Chemical processes and migration of elements during retrogression of a staurolite-zone assemblage in western North Carolina

A detailed study of retrograde alteration of a staurolite porphyroblast and its surrounding matrix of mica schist has made use of petrographic, modal, and microprobe analysis. Retrogression was to the garnet zone of metamorphism and apparently occurred largely after a temperature decline of 70–100° C. The event caused metasomatic removal of Zn but may have been isochemical relative to other analyzed elements. The best estimate of the overall reaction is: 1 staurolite+3.018 biotite+3.550 quartz+0.629 albite +0.014 anorthite+0.678 NaCl+14.004 H₂O =3.274 Na-rich muscovite+3.561 chlorite +0.273 ilmenite+0.110 chloritoid+0.039 garnet +0.339 ZnCl₂.Non-systematic variation in composition of analyzed minerals is revealed by statistical treatment of replicate analyses. Such variation involves monovalent and divalent cations within many minerals, but is most pronounced within retrograde muscovite. Muscovite variation involves Si and Al as well as FM and alkalis and does not follow a phengite law of charge-coupled substitution.Relative to the core of the retrograded staurolite crystal, zoning is seen in averaged muscovite compositions and in development of incompatible mineral assemblages, which include chloritoid well within retrograded staurolite but biotite within the matrix. A local gradient in the chemical potential of an Al-bearing component was likely present during retrogression.Alteration of staurolite was probably accomplished by reaction and diffusion through the medium of an intergranular fluid phase. Relative to staurolite, migration of elements involved immigration of considerable amounts of Mg, Na, K, and H and expulsion of Al, Fe, Zn, and O. It is inferred that concentration of Al within the fluid phase was considerably lower than those of monovalent and divalent cations.Preservation of considerable staurolite and evidence for a local concentration gradient of Al in the fluid phase suggest that limited amounts of H₂O were available. Expulsion of Zn suggests that much water was not consumed locally but exited the terrane. An attempt at resolution of this dilemna involves fracture-channelized infiltration of H₂O into the rock. A more regional petrographic study of retrogression suggests that H₂O which entered the rock may have been liberated initially by prograde dehydration at a moderately greater depth of 2–3 km.Results of this study, especially the non-phengitic nature of crystal-chemical substitution within muscovite, indicate chemical reaction under conditions of disequilibrium. Apparently, extent of retrogression was controlled by availability of H₂O rather than by thermochemical equilibria.     

Zum Einfluß von Rückständen von Zink- und Bleiverbindungen im Wasser auf die Assimilation von Fontinalis antipyretica

The carbon-dioxide assimilation of Fontinalis antipyretica is inhibited by 100 mg/1Zn²⁺ or Pb²⁺, without a lethal effect being caused. With increasing time of exposure from one to six days the threshold value of toxicity is lowered and at the same time the net assimilation is reduced within the range of concentration of 0.1 mg/1. In the ecological optimum of the environmental conditions the toxicity is weaker than under other unfavourable environmental conditions at the same time. Therefore, the photoecologically optimum illumination of 1200 lx is an effective bioprotector against phytotoxic lead ion concentrations, so that at 1200 lx also at a comparatively high load a positive photosynthesis balance can be maintained. In the dark, in the first hour after the application of the lead ions dissimilation is a function of concentration, subsequently the respiration differences decrease very much in the range between 0 and 100 mg/1 lead(II)-ions. Stimulating effects could be demonstrated only by 0.01 mg/1 Pb²⁺ and only for the carbondioxide assimilation.     

The Use of Seasonal Climate Forecasting in Policymaking: Lessons from Northeast Brazil

This article examines the use of seasonal climate forecasting in public and private efforts to mitigate the impacts of drought in Ceará, Northeast Brazil. Here, forecasts have been directed towards small scale, rainfed agriculturalists as well as state and local level policymakers in the areas of agriculture, water management, and emergency drought relief. In assessing possibilities and constraints of forecast application in Ceará, the present analysis takes into account three types of variables: (a)characteristics of the forecasts; (b) policymaking systems; and (c)institutional environments. We conclude that, on the one hand, several factors in the Ceará case have limited the effectiveness of seasonal climate forecast use. First, the current level of skill of the forecasts is inadequate for the needs of policy development and farmer decisionmaking. Second, forecast information application has been subject to distortion, misinterpretation and political manipulation. Third, focus on the forecast as a product until recently neglected to take into account end users' needs and decisionmaking behavior. On the other hand, climate forecasting has the potential to offer a dramatic opportunity for state and local level bureaucracies to embark on a path of proactive drought planning.     

