Influence of landscape restoration and degradation on storm surge and waves in southern Louisiana

The purpose of this investigation was to examine storm surge and wave reduction benefits of different environmental restoration features (marsh restoration and barrier island changes), as well as the impact of future wetland degradation on local surge and wave conditions. Storm surge simulations of two representative hurricanes were performed using the ADCIRC storm surge model with the inclusion of radiation stress gradients from the STWAVE nearshore wave model. Coupled model simulations were made for a number of landscape configurations that involved both restored and degraded wetland features. The impact of barrier island condition on hurricane surge and waves was also evaluated. Effects of landscape features were represented by changes in elevation and frictional resistance. Restoration and degradation of marsh resulted in decreases (for restoration cases) and increases (for degradation cases) in both surge and waves. The magnitude of change was correlated with the magnitude of the horizontal extent and elevation changes in the marsh. In general, the wave change patterns are consistent with the water level changes. Deflation of the Chandeleur Islands (barrier island chain) resulted in slightly increased surge. Results suggest that coastal marsh does have surge and wave reduction potential. Results also indicate that the impact of the landscape features is amplified in areas where there are levee “pockets.” Barrier islands and coastal ridges reduce wave heights, even if in a degraded condition and thus can reduce wave energy in wetland areas, protecting them from erosion.     

Status of sedimentation in King Talal Dam,case study from Jordan

This paper focuses on characterizing the current status of physical and chemical characteristics of King Talal Dam (KTD) sediments. The quality of sediments was investigated based on several international sediment quality guidelines. The volume of sediment and sedimentation rate in (KTD) was also estimated. Five types of granulometric textural facies were observed for the sediments of KTD reservoir bed, with an average grain size distribution of gravel (1.38%), sand (32.38%), silt (32.35%) and clay (32.38%). The fraction of <63 micron showed that the total mean size was 8.0 micron. Other sediment parameters in KTD were 7.0% for total organic matter (TOM), 7.3 for pH, 35.9% for CaCO₃ and 100.5 meq/100 g for cation exchange capacity, with dominant mineralogical constituents of quartz, calcite, dolomite, clay minerals and minor feldspar. The total concentrations of F, Cl, NO₂, NO₃, PO₄ and SO₄ in sediment samples were lower inward for KTD. The vast majority of trace metals in sediments were generally within the standard limits recommended for soils. TOM and grain size of sediment are major factors governing the trace metal concentrations. The calculated geoaccumulation index (I _geo) and enrichment factor of metals in bottom sediments showed that the metals were in the following order: Cd > Pb > Zn > Co > Cr > Ni > Fe > Cu > Sr > Mn and Cd > Zn > Pb > Co > Cr > Ni > Cu > Sr > Mn, respectively. Based on the sonic survey of KTD reservoir, the annual sedimentation rate was about 0.4061 MCM/year, in which about 18.66% of the reservoir initial storage capacity was lost to sediments and a projected lifespan of about 198 years.     

Fluid inclusion and cathodoluminescence studies on fluorite from the Kerio valley, Kenya

The Kerio valley lies between the Elgeyo escarpment and the Tugen hills which mark the western margin of the Kenya rift valley. The main fluorite deposits are located in the southern part of the valley at Kimwarer, Choff and Kamnaon.Three types of inclusion fillings were identified: Liquid+Vapour, Liquid+Daughter Minerals and Liquid. The L+V type is dominant. Inclusions occur as clusters, trails along the crystal growth zones and as isolated ones. Low salinities, apparently lower than the 5% wt. NaCl equivalent, were established. Homogenization temperatures suggest that fluorite mineralization took place at different stages and at temperatures between 120 and 180 °C. Isolated readings above 180°C may be referring to the original inclusions in limestone. These measurements and the absence of CO₂ in the inclusions, as well as the occurrence of vugs and crustifications with fluorite, suggest that mineralization took place at relatively shallow depths.Emission spectrum lines representing Eu²⁺, Dy³⁺, Tb³⁺ and Sm³⁺ in fluorite were identified. Sm³⁺ was detected only in the pinkish luminescence of veined fluorite, whereas the pinkish zone in banded fluorite contains Tb³⁺. Eu²⁺ which gives the strongest emission lines in the blue part of the visible spectrum, apparently is responsible for the strong blue cathodoluminescence (CL) in fluorite. The dominance of Eu²⁺ peaks further points to the fact that fluorite mineralization in the Kerio valley took place in an environment that was enriched in Lanthanide Rare Earth Elements (LREE). The presence of rare earths and radioactive elements in fluorite points towards their enrichment in the environment of fluorite mineralization. A juvenile origin of mineral forming solutions is proposed.Two generations of fluorite were established: allotriomorphic fluorite, forming the matrix, and the idiomorphic variety, occurring either in barite or in druzes in early fluorite. Barite in turn forms idiomorphic crystals in allotriomorphic fluorite. Relics of calcite occur in both K-feldspars and in early fluorite. Oxides and hydroxides of Fe, Mn, Ti and Al commonly occur in open spaces in fluorite. Of significance is the presence of gold in fluorite. Fluorite mineralization is of hydrothermal origin in the post-Miocene era and was formed as a result of metasomatic replacement of marble and open space fillings.     

