Occurrence and distribution of bacteria indicators,chemical tracers and pathogenic vibrios in Singapore coastal waters

Water quality in Singapore's coastal area was evaluated with microbial indicators, pathogenic vibrios, chemical tracers and physico-chemical parameters. Sampling sites were grouped into two clusters (coastal sites at (i) northern and (ii) southern part of Singapore). The coastal sites located at northern part of Singapore along the Johor Straits exhibited greater pollution. Principal component analysis revealed that sampling sites at Johor Straits have greater loading on carbamazepine, while turbidity poses greater influence on sampling sites at Singapore Straits. Detection of pathogenic vibrios was also more prominent at Johor Straits than the Singapore Straits. This study examined the spatial variations in Singapore's coastal water quality and provided the baseline information for health risk assessment and future pollution management.     

Toxicity studies of elemental sulfur in marine sediments

Elemental sulfur(ES) is a component essential for proper development of animals, but it can be toxic for aquatic organisms. The objectives of the study reported here included determination of ES concentrations in sediment collected in the area of the Gulf of Gdansk(Baltic Sea) and search for the possible correlations with the ecotoxicity results. Sediment samples were collected from four locations: the Vistula River mouth, in the Port Basin, in the area of discharge of the treated wastewater from the Wastewater Treatment Plant(WWTP) and in the area of the sunken World War Ⅱ s/s 'Stuttgart' shipwreck. The levels of elemental sulfur were determined using a gas chromatograph coupled with a mass spectrometer(GC-MS). Toxicity of marine sediment samples was estimated for three biotest organisms-bioluminescent bacteria Vibrio fischeri, crustacean Heterocypris incongruens, and Synapis alba plant. The highest toxicity of sediments for all indicator organisms was observed in samples taken at the place of the shipwreck(2-100%). The same samples had a high sulfur content(16.7-143.2 μg/g dry weight(d.w.))therefore, it was decided to investigate whether the presence of ES in the sediment in the studied area can have an impact on the results of the ecotoxicity determination in real samples. However, the removal of sulfur from the samples resulted in no significant changes in the level of toxicity of the samples. In this research it could not be confirmed that the presence of elemental sulfur is the only factor responsible for the observed sediment toxicity. It seems that other compounds or their mixtures present in the sediment may have a significant influence on the results obtained.     

Constraints on Mercury’s Na exosphere: Combined MESSENGER and ground-based data

We have used observations of sodium emission obtained with the McMath-Pierce solar telescope and MESSENGER’s Mercury Atmospheric and Surface Composition Spectrometer (MASCS) to constrain models of Mercury’s sodium exosphere. The distribution of sodium in Mercury’s exosphere during the period January 12-15, 2008, was mapped using the McMath-Pierce solar telescope with the 5″ × 5″ image slicer to observe the D-line emission. On January 14, 2008, the Ultraviolet and Visible Spectrometer (UVVS) channel on MASCS sampled the sodium in Mercury’s anti-sunward tail region. We find that the bound exosphere has an equivalent temperature of 900-1200 K, and that this temperature can be achieved if the sodium is ejected either by photon-stimulated desorption (PSD) with a 1200 K Maxwellian velocity distribution, or by thermal accommodation of a hotter source. We were not able to discriminate between the two assumed velocity distributions of the ejected particles for the PSD, but the velocity distributions require different values of the thermal accommodation coefficient and result in different upper limits on impact vaporization. We were able to place a strong constraint on the impact vaporization rate that results in the release of neutral Na atoms with an upper limit of 2.1 × 10⁶ cm⁻² s⁻¹. The variability of the week-long ground-based observations can be explained by variations in the sources, including both PSD and ion-enhanced PSD, as well as possible temporal enhancements in meteoroid vaporization. Knowledge of both dayside and anti-sunward tail morphologies and radiances are necessary to correctly deduce the exospheric source rates, processes, velocity distribution, and surface interaction.     

