Micromechanical approach to effective viscoelastic properties of micro‐fractured geomaterials

The aim of this paper is to formulate a micromechanics‐based approach to non‐aging viscoelastic behavior of materials with randomly distributed micro‐fractures. Unlike cracks, fractures are discontinuities that are able to transfer stresses and can therefore be regarded from a mechanical viewpoint as interfaces endowed with a specific behavior under normal and shear loading. Making use of the elastic‐viscoelastic correspondence principle together with a Mori‐Tanka homogenization scheme, the effective viscoelastic behavior is assessed from properties of the material constituents and damage parameters related to density and size of fractures. It is notably shown that the homogenized behavior thus formulated can be described in most cases by means of a generalized Maxwell rheological model. For practical implementation in structural analyses, an approximate model for the isotropic homogenized fractured medium is formulated within the class of Burger models. Although the approximation is basically developed for short‐term and long‐term behaviors, numerical applications indicate that the approximate Burger model accurately reproduce the homogenized viscoelastic behavior also in the transient conditions.     

Geochemical fixation of rare earth elements into secondary minerals in sandstones beneath a natural fission reactor at Bangombé, Gabon

To study geochemical processes for migration and fixation of fissiogenic rare earth elements (REE) in association with uranium dissolution, in situ isotopic analyses using an ion microprobe were performed on U- and REE-bearing secondary minerals, such as coffinite, françoisite, uraniferous goethite, and uraninite found in a sandstone layer 30 to 110 cm beneath a natural fission reactor at Bangombé, Gabon. Phosphate minerals such as phosphatian coffinite and françoisite with depleted ²³⁵U (²³⁵U/²³⁸U = 0.00609 to 0.00638) contained large amount of fissiogenic light REE, while micro-sized uraninite grains in a solid bitumen aggregate have normal U isotopic values (²³⁵U/²³⁸U = 0.00725) and small amount of fissiogenic REE components. The proportions of fissiogenic and non-fissiogenic REE components in four samples from the core of BAX03 vary in depth ranging from 30 cm to 130 cm beneath the reactor, which suggests mixing between fissiogenic isotopes from the reactor and non-fissiogenic isotopes from original minerals in the sandstone. Significant chemical fractionation was observed between Ce and the other REE in the secondary minerals, which shows evidence of an oxidizing atmosphere during their formation. Pb-isotopic analyses of individual minerals do not directly provide chronological information because of the disturbance of U-Pb decay system due to recent geologic alteration. However, systematic Pb-isotopic results from all of the minerals reveal the mobilization of fissiogenic isotopes, Pb and U from the reactor in association with dolerite dyke intrusion ∼0.798 Ga ago and the formation of the secondary minerals by mixing event between 2.05 Ga-old original minerals and reactor materials due to recent alteration.     

Regional metamorphism of some Dalradian pelites in the Buchan area,N.E. Scotland

Regional metamorphic zones, based on mineral assemblages in pelites, are presented for the Dalradian rocks of Aberdeenshire and Banffshire, in the type area of Buchan metamorphism; electron microprobe analyses of cordierite (C), staurolite (S), chlorite (Chl), biotite (B) and white mica (Ms) are reported for rocks from the classic sections of the Banffshire coast and the valley of the Ythan.A low grade biotite zone, separates two NE-SW trending sets of higher grade zones, in which the sequence s defined by the entry of cordierite, andalusite (A) and (in the west only) staurolite. The zones are characterised by the assemblages (with quartz and muscovite) B-Chl, C-B-Chl, A-C-B and S-A-B.The western sequence contains a transition towards higher pressure, Barrovian type, metamorphism. The isograds arise from continuous reactions affecting rocks of restricted bulk composition (M/FM). With increasing grade, there is a regular trend towards more magnesian ranges of composition for the assemblages C-B-Chl, A-C-B and finally (as P increases in the west), S-A-B. The isograds form when these assemblages intersect the most Fe⁺⁺-rich rock compositions present which occurs in each case when the biotite M/FM=40. A complex of divariant equilibria, derived for the system KFMASH, is used to model the natural reactions.     