Socio-spatial polarization and the (re-)distribution of deprived groups in world cities: A case study of Hong Kong

This paper draws on theoretical discussions of world cities to analyze socio-spatial polarization and (re-)distribution of deprived groups in Hong Kong in the 2000s. Intensifying global economic restructuring processes have induced socio-economic polarization, thereby producing deprived groups although the spatial outcomes may depend on the city-specific context. When local policies do not counteract the polarization trend, a spatial manifestation of widening socio-economic gaps can be expected. Intensified pro-growth policies adopted since Hong Kong’s return to Chinese rule in 1997 and during its economic recession in the early 2000s have worsened the impact of globalization-induced socio-economic and spatial restructuring. Census data from 2001 and 2011 show increasingly differentiated socio-economic profiles at the district level. The analysis offered in this study also points to a decreased socially mixed society in 2011 when the deprived groups lived in districts with less presence of the advantaged population.     

Transfer,loss and physical processing of water in hit-and-run collisions of planetary embryos

Collisions between large, similar-sized bodies are believed to shape the final characteristics and composition of terrestrial planets. Their inventories of volatiles such as water are either delivered or at least significantly modified by such events. Besides the transition from accretion to erosion with increasing impact velocity, similar-sized collisions can also result in hit-and-run outcomes for sufficiently oblique impact angles and large enough projectile-to-target mass ratios. We study volatile transfer and loss focusing on hit-and-run encounters by means of smooth particle hydrodynamics simulations, including all main parameters: impact velocity, impact angle, mass ratio and also the total colliding mass. We find a broad range of overall water losses, up to 75% in the most energetic hit-and-run events, and confirm the much more severe consequences for the smaller body also for stripping of volatile layers. Transfer of water between projectile and target inventories is found to be mostly rather inefficient, and final water contents are dominated by pre-collision inventories reduced by impact losses, for similar pre-collision water mass fractions. Comparison with our numerical results shows that current collision outcome models are not accurate enough to reliably predict these composition changes in hit-and-run events. To also account for non-mechanical losses, we estimate the amount of collisionally vaporized water over a broad range of masses and find that these contributions are particularly important in collisions of \(\sim \) Mars-sized bodies, with sufficiently high impact energies, but still relatively low gravity. Our results clearly indicate that the cumulative effect of several (hit-and-run) collisions can efficiently strip protoplanets of their volatile layers, especially the smaller body, as it might be common, e.g., for Earth-mass planets in systems with Super-Earths. An accurate model for stripping of volatiles that can be included in future planet formation simulations has to account for the peculiarities of hit-and-run events and track compositional changes in both large post-collision fragments.     

Charting the territory: Exploring stakeholder reactions to the prospect of seafloor exploration and mining in Australia

Geological surveys of Australia’s marine territory have revealed significant potential for development of a marine resource industry. As onshore mineral deposits become harder to find, less accessible to their market and more challenging to extract, seafloor exploration and mining becomes an economically viable option. However, evidence from industry and environmental literature suggests that social acceptance will be important in determining the future of this industry in Australia. This paper reports on findings from research investigating the social viability of seafloor mining in Australia. A combination of interviews and focus groups were used to explore industry and community reactions to the possible development of seafloor mining in Australia. Although stakeholders’ reactions were variable, the majority of the participants were reluctant to see development of seafloor mining in Australia, primarily because of concerns about the industry’s potential environmental impact. All stakeholders sought further information about the benefits and costs associated with the industry suggesting that they did not yet have a fixed attitude towards the industry. Stakeholders favoured a precautionary approach towards the industry, supported by rigorous scientific analysis of the potential environmental impacts, transparent and socially responsive management processes and meaningful engagement with stakeholders.     

Selective uptake of prokaryotic picoplankton by a marine sponge (Callyspongia sp.) within an oligotrophic coastal system

Marine sponges are key players in the transfer of carbon from the pelagic microbial food web into the benthos. Selective uptake of prokaryotic picoplankton (<2 μm) by a demosponge (Callyspongia sp.), and carbon flux through this process, were examined for the first time in the oligotrophic coastal waters of southwestern Australia, where sponge abundance and biodiversity ranks among the highest in the world. Water sampling and flow rate measurements were conducted over five sampling occasions following the InEx method of Yahel et al. (2005), with heterotrophic bacteria and autotrophic Synechococcus cyanobacteria identified and enumerated by flow cytometry. Callyspongia sp. demonstrated high filtration efficiencies, particularly for high DNA (HDNA) bacteria (up to 85.3% in summer 2008) and Synechococcus (up to 91.1% in autumn 2007), however efficiency varied non-uniformly with time and food type (p < 0.01). Overall filtration efficiency for Synechococcus (86.6 ± 6.3%; mean ± s.d.) was always significantly higher (p < 0.05) than for low DNA (LDNA) bacteria (40 ± 17.2%), except during winter 2007 (p = 0.14) when ambient Synechococcus concentrations were lowest. When compared to ambient abundances of the different food types, Callyspongia sp. exhibited consistently negative selectivity for LDNA bacteria and positive selectivity for Synechococcus, while HDNA bacteria was generally a neutral or positive selection. The total carbon removal rate (sum of all prokaryotic picoplankton cells), calculated on a per unit area basis, varied significantly with time (p < 0.01), with lowest rates recorded during the winter (0.5 ± 0.4–0.6 ± 0.8 mg C m⁻² d⁻¹) and highest values recorded in summer (3.5 ± 1.9 mg C m⁻² d⁻¹). These flux estimates quantify the role of a demosponge species in the ultimate fate of prokaryotic picoplankton within the nearshore food webs of southwestern Australia, and support the conclusion that sponges actively select food particles that optimise their nutritional intake.     