Environmental change,hydromorphological reference conditions and the restoration of Polish Carpathian rivers

In the twentieth century Polish Carpathian rivers were considerably modified by channelization and gravel mining, with significant detrimental effects to their ecological integrity, vertical stability of the streambeds and flood hazard to downstream river reaches. Restoration of the rivers is thus necessary to improve their ecological status and re‐establish geomorphic dynamic equilibrium conditions. Various approaches to defining hydromorphological reference conditions, proposed to date in river restoration literature, have serious deficiencies. In particular, environmental changes that took place in the catchments of Carpathian rivers during the twentieth century invalidate the historical state of the rivers as reference for their restoration. This is illustrated by a change from bar‐braided to island‐braided channel pattern that occurred in the past century in unmanaged sections of the Czarny Dunajec in response to a reduction in flow and sediment dynamics of the river. We indicate that reference conditions should be defined as those which exist or would exist under present environmental conditions in the catchment but without human influence on the channel, riparian zone and floodplain of the river which is to be restored. This assumption was tested through the evaluation of hydromorphological river quality of the Czarny Dunajec according to the European Standard EN‐14614. The evaluation confirmed a high‐status hydromorphological quality in an unmanaged channel section, which can thus be used as a reference for restoration of impacted river sections. Copyright © 2012 John Wiley & Sons, Ltd.     

Contemporary glacigenic inputs to the dust cycle

The importance of glacigenic dust in the Earth's system during glacial periods is widely acknowledged. Under contemporary conditions, the world's largest dust sources are in low‐lying, hot, arid regions and this is where most aeolian research is focused. However the processes of dust production and emissions are still operating in cold climate regions, particularly in proglacial areas. This paper assesses current understanding of the relationship between glacierised landscapes and dust emissions and inputs to the global dust cycle. It focuses on how elements in the glacial and aeolian geomorphic sub‐systems interact to determine the magnitude, frequency and timing of aeolian dust emissions, and on feedback mechanisms between the systems. Where they have been measured, dust emission intensity and deposition rates in glacierised catchments are very high, in some cases far exceeding those in lower latitudes, however, few studies span long time scales. The impact of future glacier retreat on the balance between sediment supply, availability and aeolian transport capacity and implications for glacigenic dust emissions is also considered. This balance depends on relative spatial and temporal changes in meltwater suspended sediment concentration and wind strengths, which promote dust emissions, and patterns and rates of soil development and vegetation succession on recently‐deglaciated terrain which protect sediments from deflation. Retreat of the Antarctic ice sheet could mean that in future glacigenic contributions to the dust cycle exceed those of non‐glacigenic sources in the southern hemisphere. Copyright © 2012 John Wiley & Sons, Ltd.     

Paleowind velocity and paleocurrents of pluvial Lake Manly,Death Valley,USA

Pluvial lake deposits are found throughout western North America and are frequently used to reconstruct regional paleoclimate. In Death Valley, California, USA, we apply the beach particle technique (BPT) of Adams (2003), Sedimentology, 50, 565–577 and Adams (2004), Sedimentology, 51, 671–673 to Lake Manly deposits at the Beatty Junction Bar Complex (BJBC), Desolation Canyon, and Manly Terraces and calculate paleowind velocities of 14–27 m/s. These wind velocities are within the range of present-day wind velocities recorded in the surrounding area. Sedimentary structures and clast provenance at Desolation Canyon and the Manly Terraces indicate sediment transport from north to south. Lake level, based on the elevation of constructional features, indicates that the hill west of the BJBC was an island and that the BJBC spits formed during simple lake regression. The data are consistent with the hypothesis that the present wind regime (velocity and direction) formed the pluvial Lake Manly features.     

