Reflections on integrating operation and maintenance activities of offshore wind farms and mariculture

Offshore waters are in a process of transition, revealing diverse and heterogenic interests in marine resources. This increasing complexity leads to limits in developing and managing the different and often spatially overlapping maritime activities independently of one another. On a showcase basis we discuss ways and manners as well as the preconditions of an offshore co-management approach for the fledgling actor groups offshore wind farmers and mariculturists. Both groups may benefit through the integration of operation and maintenance (O&M) activities. Their resources in terms of offers, needs and constraints characteristics and thereof deduced potentialities for interaction is a prerequisite for initiating a co-management process. This process is more likely to develop and succeed if an interface management that acts as a moderator, disclosing the interests of the actor groups and offering possibilities for concerted action, guides it. It is concluded that such an institutional arrangement may in the long term contribute to a sound methodological tool for a co-management approach between different offshore maritime sectors.     

Flexural uplift of a lithospheric slab near the Vema transform (Central Atlantic): Timing and mechanisms

The Vema Transverse Ridge (VTR) is a prominent, long and narrow topographic anomaly that runs for over 300 km along a sea floor spreading flow line south of the Vema transform at 11° N in the Atlantic. It rises abruptly about 140 km from the axis of the Mid-Atlantic Ridge (MAR) in 10 Myr old crust and runs continuously up to 25 Myr old crust. It reaches over 3 km above the predicted lithospheric thermal contraction level. It is absent in crust younger than 10 Myr; thus, the uplift of the VTR must have ended roughly 10 Ma. The VTR is interpreted as the exposed edge of a flexured and uplifted slab of oceanic lithosphere that was generated at an 80 km long MAR segment. Based on satellite gravimetry imagery this MAR segment was born roughly 50 Ma and increased its length at an average rate of 1.6 mm/yr. Multibeam data show that the MAR-parallel sea floor fabric south of the VTR shifts its orientation by 5° to 10° clockwise in 11–12 Myr old crust, indicating a change at that time of the orientation of the MAR axis and of the position of the Euler rotation pole. This change caused extension normal to the transform, followed between 12 and 10 Ma by flexure of the edge of the lithospheric slab, uplift of the VTR at a rate of 2 to 4 mm/yr, and exposure of a lithospheric section (Vema Lithospheric Section or VLS) at the northern edge of the slab, parallel to the Vema transform. Ages of pelagic carbonates encrusting ultramafic rocks sampled at the base of the VLS at different distances from the MAR axis suggest that the entire VTR rose vertically as a single block within the active transform offset. A 50 km long portion of the crest of the VTR rose above sea level, subsided, was truncated at sea level and covered by a carbonate platform. Subaerial and submarine erosion has gradually removed material from the top of the VTR and has modified its slopes. Spreading half rate of the crust south of the transform decreased from 17.2 mm/yr between 26 and 19 Ma to 16.9 mm/yr between 19 and 10 Ma, to 13.6 mm/yr from 10 Ma to present. The slowing down of spreading occurred close in time to the change in ridge/transform geometry, suggesting that the two events are related. A numerical model relates lithospheric flexure to extension normal to the transform, suggesting that the extent of the uplift depends on the thickness of the brittle layer, consistent with the observed greater uplift of the older lithosphere along the VTR.     

Snowball morphology and SEM analysis of pedogenic gypsum, southern New Mexico, U.S.A.

Late Quaternary soils in southern New Mexico support previous work that suggested pedogenic gypsum accumulates in successive stages as a function of time, similar to pedogenic carbonate. However, gypsum also occurs as small (0·5–1 mm), powdery spheres that we term snowball morphology. The snowball morphology represents one of the initial stages of pedogenic gypsum development. Scanning electron microscope analyses indicate that soil microorganisms and organic material may play a crucial role in the development of this morphology. However, no trends were found in the crystal habits of gypsum suggesting the snowball morphology forms in a dynamic environment.     

