Unique isoprene oxidation products demonstrate chlorine atom chemistry occurs in the Houston,Texas urban area

As part of the 2000 Texas Air Quality Study (TexAQS), we studied the isoprene oxidation process under ambient conditions to discern the presence of chlorine atom (Cl) chemistry in the Houston, Texas urban area. By measuring chloromethylbutenone (CMBO) and an isomer of chloromethylbutenal (CMBA), we clearly observed sixteen episodes of active Cl chemistry during the 24-day experiment. Estimated median Cl concentration during each of these episodes was between the detection limit of ~10² atoms cm⁻³ and 50 _{- 30} ^{+ 70} ×10⁴ 50_{ - 30}^{ + 70} \times {10^4} atoms cm⁻³. Cl concentration during all the episodes averaged 7.6 _{- 2.0} ^{+ 4.7} ×10⁴ 7.6_{ - 2.0}^{ + 4.7} \times {10^4} atoms cm⁻³ and thus amounted to less than 3% of the OH concentration during the same periods. During the episodes, the fraction of oxidation chemistry initiated by Cl ranged from 3–43% and was strongly dependent on the quantity and type of hydrocarbons present in the atmosphere. Because of its intermittent presence and low concentration, Cl is not a broadly influential oxidant in the Houston, Texas urban area.     

Theoretical meteorology and the operational meteorologist

Abstract

Values of incoming solar and long‐wave radiation measured at the vessel Quadra during the three phases of GATE are used to assess the daily performance of three models, one for solar and two for long‐wave radiation. The solar radiation model, which uses data on precipitable water and cloud amount at three levels in the atmosphere performed satisfactorily during the first phase but gave poor results in the other two phases when cumulonimbus became more dominant. Both the flux‐emissivity approach using measured and interpolated Upper air data and Paltridge's empirical procedure produced estimates of long‐wave radiation which compared very closely with the measurements.     

Frequency response corrections for eddy correlation systems

Simplified expressions describing the frequency response of eddy correlation systems due to sensor response, path-length averaging, sensor separation and signal processing are presented. A routine procedure for estimating and correcting for the frequency response loss in flux and variance measurements is discussed and illustrated by application to the Institute of Hydrology's Hydra eddy correlation system.The results show that flux loss from such a system is typically 5 to 10% for sensible and latent heat flux, but can be much larger for momentum flux and variance measurements in certain conditions.A microcomputer program is included which, with little modification, can be used for estimating flux loss from other eddy correlation systems with different or additional sensors.     

Characteristics of precipitation in northern Mauritania and its links with sea surface temperature

This paper deals with the periodic fluctuation of precipitation at three meteorological stations (Atar, Chenguitti, and Akjoujt) in the Adrar and Inchiri provinces in northern Mauritania and its links with sea surface temperature (SST). Trends for these three meteorological stations were evaluated using the Mann–Kendall (MK) nonparametric test, regression analysis, and autocorrelation for persistence analysis. The MK test showed a significant decreasing trend for Akjoujt and an insignificant trend for the other rainfall time series. However, the decreasing linear regression trends were highly significant for the different time series. On the other hand, persistence analysis indicated the presence of a linear Markov type. The cycles found by power spectrum analysis ranged from 0.5 years to about 11 years. The possibility of a connection between precipitation in this region and sunspot numbers was suggested. SST of the Atlantic Ocean, Indian Ocean, and Mediterranean Sea have significant cross-correlations with precipitation in the study area. The El Niño-Southern Oscillation effect was found to be marginal.     

Storm rainfall conditions for floods and debris flows from recently burned areas in southwestern Colorado and southern California