Impact of the azores front propagation on deep ocean particle flux

The Azores Current originating as a branch of the Gulf Stream is a highly dynamic system in the subtropical North Atlantic. The associated front forms the northeastern boundary of the North Atlantic Subtropical Gyre. In this study we analyzed 42 years of assimilated modeled temperature fields to localize the position of the Azores Front at 22°W and observed a fast north- and southward propagation between 30°N and 37°N on monthly to decadal time scales. The North Atlantic Oscillation with correlated changes of the wind direction was identified as one driving mechanism. As the front is acting as a guide for Rossby waves, the signal of the front??s propagation is transferred to the western Atlantic and, among other atmospheric forcing mechanisms, induces a shifting of the Northern Wall of the Gulf Stream with one year delay. Shallower mixed layer depths in the northern frontal region of the Azores Current caused by the rise of the isotherms lead to nutrient supply and primary production different from those found in the southern frontal region of the current system. A high interannual variability is manifested in deep ocean particle flux, derived from a sediment trap in 2000 m water depth at the mooring site KIEL276 (33°N, 22°W) from 1993 to 2008, which is directly related to the phytoplankton bloom in the euphotic zone. This variability is explained by the propagation of the front and strong variations in the catchment areas of the sediment trap due to the associated eddy activity in the frontal region.     

Multi‐Criteria Analysis for Optimization of Sodium Chromate Production from Chromic Waste

The proposal of application of multi‐criteria analysis and technological quality method for optimization of technological processes on the case study of sodium chromate production variants from waste was presented. The research on the use of chromic waste for the production of sodium chromate made it possible to determine the optimal process parameters. Technological quality method was used to define the value of criterions for multi‐criteria analysis while multi‐criteria analysis allowed determining the impact of criterions weights for ranking variants of technological process. Both methods in a complex way evaluate the degree of modernization of technologies, describing them qualitatively within the area of environmental, technical, and the economic effects of the proposed technological variants. Based on the proposed evaluating criteria both methods yield comparable results. The most advantageous alternatives provided realization of the sodium chromate production process with the use of in‐process recycling of chromic mud, off‐site recycling of chromic tannery waste and on‐site recycling of waste from the old chromic heaps.     

A SIMS zircon age for a biostratigraphically dated Upper Viséan (Asbian) bentonite in the Central-European Variscides (Bardo Unit,Polish Sudetes)

A Lower Carboniferous platform sedimentary sequence (the Paprotnia Beds) in the Bardo Unit of the central Sudetes (NE part of the Bohemian Massif, SW Poland) is biostratigraphically well dated, based on rich macro- and micro-fossil evidence, as Late Viséan (late Asbian, crenistria, Go III α zone). The beds contain several bentonite layers, one of which was dated using the U–Pb SHRIMP method on volcanic zircons and yielded an age of 334 ± 3 Ma. This date fits well to the recently established chronostratigraphic limits of the Viséan, and is consistent with the newest isotopic age constraints of 336.5–332 Ma for the Asbian boundaries.     

Mineralogical and Geochemical Constraints on the Sediment Sources of Late Stone Age Pottery from the Birimi Site,Northern Ghana

The mineralogy and bulk chemical compositions of 15 Kintampo (Late Stone Age) potsherds from the Birimi site on the Gambaga Escarpment and eight samples of local sediment were determined with the intent of characterizing these wares and identifying the material used in their manufacture. Sediment from clay pits still used by potters north of the escarpment contains iron‐rich laterite clasts (100 × XFeO_t = 100 × FeO_t/[FeO_t + Al₂O₃ + SiO₂] ≥10). Sedimentary clasts in stream sediments are relatively siliceous and iron‐poor (100 × XFeO_t < 10). Bulk geochemical data together with the compositions of lithic clasts (laterite, siltstone/sandstone) link the pottery to sediment sources, including escarpment sediments not presently used by Ghanaian potters. Fresh granite clasts found in some of the sherds were not found in the analyzed sediment samples, although some of their distinctive mineralogical constituents (e.g., variably barian alkali feldspar) are present. The analytical data suggest that pots found at Birimi were made locally by mixing escarpment sediment with clay and stream sediment brought in from below the escarpment. This contrasts with present‐day practice, whereby the pots themselves are imported. The place where Birimi pottery was made and the outcrop source of aluminous sediment (mudstone with an “escarpment” trace element signature) used in these wares, however, remain unidentified. © 2013 Wiley Periodicals, Inc.