Interaction between nulls and emission in the pulsar B0834+06

We present a detailed study of the single pulses of the bright radio pulsar B0834+06, and offer evidence that the dominant periodic modulation in this pulsar's emission governs the occurrence of nulls. The nulls of B0834+06 constitute approximately 9 per cent of the total pulses and we demonstrate that they do not occur at random in the pulse sequence. On the contrary, they are found to occur preferentially close to the minimum of the pulsar's emission cycle, whose period jitters around a central value of P ₃≈ 2.17 rotation periods. It is likely that the intrinsic duration of the nulls averages about 0.2 times the pulsar rotation period. Surprisingly, the clearly distinct population of nulls and partial nulls of B0834+06 exhibit a two-peak profile slightly broader than that of the normal emission. This is in contrast to the profile of extremely weak normal pulses, which is narrower than the overall profile. A flow/counterflow model for the pulsar's two components can reproduce the essential observed features of the emission in its dominant mode, with nulls occurring at the point where the minima of the two systems are aligned. This suggests that the observed nulling rate is determined by the chance positioning of our sightline with respect to the system. If the flow is interpreted as part of a circulating carousel, a fit yields a best estimate of 14 'sparks'.     

The influence of river training on mountain channel changes (Polish Carpathian Mountains)

The purpose of this paper is to explain the influence of river training on channel changes in mountain rivers. Also considered are the causes of failure of different training schemes. The research was conducted on the regulated Mszanka and Porębianka Rivers, belonging to the Raba River drainage basin in the Polish Flysh Carpathian Mountains. Channel mapping carried out in 2004 drew attention to the contemporary morphology of the channels and the development of their dynamic typology. General changes in channel morphometry and land cover were identified by comparing cartographic sources from various years. Archive material from Cracow's Regional Water Management Authority (RZGW) was used to analyse the detailed channel changes caused by each regulation structure. The material consisted of technical designs of individual training works, as well as plans, longitudinal profiles and cross-sections of trained channel reaches. A series of minimum annual water stages at the Mszana Dolna gauging station was used to determine the tendency of channel bed degradation over 53 years. During the first half of the 20th century, the middle and lower courses of the Mszanka and Porębianka Rivers had braided patterns. The slopes, mostly covered with crops, were an important source of sediment delivery to the river channels. Today, both channels are single-threaded, narrow and sinuous. Downcutting is the leading process transforming the channels. They cut down to bedrock along about 60% of their lengths. The main type of channel is an erosion channel, which occurs also in the middle and lower courses of the rivers. The channel sediment deficit is an important cause for river incision. Sediment supply to the channels was reduced after a replacement of crops on the slopes by meadows or forests. Gravel mining has also caused channel downcutting. The rapid channel changes began after 1959, as systematic training was introduced. Channel regulation seems therefore to be a major factor determining channel adjustment. Debris dams and groynes were built before 1980 and these caused the greatest change of channel pattern, increase of channel gradient and magnitude of river incision. After that date the measures mostly involved drop structures. From then on, the rate of downcutting decreased considerably, but has not ceased. The rivers continued to incise until bedrock was exposed or training structures were destroyed. After that, a tendency to lateral migration and local braiding were observed in the deepened channel. The channels displayed a tendency to return to their morphology and dynamic from before the training. The results demonstrate that river training distorts the equilibrium of channel systems. A channel becomes divided into artificial reaches, which later follow different evolutionary patterns. Most training schemes on mountain channels are ineffective in the long term, as river managers seem to consider a channel at a reach scale only. Individual channel reaches, however, are not independent but rather form a system that must be managed at the entire channel scale.     

The decrease in shear stress and increase in transport rates subsequent to an increase in sand supply to a gravel-bed channel

It is generally accepted that a gravel-bed river will aggrade if the supply of sediment to the river is increased. In a series of flume experiments using constant discharge and gravel feed rate, sand feed rates were increased to 6.1 times that of gravel. The slope of the bed decreased with increasing sand supply, indicating that the increased sediment load could be transported at the same rate due to a decrease in shear stresses. These results extend previous experiments to a wider range of boundary conditions. A recent surface transport model is used to predict the changes in bed composition and transport using the same sediment supply composition and feed rates as in the laboratory experiments. This model reasonably predicts a decrease in the reference shear stresses of the sand and gravel fractions as the sand supply is increased. An increase in sand supply can increase the mobility of gravel fractions in the stream bed, which can lead to bed degradation and preferential evacuation of these sediments from the river.