P-T-t-deformation paths recorded by kinzigites during diapirism in the western Variscan belt (Golfe du Morbihan, southern Brittany, France)

Abstract The high-grade metamorphic rocks of southern Brittany underwent a complex tectonic evolution under various P-T conditions (high-P, high-T), related to stacking of nappes during Palaeozoic continentcontinent collision. The east to west thrusting observed in the whole belt is strongly perturbed by vertical movements attributed to the ascent of anatectic granites in the high-T area. The field reconstruction of subvertical, closed elliptical structures in gneisses and migmatites, associated with the subhorizontal, doubly radial pattern of stretching lineation in the mica schists, suggests the existence of an elliptical diapiric body buried at depth beneath the present erosion level. Deformation is associated with a complex P-T evolution partly recorded in aluminous gneisses (kinzigites, e.g. morbihanites). A chronology of successive episodes of mineral growth at different compositions is established by detailed studies of the mineral-microstructure relationships in X-Z sections, using the deformation-partitioning concept (low- and high-strain zones). Several thermometric and barometric calibrations are applied to mineral pairs either in contact or not in contact but in equivalent microstructiiral positions with respect to the deformation history. This methodology provides a continuous microstructural control of P-T variations through time and leads to three P-T-t-d paths constructed from numerous successive P-T estimations. Path 1 is a clockwise retrograde path preserved in low-strain zones, which records general exhumation movements after crustal thickening. Paths 2 and 3 are clockwise prograde/retrograde paths from high-strain zones; they are interpreted and discussed in the light of models of crustal anatexis and upward movement of magma (diapirism). Deformation and P-T effects induced by diapirism can be distinguished from the general deformation-metamorphic history of a belt, and would seem to be produced during a late stage of its history. The present microstructural-petrological approach to defining successive mineral equilibria in relation to progressive deformation steps provides a far more accurate evaluation of the metamorphic evolution than is possible by ‘standard’thermobarometry.     

Late Quaternary vegetation changes around Lake Rutundu,Mount Kenya,East Africa: evidence from grass cuticles,pollen and stable carbon isotopes

Woody, subalpine shrubs and grasses currently surround Lake Rutundu, Mount Kenya. Multiple proxies, including carbon isotopes, pollen and grass cuticles, from a 755‐cm‐long core were used to reconstruct the vegetation over the past 38 300 calendar years. Stable carbon‐isotope ratios of total organic carbon and terrestrial biomarkers from the lake sediments imply that the proportion of terrestrial plants using the C₄ photosynthetic pathway was greater during the Late Pleistocene than in the Holocene. Pollen data show that grasses were a major constituent of the vegetation throughout the Late Pleistocene and Holocene. The proportion of grass pollen relative to the pollen from other plants was greatest at the last glacial maximum (LGM). Grass cuticles confirm evidence that C₄ grass taxa were present at the LGM and that the majority followed the cold‐tolerant NADP‐MEC₄ subpathway. Copyright © 2003 John Wiley & Sons, Ltd.     

Estimation of snow water equivalent using microwave radiometry over Arctic first‐year sea ice

The magnitude and spatial distribution of snow on sea ice are both integral components of the ocean–sea‐ice–atmosphere system. Although there exists a number of algorithms to estimate the snow water equivalent (SWE) on terrestrial surfaces, to date there is no precise method to estimate SWE on sea ice. Physical snow properties and in situ microwave radiometry at 19, 37 and 85 GHz, V and H polarization were collected for a 10‐day period over 20 first‐year sea ice sites. We present and compare the in situ physical, electrical and microwave emission properties of snow over smooth Arctic first‐year sea ice for 19 of the 20 sites sampled. Physical processes creating the observed vertical patterns in the physical and electrical properties are discussed. An algorithm is then developed from the relationship between the SWE and the brightness temperature measured at 37 GHz (55°) H polarization and the air temperature. The multiple regression between these variables is able to account for over 90% of the variability in the measured SWE. This algorithm is validated with a small in situ data set collected during the 1999 field experiment. We then compare our data against the NASA snow thickness algorithm, designed as part of the NASA Earth Enterprise Program. The results indicated a lack of agreement between the NASA algorithm and the algorithm developed here. This lack of agreement is attributed to differences in scale between the Special Sensor Microwave/Imager and surface radiometers and to differences in the Antarctic versus Arctic snow physical and electrical properties. Copyright © 2003 John Wiley & Sons, Ltd.     

