In the processes of discrimination between oil-cracked gases and kerogen-cracked gases, Behar and Pinzgofer et al.’s results were adopted in the former researches, in which the ratio of C2/C3 is basically a constant while the ratio of C1/C2 gradually increases in the course of primary cracking of kerogen. Otherwise in the course of secondary cracking of oil, the ratio of C2/C3 increases rapidly while C1/C2 keeps relatively stable. Our study on analogue experiment shows that, whether it is oil or kerogen, in its process of gas generating by cracking, the ratios of C2/C3, C1/C2 or C1/C3 will all be increased with the growth of thermal conditions. In comparison, the ratio of C2/C3, which is affected by genetic type to some comparatively less extent, mainly responds to the maturity of gases, while the value of C2/C3 is about 2, and that of C2/iC4 is about 10, and the corresponding value of Ro is about 1.5%–1.6%. The influence of gas source on C2/C3 is less than that of gas maturity, otherwise C1/C2 (or C1/C3) is obviously affected by cracking matrices. The ratios of C1/C2, C1/C3 of oil-cracked gases are less than that of kerogen-cracked gases, under the condition that the ratios of C2/C3 are similar in value, so are the value of dryness indexes. There exists wide diffidence between this view and the former discrimination method in theory. The analysis of the spot sample indicates that we can apply the above basic view to dealing efficiently with the problem of the discrimination between oil-cracked gas and kerogen-cracked gas.
Phase equilibria for the NaCl/KCl-PEG400-H_2 O aqueous ternary systems at 298 K were studied using an isothermal dissolution method. In addition,the densities and refractive indices were determined. The corresponding phase diagrams,as well as the density vs. composition and refractive index vs.composition diagrams,were plotted. Results revealed that over the entire PEG400 composition range studied at 298 K only 1 liquid phase was obtained,without the formation of a biphase region. The phase diagrams of these 2 systems consist of 1 homogeneous area with unsaturated liquid( L) and an equilibrium area containing the solid phase of NaCl/KCl and the saturated liquid phase( S + L). The solubility of NaCl/KCl decreases with the addition of PEG400 at 298 K. 相似文献
The Purdue Regional Model (PRM) is applied to study the evolution of regional climate and weather systems during the heavy precipitation over Korea and China between 30 July and 18 August 1998. The results show that heavy rainfall along the Mei-yu and Changma front was due to the combination of: (1) an anomalous 850 hPa subtropical high, (2) a stronger baroclinicity around 40°N over eastern Asia and a low pressure located to the north of the front, and (3) an excessive evaporation from abnormal wet, warm land. The precipitation ended by 18 August when the subtropical high had retreated and the low pressure in Mongolia moved away from Asia continent. The model reproduced in great detail the observed baroclinic waves to the north, subtropical high and low-level jet to the south, and the front with heavy precipitation extending from southern China, and the Korean peninsula to Japan. High correlations are found for mass, momentum, and moisture fields between model simulation and the European Center for Medium Range Weather Forecast (ECMWF) reanalysis for the 20-day means. 相似文献