Climate Change Studies Using Space Based Observation

Climate change is associated with earth radiation budget that depends upon incoming solar radiation, surface albedo and radiative forcing by greenhouse gases. Human activities are contributing to climate change by causing changes in Earth’s atmosphere (greenhouse gases, aerosols) and biosphere (deforestation, urbanization, irrigation). Long term and precise measurements from calibrated global observation constellation is a vital component in climate system modelling. Space based records of biosphere, cryosphere, hydrosphere and atmosphere over more than three decades are providing important information on climate change. Space observations are an important source of climate variables due to multi scale simultaneous observation (local, regional, and global scales) capability with temporal revisit in tune with requirements of land, ocean and atmospheric processes. Essential climatic variables that can be measured from space include atmosphere (upper air temperature, water vapour, precipitation, clouds, aerosols, GHGs etc.), ocean (sea ice, sea level, SST, salinity, ocean colour etc.) and land (snow, glacier, albedo, biomass, LAI/fAPAR, soil moisture etc.). India’s Earth Observation Programme addresses various aspects of land, ocean and atmospheric applications. The present and planned missions such as Resourcesat-1, Oceansat-2, RISAT, Megha-Tropiques, INSAT-3D, SARAL, Resourcesat-2, Geo-HR Imager and series of Environmental satellites (I-STAG) would help in understanding the issues related to climate changes. The paper reviews observational needs, space observation systems and studies that have been carried out at ISRO (Indian Space Research Organization) towards mapping/detecting the indicators of climate change, monitoring the agents of climate change and understanding the impact of climate change, in national perspectives. Studies to assess glacier retreat, changes in polar ice cover, timberline change and coral bleaching are being carried out towards monitoring of climate change indicators. Spatial methane inventories from paddy rice, livestock and wetlands have been prepared and seasonal pattern of CO₂, and CO have been analysed. Future challenges in space observations include design and placement of adequate and accurate multi-platform observational systems to monitor all parameters related to various interaction processes and generation of long term calibrated climate data records pertaining to land ocean and atmosphere.     

Fine grain sediment transport and deposition in the Patos Lagoon–Cassino beach sedimentary system

Extensive mud deposits superimposed on the predominantly sandy inner continental shelf adjacent to the Patos Lagoon estuary, indicates that the Lagoon is a potential source of fine sediments to the coastal sedimentary system. The lagoon is large and shallow, and the water movement is mainly controlled by wind-driven set-up and set-down. The mean river inflow is around 2000 m³ s⁻¹, although peak flow rates exceeding 20,000 m³ s⁻¹ have been observed during El Niño periods. Though the tidal elevations are small, tidal velocities in the lagoon's inlet can be significant due to the large extension of the backwaters. Moreover, significant exchange flows can be generated between the estuary and coastal area due to barotropic pressure gradients established as a function of wind and freshwater discharge. The predominant net flow is seawards, but opposite near-bed flows due to pronounced vertical salinity stratification can also be observed. The coastal area is characterized by small tidal effects, large scale ocean circulation, wind-induced residual flows and wave-driven currents, where the waves originate from swell or are locally generated.     

Geochemistry,chronology and stratigraphy of Neogene tuffs of the Central Andean region

