Comparison of three oxidation methods used for the analysis of the dissolved organic carbon in seawater

Three methods for the determination of dissolved organic carbon in seawater were compared. Samples were analysed using persulphate oxidation, high-temperature combustion, and ultraviolet photo-oxidation. The dissolved organic carbon content of the seawater samples ranged from 0.6 to 1.6 mg C/I. This study shows that results of high-temperature oxidation and photo-oxidation procedures differ by less than 5%, whereas results with persulphate oxidation are about 15% less than those obtained with the high-temperature oxidation. The relative merits of each of the oxidation techniques for the determination of organic matter in seawater are discussed.     

3,4-benzopyrene and perylene in mussels, Mytilus sp., from the Laguna Veneta,North-East Italy

From July, 1975 to November, 1976 mussels from the Laguna Veneta, north-east Italy, and the adjacent Adriatic Sea were collected bimonthly at ten stations and analysed for 3,4-benzopyrene (BaP) and perylene (Pe) content. Mean concentrations were in the range 12·0–135·1 μg/kg dry weight for BaP and 1·5–16·9 μg/kg for Pe, but values as high as 327 μg/kg for BaP and 71 μg/kg for Pe have been measured. The distribution of BaP and Pe closely matches previous results on petroleum hydrocarbon contamination in mussels from this area and indicates that the major portion of BaP and Pe in these bivalves is due principally to human activities.     

Dispersal patterns of clay minerals in the sediments of the eastern Mediterranean Sea

A semiquantitative X-ray diffraction study of the finer-than-2μ-size fraction of the surface sediments of the eastern Mediterranean Sea has been carried out. On the basis of the abundances and the distributional patterns of the different clay minerals six mineral assemblages are distinguished. These assemblages have distinctive sources and their dispersal reflects different agents of transport in the eastern Mediterranean Sea.     

Bifurcating and wandering ocean ridges: A progress report

First conclusions of a study of the fault pattern in the North Atlantic ocean are briefly outlined. Correlation of fracture zones in deep ocean basins, even over short distances (30 miles) is difficult when using only topographic and seismic profiler data, and requires the additional criterion that the magnetic pattern is shifted along the fracture zones. This implies that each track must be paralleled by at least one more track at close distance to detect breaks in the magnetic pattern.Transform faults are regarded as complementary to the median rift, which, as a tension fault, should be normal to the direction of maximum strain according to laboratory experiments by Gramberg. Median rift segments and transform faults together form an orthogonal system approximating an originally irregular but continuous fissure.Mantle convection currents are thought to be the agents of continental drift. In view of the dimensions of convection cells, a direct coupling between ridges (or ridge segments) and the upwelling branch of a convection current seems impossible. Thus the known bifurcations of mid-ocean ridges in the Indian and in the Pacific Ocean may be interpreted as the result of a divergence of the horizontal branch of a convection cell or a divergence of the movements of crustal plates through collision of continents. Secondary fissures would lead to the development of secondary ridges that cannot be distinguished from primary ridges. In this concept mid-ocean ridges can partake in the horizontal movement by asymmetrical spreading. This might explain the disappearance of the East Pacific Rise under the North American continent.The resulting convection current system is simple: one upwelling and one downgoing current as two complementary helices winding round the earth. Ways are indicated to check several aspects of the proposed hypotheses.     

Studies on the determination of inorganic iodine in seawater

Existing methods for the determination of the various forms of iodine present in seawater are laborious or unwieldy in use. This paper describes modified forms of the iodate and total iodine methods described by Barkley and Thompson (1960), a spectrophotometric procedure for iodate determination derived from Johannesson's (1958) work, and an automatic method for total iodine determination. Procedures for iodate and total-iodine determination which are suitable for use aboard ship, are recommended. Both procedures for iodate determination returned a standard deviation close to 0.5 μg/l when several replicate samples of a seawater containing approximately 30 μg/l of iodate-iodine were analysed. The automatic method for total iodine determination yielded a standard deviation of 0.8 μg/l by the repeated analysis of a seawater containing a total of approximately 50 μg/l of iodine. Suitable methods for the filtration and storage of seawater are also described.     

Plate boundaries and evolution of the Solomon Sea region

The Solomon Sea Plate was widely developed during late Oligocene, separating the proto-West Melanesian Arc from the proto-Trobriand Arc. Spreading in the Bismarck Sea and in the Woodlark Basin resulted from interaction between the Pacific and Australian Plates, specifically from the collision of the proto-West Melanesian Arc with north New Guinea, which occurred after arc reversal. This model explains the extensive Miocene, Pliocene, and Quaternary volcanism of the Papua New Guinea mainland as it related to southward subduction of the Trobriand Trough. Our interpreted plate motions are concordant with the geological evidence onshore and also with complex tectonic features in the Solomon Sea Basin Region.     

A random walk model for simulating simultaneous currents at several depths

Empirical orthogonal function (EOF) analysis is used in conjunction with Markov chains to generate simultaneous current time series at several depths with a random walk model. Duration statistics and probability distributions for EOF modes obtained from real data are used to generate transition probability matrices for the random walk model. New time series of EOF modes are generated, and then combined to produce current time series. The technique has been tested on data from Haltenbanken. Statistical properties of real and simulated time series were compared. Results indicate that the model is acceptable as a tool in simulating current time series to be used in offshore operation models.     

Gravity anomalies over inactive fracture zones in the central North Atlantic

The basement topography and the free-air gravity along two profiles in the central North Atlantic between 16° and 25° N, crossing a number of fracture zones, were divided in three wavelength intervals. Two-dimensional modelling shows that the short wavelength (>50 km) gravity is well explained by uncompensated topography (mainly spreading topography). For the long wavelengths (>200 km) there is no correlation of topography and gravity. In principle this topography is compensated. Residual anomalies comprise the Ridge effect as well as regional anomalies related to depth anomalies. The 50 to 200km band-pass filtered topography and gravity contain relevant information on fracture zones. Models require a base of the crust that parallels the topography rather than a form of regional compensation. For an explanation of this crustal model that has the appearance of frozen in normal faults we have to consider the typical morphology as created in the transform domain. The geophysical processes that cause this morphology are still an object of study.