Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.     

Petrogenesis and paleotectonic history of the Wild Bight Group,an Ordovician rifted island arc in central Newfoundland

The Wild Bight Group (WBG) is a sequence of early and middle Ordovician volcanic, subvolcanic and epiclastic rocks, part of the Dunnage Tectonostratigraphic Zone of the Newfoundland Appalachians. A detailed geochemical and Nd-isotopic study of the volcanic and subvolcanic rocks has been carried out to determine the geochemical characteristics of the rocks, interpret their palcotectonic environments and constrain their petrogenetic history. The lower and central stratigraphic levels of the WBG contain mafic volcanic rocks with island-arc geochemical signatures, including LREE-enriched are tholeiites with _Nd(t) =-0.1 to +2.2 (type A-I), LREE-depleted arc tholeiites with _Nd(t) =+5.6 to +7.1 (type A-II) and an unusual suite of strongly incompatible-element depleted tholeiites in which _Nd(t) ranges from-0.9 to +4.6 and is negatively correlated with¹⁴⁷Sm/¹⁴⁴Nd (type A-III). High-silica, low-K rhyolites occur locally in the central part of the stratigraphy, associated with mafic rocks of arc affinity, and have _Nd(t) =+4.7 to +5.4. The upper stratigraphic levels of the WBG dominantly contain rocks with non-arc geochemical signatures, including alkalic basalts with _Nd(t) =+4.6 to +5.5 (type N-I), strongly LREE- and incompatible element-enriched tholeiites that are transitional between alkalic and non-alkalic rocks with _Nd(t) =+4.4 to +7.0 (type N-II) and rocks with flat to slightly LREE-enriched patterns and _Nd(t) =+5.1 to +7.4 (type N-III). Rocks with non-arc and arc signatures are locally interbedded near the stratigraphic type of the WBG. Nd-isotopic data in the type A-I and A-II rocks are generally compatible with mixing/partial melting models involving depleted mantle, variably contaminated by a subducted crustally-derived sediment. The petrogenesis of type A-III rocks must involve source mixing and multi-stage partial melting, but the details are not clear. The geochemistry and Nd isotope data for types N-I, N-II and N-III rocks are compatible with petrogenetic models involving variable partial melting of a source similar to that postulated for modern oceanic island basalts. Comparison of the WBG with modern analogues suggests a 3-stage developmental model: stage 1) island-arc volcanism (eruption of type mafic volcancs); stage 2) arc-rifting (continued eruption of type A-I, A-I, eruption of types A-II and A-III mafic volcanics and high-silica, low-K rhyolites); and stage 3) back-arc basin volcanism (continued minor eruption of type A-I basalts, eruption of types N-I, N-II, N-III basalts). Stages 1 and 2 volcanism involved partial melting of subduction contaminated mantle, while stage 3 volcanism utilized depleted-mantle sources not affected by the subducting slab. This model provides a basis for interpreting coeval sequences in central Newfoundland and a comparative framework for some early Paleozoic oceanic volcanic sequences elsewhere in the Appalachian orogen.     

Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.     

Deep drilling at the Siljan Ring impact structure: oxygen-isotope geochemistry of granite

The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, ¹⁸O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5 at 5760 m depth. In contrast, feldspar ¹⁸O values decrease with depth from near 10 at the surface to 7.1 at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of ¹⁸O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar ¹⁸O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100–300° C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500° C) exchange between alkali feldspar and fluids. The high-temperature exchange may have been a post-impact event involving impact-heated fluids, or a post-magmatic event.     

Examples of predominantly two-body orbits in the Sun-Jupiter asteroid system

Accurate numerical continuation of families of plane symmetric direct periodic orbits around the large primary in the Sun-Jupiter case of the restricted problem of three bodies allows the determination of the vertical branching points where families of three-dimensional symmetric periodic orbits bifurcate from the planar ones. Three families of plane periodic orbits, and the initial segments of ten bifurcating families of three-dimensional ones are determined. The stability of these families is examined and examples of their orbits are illustrated.     

A Monte Carlo investigation of Jovian perturbations on short-period comet orbits

We present statistical distributions of Jovian perturbations on short-period comet orbits resulting from accurate numerical integrations. Our sample of 60, 000 cometary orbits with low inclinations and random orientations is characterized by perihelia between 0 and 7 AU and aphelia between 4 and 13 AU. The perturbations considered are those experienced because of Jupiter's gravitation per orbital revolution by the comets. Regularization and accurate step-length control in the numerical integration gives statistical results appreciably different from those computed by Rickman and Vaghi (1978). Their use of a crude method of integration led to erroneous results for close encounters. Strong asymmetries of the $\text{δ(}\text{1}\text{a}\text{)}$ distributions, in particular for the extreme tails, are observed for perihelion- or aphelion-tangent orbits. These orbits are also shown to experience the strongest energy perturbations on the average. Some results concerning the perturbations of Tisserand parameters are indicated. The perturbation distributions for the angular elements are described and discussed. The role of the minimum distance from Jupiter as an indicator of perturbations is investigated.     

OSO-8 observations of CaII H and K,MgII h and k,Lα and Lβ above a sunspot

Observations with the French (L.P.S.P.) experiment on board OSO-8 of a sunspot and nearby plage region are described. The behaviour of the emission cores of the Ca II H and K and Mg II h and k resonance lines is very similar and the correspondence in intensity between the four lines persists in all observed features. In contrast, the Lyman lines show little correlation with the other lines. Their emission regions appear broader in the spectroheliograms than the underlying sunspot structure and must not necessarily possess a counterpart in lower layers. From the central intensity of L above the umbra an electron density of 4.3 × 10¹⁰ cm^-3 n _e ^* 2.3 × 10¹¹ cm^-3 at 20 000 K is estimated.Mitteilungen aus dem Kiepenheuer-Institut Nr. 186.Stockholm Observatorium, S-13300 Saltsjöbaden, Sweden.Laboratoire de Physique Stellaire et Planétaire, CNRS, P.O. Box 10, F-91370 Verrières-le-Buisson, France.     

Radius of convergence of Lie series for some elliptic elements

For equatorial orbits about an oblate body, we show that the Lie series for the elliptic elementse,f,l and diverge when the oblateness exceeds a critical multiple of the transformed eccentricity constant. The use of similar truncated series expansions for such elliptic elements by Brouwer accounts for the first-order errors at low eccentricity in his derived coordinates for an artificial satellite.     

The inter-relationship of hard X-ray and EUV bursts during solar flares

A comparison is made between the flux-versus-time profile in the EUV band and the thick target electron flux profile as inferred from hard X-rays for a number of moderately large solar flares. This complements Kane and Donnelly's (1971) study of small flares. The hard X-ray data are from ESRO TD-1A and the EUV inferred from SFD observations.Use of a ₂ minimising method shows that the best overall fit between the profile fine structures obtains for synchronism to 5 s which is within the timing accuracy. This suggests that neither conduction nor convection is fast enough as the primary mechanism of energy transport into the EUV flare and rather favours heating by the electrons themselves or by some MHD wave process much faster than acoustic waves.The electron power deposited, for a thick target model, is however far greater than the EUV luminosity for any reasonable assumptions about the area and depth over which EUV is emitted. This means that either most of the power deposited is conducted away to the optical flare or that only a fraction 1–10% of the X-ray emitting electrons are injected downwards. Recent work on H flare heating strongly favours the latter alternative - i.e. that electrons are mostly confined in the corona.