Debris flows generated during rain storms on recently burned areas have destroyed lives and property throughout the Western U.S. Field evidence indicate that unlike landslide-triggered debris flows, these events have no identifiable initiation source and can occur with little or no antecedent moisture. Using rain gage and response data from five fires in Colorado and southern California, we document the rainfall conditions that have triggered post-fire debris flows and develop empirical rainfall intensity–duration thresholds for the occurrence of debris flows and floods following wildfires in these settings. This information can provide guidance for warning systems and planning for emergency response in similar settings.Debris flows were produced from 25 recently burned basins in Colorado in response to 13 short-duration, high-intensity convective storms. Debris flows were triggered after as little as six to 10 min of storm rainfall. About 80% of the storms that generated debris flows lasted less than 3 h, with most of the rain falling in less than 1 h. The storms triggering debris flows ranged in average intensity between 1.0 and 32.0 mm/h, and had recurrence intervals of two years or less. Threshold rainfall conditions for floods and debris flows sufficiently large to pose threats to life and property from recently burned areas in south-central, and southwestern, Colorado are defined by: I = 6.5D^− 0.7 and I = 9.5D^− 0.7, respectively, where I = rainfall intensity (in mm/h) and D = duration (in hours).Debris flows were generated from 68 recently burned areas in southern California in response to long-duration frontal storms. The flows occurred after as little as two hours, and up to 16 h, of low-intensity (2–10 mm/h) rainfall. The storms lasted between 5.5 and 33 h, with average intensities between 1.3 and 20.4 mm/h, and had recurrence intervals of two years or less. Threshold rainfall conditions for life- and property-threatening floods and debris flows during the first winter season following fires in Ventura County, and in the San Bernardino, San Gabriel and San Jacinto Mountains of southern California are defined by I = 12.5D^−0.4, and I = 7.2D^−0.4, respectively. A threshold defined for flood and debris-flow conditions following a year of vegetative recovery and sediment removal for the San Bernardino, San Gabriel and San Jacinto Mountains of I = 14.0D^−0.5 is approximately 25 mm/h higher than that developed for the first year following fires.The thresholds defined here are significantly lower than most identified for unburned settings, perhaps because of the difference between extremely rapid, runoff-dominated processes acting in burned areas and longer-term, infiltration-dominated processes on unburned hillslopes.     

Simulating the 1999 Capbreton canyon turbidity current with a Cellular Automata model

A numerical model has been developed for the simulation of turbidity currents driven by nonuniform, non cohesive sediment and flowing over a complex three dimensional submarine topography. The model is based on an alternative approach known as Cellular Automata paradigm. The model is validated by comparing a simulation with a reported field-scale event. The chosen case is a turbidity current which occurred in Capbreton Canyon and was initiated by a storm in December 1999. Using data from recent oceanographic cruises, the deposit of the event has been precisely described, which constrain values of model parameters. The model simulates the 1999 turbidity current over the actual canyon topography and related turbidite using three different types of particle. The model successfully simulates areas of erosion and deposition in the canyon. It predicts the vertical and longitudinal grain size evolution, and shows that the fining-up sequence can be deposited by several phases of deposition and erosion related to the current energetic variation during its evolution. This result could explain the presence of intrabed contacts or the frequent lack of facies in Bouma sequences.     

Atmospheric circulation and storminess derived from Royal Navy logbooks: 1685 to 1750

This paper is concerned with the use of Royal Navy ships’ logbooks for the period 1685 to 1750, thereby embracing the oldest members of this documentary series that extends to the present day. The geographic range of the undertaking is confined to the English Channel and its western approaches where the abundance of logbooks for this period allows for the abstraction of a daily series of wind force and direction data. These are verified and processed for inclusion in a database from which indices are derived for air circulation patterns based on the frequency of winds from north, east, south and west quarters, and of gale frequency, based on the contemporary terminology of wind force. The methods by which the data are abstracted and processed are described, as is the nature of the raw data and source material. The results provide a uniquely detailed insight into the changing patterns of air circulation over this critical period that marked the transition from the depths of the Little Ice Age in the late seventeenth century. Attention is also drawn to the changing nature of gale frequency, which revealed a notable decrease over the study period. Associations between changing circulation patterns and temperature regimes are also explored.     

PHYSICO‐GEOCHEMICAL AND MINERAL COMPOSITION OF NEEM TREE SOILS AND RELATION TO ORGANIC PROPERTIES

The Neem tree, the oil of which has a long history of pesticide, fertilizer and medicinal use in India, has been studied extensively for its organic compounds. Here we present a physical, mineralogical and geochemical database resulting from the analyses of two Neem soil profiles (epipedons) in India. Neem tree derivatives are used in the manufacture of a variety of products, from anti‐bacterial drugs and insecticides to fertilizers and animal feeds. A preliminary geochemical and mineralogical analysis of Neem soils is made to explore the potential for chemical links between Neem tree derivatives and soils. Physical soil characteristics, including colour, texture and clay mineralogy, suggest the two pedons formed under different hydrological regimes, and hence, are products of different leaching environments, one well‐drained site, the other poorly drained. Geochemically, the two Neem soils exhibit similarities, with elevated concentrations of Th and rare earth elements. These elements are of interest because of their association with phosphates, especially monazite and apatite, and the potential link to fertilizer derivatives. Higher concentrations of trace elements in the soils may be linked to nutritional derivatives and to cell growth in the Neem tree.