Himalayan magmatism and porphyry copper–molybdenum mineralization in the Yulong ore belt, East Tibet

Summary ?The NW–SE-trending Yulong porphyry Cu–Mo ore belt, situated in the Sanjiang0 area of eastern Tibet, is approximately 400 km long and 35 to 70 km wide. Complex tectonic and magmatic processes during the Himalayan epoch have given rise to favorable conditions for porphyry-type Cu–Mo mineralization. Porphyry masses of the Himalayan epoch in the Yulong ore belt are distributed in groups along regional NW–SE striking tectonic lineaments. They were emplaced mainly into Triassic and Lower Permian sedimentary-volcanic rocks. K–Ar und U–Pb isotopic datings give an intrusion age range of 57–26 Ma. The porphyries are mainly of biotite monzogranitic and biotite syenogranitic compositions. Geological and geochemical data indicate that the various porphyritic intrusions in the belt had a common or similar magma source, are metaluminous to peraluminous, Nb–Y–Ba-depleted, I-type granitoids, and belong to the high-K calc-alkaline series. Within the Yulong subvolcanic belt a number of porphyry stocks bear typical porphyry type Cu–Mo alteration and mineralization. The most prominent porphyry Co–Mo deposits include Yulong, Malasongduo, Duoxiasongduo, Mangzong and Zhanaga, of which Yulong is one of the largest porphyry Cu (Mo) deposits in China with approximately 8 × 10⁶ tons of contained Cu metal. Hydrothermal alteration at Yulong developed around a biotite–monzogranitic porphyry stock that was emplaced within Upper Triassic limestone, siltstone and mudstone. The earliest alteration was due to the effects of contact metamorphism of the country rocks and alkali metasomatism (potassic alteration) within and around the porphyry body. The alteration of this stage was accompanied by a small amount of disseminated and veinlet Cu–Mo sulfide mineralization. Later alteration–mineralization zones form more or less concentric shells around the potassic zone, around which are distributed a phyllic or quartz–sericite–pyrite zone, a silicification and argillic zone, and a propylitic zone. Fluid inclusion data indicate that three types of fluids were involved in the alteration–mineralization processes: (1) early high temperature (660–420 °C) and high salinity (30–51 wt% NaCl equiv) fluids responsible for the potassic alteration and the earliest disseminated and/or veinlet Cu–Mo sulfide mineralization; (2) intermediate unmixed fluids corresponding to phyllic alteration and most Cu–Mo sulfide mineralization, with salinities of 30–50 wt% NaCl equiv and homogenization temperatures of 460–280 °C; and (3) late low to moderate temperature (300–160 °C) and low salinity (6–13 wt% NaCl equiv) fluids responsible for argillic and propylitic alteration. Hydrogen and oxygen isotopic studies show that the early hydrothermal fluids are of magmatic origin and were succeeded by increasing amounts of meteoric-derived convective waters. Sulfur isotopes also indicate a magmatic source for the sulfur in the early sulfide mineralization, with the increasing addition of sedimentary sulfur outward from the porphyry stock. Received August 29, 2001; revised version accepted May 1, 2002 Published online: November 29, 2002     

An Instantaneous-Frequency Filtering Technique for High-Frequency Radar Oceanography

High-frequency (HF) radar systems are remote sensing tools that can be used to measure oceanographic parameters. Problems can occur when using the conventional periodogram (PG) method for computing power spectral estimates from backscattered radar signals. Temporal and spatial inhomogeneities within the radar measurement region can cause distortion in the spectra. This paper describes an instantaneous-frequency (IF) filtering technique that has been developed to measure the first-order modulation contained within the radar signal. Successful removal of this modulation is shown to yield an increased quality and quantity of ocean measurements     

The significance of Messinian occurrences of Globorotalia margaritae and Globorotalia puncticulata in Sicily

Globorotalia puncticulata and Globorotalia margaritae are critical species that define internationally recognized planktonic foraminiferal biozones in the Pliocene. These biozones are defined from stratotype sections on Sicily and their fauna are commonly considered to have been introduced to the Mediterranean after an influx of Atlantic water that terminated the late Miocene desiccation of the basin. Herein new discoveries of these species in rocks that predate the late Miocene desiccation are described. These data are supported by magneto- and lithostratigraphy that have been integrated at a single continuous section. Not only do these discoveries question the existing foraminiferal biozone stratigraphy, they also suggest new models for the dispersal of planktonic species. It is proposed that Globorotalia puncticulata and perhaps even Globorotalia margaritae evolved in the Mediterranean during earliest Messinian times (during or before chron C3Bn1n) and dispersed into the Atlantic. This suggests that a marine connection remained between the two sea areas until at least chron C3An.1n. Using the existing geomagnetic polarity time scale, these occurrences are some 2 Myr earlier than previously recorded in the Mediterranean. The distribution of G. margaritae and G. puncticulata in Mediterranean sections is likely to reflect palaeoenvironment or the preservation of deposits rather than the absolute age of the sediments.