Detection of lithium in the spectrum of the symbiotic Mira star V407 Cygni

We detected the resonance lithium doublet, ⁷LiI λ6708, in the spectra of the symbiotic Mira V407 Cyg (P≈763^d) obtained with a resolution R = λ/Δλ ≈ 18 500. The line equivalent width is ～0.34 Å. The presence of lithium in the atmosphere of the Mira, which, judging by its period, appreciably ascended the asymptotic giant branch (AGB), can be explained by the penetration of its convective envelope into the hot-bottom-burning (HBB) hydrogen-shell source. At the same time, the spectrum of V407 Cyg does not reveal the ZrO λ5551, 6474 absorption bands, which are used to classify S-type stars from low-resolution spectra. We found only weak ZrO λ5718, 6412 bands, which are, however, invisible in low-resolution spectra. Thus, the Mira star V407 Cyg should be classified as being of the spectral type M. In general, the spectrum of V407 Cyg is similar to the spectrum of the red giant in the symbiotic star CH Cyg, but the latter exhibits no lithium lines. The switch-on of the HBB process without any significant enrichment of the atmosphere of an AGB star with s-process elements implies that the third dredge-up is not efficient for some of these stars.     

The weathering of stones due to dissolution

We hypothesize that the weathering of building stones can be attributed to surface dissolution processes. We assume that chemical interactions occur on grain boundaries and/or microcracks and that diffusion is the controlling process. A dissolution layer (rind) develops adjacent to the weathering surface. We quantify the extent of dissolution by introducing a damage variable f; f=0 for pristine rock, and when f=1 the rock disintegrates. We assume that the variations of the damage variable are given by the diffusion equation. We solve two problems. The first is for the structure of the transient dissolution boundary layer prior to surface disintegration. We find an incubation time t_i, before active weathering (disintegration) begins. The second is the solution for steady-state weathering with a constant weathering velocity v_w. Our results are entirely consistent with weathering studies on Carrara marble gravestones in the United Kingdom. Typical incubation times are t_i=20–30 years, and typical steady-state weathering velocities are v_w=5–50 m year^–1.     

Geochemistry and origin of elements in some UK coals

Twenty-four UK coals ranging in rank with 4.6%–37.6% volatile matter were analysed for 46 major and trace elements. The samples were obtained from the UK Coal Bank and are representative of the major UK coal fields. The major element distributions are interpreted in terms of the mineralogical variations—quartz and kaolinite are largely responsible for the Si and Al, carbonates for Ca and Mg and pyrite for Fe. Also exerting an influence in some samples are siderite, Al-phosphate minerals and illite. Based on statistical relationships with the major elements, Rb, Cr, Th, Ce, Zr, Y, Ga, La, Ta, Nb and V are thought to be mainly present in the clay minerals, and As, Mo, Sb, Tl, Se and Bi and Pb are probably present in pyrite. Strontium and Ba are concentrated in a restricted number of samples related to the phosphate minerals. Germanium is the only element for which a major organic association can be demonstrated. Elements with an indirect association with the organic matter are Na, Cl, and Br in porefluids and possibly Te. The ash content is controlled mainly by the detrital input and the trace elements related to the ash content are therefore those elements associated with the clay minerals. Variations with rank would appear to be mainly related to the moisture content (porefluids). The trace elements associated with the quartz and clay minerals are thought to be dominantly detrital in origin. The non-detrital elements, essentially those contained in pyrite, are thought to have been incorporated in the depositional environment from waters with enhanced salinities through seawater ingress, hence there are positive relationships between S and trace element concentrations.     

Emission spectrographic estimation of gold

A procedure for estimating minute quantities (parts per billion) of gold is described, based on dissolution of the sample in aqua regia, adsorption on activated charcoal, arcing of the charcoal ash, and measurement of the intensity of the emitted spectra.