperatures of >850°C, zircon solubility–melt composition relationships show that they were only one-third saturated in zircon. Any zircon entrained in the precursor magmas would thus have been highly soluble. Combined with the cathodoluminesence imaging, this demonstrates that the c. 3,850 Ma oscillatory zoned zircon crystallised out of the melt and hence gives a magmatic age. Thus the rare well-preserved tonalites and palaeosome in migmatites testify that c. 3,850 Ma quartzo–feldspathic rocks are a widespread (but probably minor) component in the Itsaq Gneiss Complex. C. 3,850 Ma zircon with negative Eu anomalies (showing growth in felsic systems) also occurs as detrital grains in rare c. 3,800 Ma metaquartzites and as inherited grains in some 3,660 Ma granites (sensu stricto). These demonstrate that still more c. 3,850 Ma rocks were present, but were recycled into Eoarchaean sediments and crustally derived granites. The major and trace element characteristics (e.g. LREE enrichment, HREE depletion, low MgO) of the best-preserved c. 3,850 Ma rocks are typical of Archaean TTG suites, and thus argue for crust formation processes involving important contributions from melting of hydrated mafic crust to the earliest Archaean. Five c. 3,850 Ma tonalites were selected as the best preserved on the basis of field criteria and zircon petrology. Four of these samples have overlapping initial ɛ_Nd (3,850 Ma) values from +2.9 to +3.6± 0.5, with the fourth having a slightly lower value of +0.6. These data provide additional evidence for a markedly LREE-depleted early terrestrial mantle reservoir. The role of c. 3,850 Ma crust should be considered in interpreting isotope signatures of the younger (3,800–3,600 Ma) rocks of the Itsaq Gneiss Complex. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

On the application of the mode-acceleration method to structural engineering problems

Mode-superposition has been extensively used in computing the dynamic response of complex structures. Two versions of mode-superposition, namely the mode-displacement method and the mode-acceleration method, have been employed. The present paper summarizes the results of a systematic study comparing the accuracy of the mode-displacement and mode-acceleration methods when applied to structures with various levels of damping or various excitation frequencies. The paper also discusses several details concerning the implementation of the mode-acceleration method.     

A method for constructing toxic waste site histories from old airphotos of coastal regions

Archive aerial photos have been used to create a skeletal history for several toxic waste sites currently under investigation in the United States. Because many of the sites are very small in area, and the majority of the historical aerial photography is not large scale, specialized methods have, through experience, been developed to do this work. The result of the work is a series of standard format film stereograms and a detailed report. The report includes several unique methods for presenting the airphoto findings.