Tuff layers are vital stratigraphic tools that allow correlations to be made between widely dispersed exposures. Despite their widespread occurrence in the central Andes, tuffs from both natural exposures and sedimentary cores extracted from the region's extensive salars (salt pans) are relatively unstudied. Here we lay the foundation for a tephrostratigraphic framework in the central Andes (14–28°S) by chemically and morphologically characterizing ash shards, and in some cases dating 36 Neogene distal tuffs. These tuffs occur in lacustrine and alluvial deposits from the southern Bolivian Altiplano and adjacent Atacama Desert. All tuffs are calc-akaline rhyolites, consistent with their setting in the Central Andean Volcanic Zone. Five of the older tuffs were ⁴⁰Ar/³⁹Ar dated and yield an age range of 6.63–0.75 Ma. Organic material associated with tuffs deposited into paleolake sediments, paleowetland deposits, or urine-encrusted rodent middens provide constraints on the age of several Late Pleistocene and Holocene tuffs.These tuffs provide key stratigraphic markers and ages for lake cycles and archeological sites on the Bolivian Altiplano and for assessing rates of surficial processes and archeology in both the Atacama and Altiplano. While modern climate, and consequently questions about geomorphic processes and climate change, differs in the hyperarid Atacama and the semi-arid Altiplano, the most extensive air-fall tuffs covered both regions, placing the Atacama and the Bolivian Altiplano in the same tephrostratigraphic province. For example, the Escara B tuff (～1.85 Ma), can be securely identified in both the Altiplano and Atacama. On the Altiplano, dates from the Escara B and E tuffs securely establish the age of the Escara Formation—representing the oldest expansive lake documented on the Bolivian Altiplano. By contrast, the presence of the Escara B tuff below ～6 m of alluvial sediment at the Blanco Encalado site in the Atacama desert yields information about sedimentation rates in this hyperarid region. Indeed, most tuffs from the Atacama Desert are older than 600,000 years, even though they occur within fluvial terraces immediately adjacent to the alluvial fans that are still active. Most of these geomorphic surfaces in the Atacama also possess well-developed saline soils that, when combined with the radiometric ages of the distal tuffs, suggest slow rates of geomorphic change and exceptional landscape stability for this area during the Quaternary.In contrast, younger tuffs are more abundant in the more recent lake records of the Altiplano. The Chita tuff was deposited at ～15,650 cal yr B.P., during the regressive phase of the region's deepest late Quaternary lake cycle—the “Tauca lake cycle”—which spanned 18.1–14.1 cal yr B.P. Two Holocene tuffs, the Sajsi tuff and the Cruzani Cocha tuff, are widespread. The Sajsi tuff was deposited just before 1700 cal yr B.P., whereas the Cruzani Cocha tuff appears to be mid-Holocene in age and shows some chemical affinities to a Holocene tuff (202B) deposited between 4420 and 5460 cal yr B.P. in a urine-encased rodent midden in the Atacama Desert.     

Representativeness of total ozone trends as derived from satellite BUV and ground-based measurements

The information content of the 7-year BUV data set has been reexamined by a comparison with a fairly large set of ground Dobson and M-83 instruments. The satellite-ground intercomparison of total ozone was done under different types of ground observation techniques (observation code) and different instrument exposure (exposure code) and for various distances of the subsatellite point from the station. Because of the existing latitudinal gradient in total ozone, at a given station the bias ground-BUV tends to be smaller when the subsatellite point is at a latitude higher than the station's latitude. Knowing the total ozone gradient at a given station, the BUV total ozone has been corrected to account for the ozone gradient and the correlation was calculated with the corresponding ground observations. These correlations seem to offer no improvement when compared with the correlations between the ground ozone and the actual BUV ozone at distances of the subsatellite point from the station within 200 km from the station used in previous studies. The seasonal variation of the BUV-ground correlation reveals information on the noise level of the measurements and the geographical distribution of the percentage mean bias: (Ground-BUV)×100/(Ground) is discussed. Both on short and on longer time scales it appears that the BUV derived recommended total ozone data set is reasonably good and possible instrumental drifts are not large. The analysis includes an extension through April 1977 of the BUV and contour-derived total ozone trends byLondon andLing (1980). Over the northern hemisphere both data sets (contour and BUV) show comparable trends over middle and high latitudes which range from –3 D.U./year to –5 D.U./year during the 7-year period April 1970–April 1977. In the southern hemisphere, however, long-term variation in total ozone cannot be determined from ground observations alone. It is concluded that for unknown reasons during the 7-year period of study, total ozone has been decreasing over most of the globe. The negative growth rates at high latitudes of the northern hemisphere are highly significant.     

Monitoring of toxic substances in the Hong Kong marine environment

A long-term programme for monitoring toxic substances in the marine environment was established in Hong Kong in 2004, focusing on chemicals of potential ecological and health concern. The programme ran on 3-year cycles, with the first two years monitoring marine water, sediment, biota, and the third year monitoring pollution sources. Twenty-four priority chemicals were measured, including dioxins/furans, dioxin-like PCBs, total PCBs, PAHs, DDTs, HCHs, TBTs, phenol, nonylphenol (NP), NP ethoxylates, PBDEs and metals. Results from the first three years of monitoring indicate that toxic substances in the Hong Kong marine environment were within the range reported for the coastal waters in China and other regions, but generally lower than in the Pearl River Estuary. The levels met the standards for protecting aquatic life and human consumption. Sewage effluent, stormwater and river water were possible sources of phenolic compounds; whereas air deposition or regional pollution, rather than local discharges, may contribute to the dioxins/furans, PAHs and PCBs found in the marine environment.