Comment on “Mechanics of tidally driven fractures in Europa's ice shell” by S. Lee, R.T. Pappalardo, and N.C. Makris [2005. Icarus 177, 367-379]

We show Lee, Pappalardo, and Makris' [2005. Icarus 177, 367-379] argument that surface cracks in Europa's icy shell penetrate 3-10 times deeper in the presence of subsurface ocean is not correct. We use numerical calculations to demonstrate that there is at most 50% increase in penetration depth for a crack opening in a shell of finite thickness compared to a half-space. We also propose a simple equation based on force balances to estimate the maximum thickness of an ice shell that can be opened under tensile stress. Our calculations show that a crack can only penetrate 330-m-thick ice shell under 200 kPa far-field tensile stress and half of that if the stress is 100 kPa. But the presence of water would allow crack penetrate ∼4.0 km into the ice shell with zero porosity.     

Stable isotopes and soil-geomorphology as indicators of Holocene climate change, northern Chihuahuan Desert

Coeval δ¹³C shifts recorded in buried soils at both piedmont slope and basin floor sites in the northern Chihuahuan Desert indicate a major shift from C₄grasses to C₃desert-scrub between 7 and 9 ka. The age assignments are based on stratigraphic correlations to charcoal dates and carbon-14 dates of carbonate. This shift is synchronous with a period of cooling in the North Atlantic that may have triggered a period of drought in the south-western United States. Coinciding with this vegetation change, geomorphic evidence in Rio Grande, piedmont, and basin floor eolian environments indicates a major period of erosion. Subsequent gradual enrichment of pedogenic carbonateδ¹³ C values in younger deposits suggests that C₄grasses rebounded in the late Holocene (approximately 4 ka), which is consistent with other evidence of increased moisture regionally. A period of less severe aridity at approximately 2·2 ka is indicated by erosion and subsequent deposition along the alluvial fans and within the basin, and correlates with depleted pedogenic carbonate δ¹³C values suggesting a decrease in C₄grasses. Isotope and packrat midden records should be used together to infer past environmental conditions at different elevations.     

Rapid scale-up of negative emissions technologies: social barriers and social implications

We describe a new approach that allows for systematic causal attribution of weather and climate-related events, in near-real time. The method is designed so as to facilitate its implementation at meteorological centers by relying on data and methods that are routinely available when numerically forecasting the weather. We thus show that causal attribution can be obtained as a by-product of data assimilation procedures run on a daily basis to update numerical weather prediction (NWP) models with new atmospheric observations; hence, the proposed methodology can take advantage of the powerful computational and observational capacity of weather forecasting centers. We explain the theoretical rationale of this approach and sketch the most prominent features of a “data assimilation–based detection and attribution” (DADA) procedure. The proposal is illustrated in the context of the classical three-variable Lorenz model with additional forcing. The paper concludes by raising several theoretical and practical questions that need to be addressed to make the proposal operational within NWP centers.     

Determination of the uranium valence state in the brannerite structure using EELS, XPS, and EDX

In this study, the valence states of uranium in synthetic and natural brannerite samples were studied using a combination of transmission electron microscopy-electron energy loss spectroscopy, scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDX), and X-ray photoelectron spectroscopy (XPS) techniques. We used a set of five (UO₂, CaUO₄, SrCa₂UO₆, UTi₂O₆, and Y_0.5U_0.5Ti₂O₆) U standard samples, including two synthetic brannerites, to calibrate the EELS branching ratio, M₅/(M₄ +M₅), against the number of f electrons. The EELS data were collected at liquid nitrogen temperature in order to minimise the effects of electron beam reduction of U⁶⁺ and U⁵⁺. Test samples consisted of three additional synthetic brannerites (Th_0.7U_0.3Ti₂O₆, Ca_0.2U_0.8Ti₂O₆, and Th_0.55U_0.3Ca_0.15Ti₂O₆) and three natural brannerites from different localities. The natural brannerite samples are all completely amorphous, due to cumulative alpha decay events over geological time periods (24–508 Ma). Our U valence calibration results are in reasonable agreement with previous work, suggesting possibly a non-linear relationship between the branching ratio and the number of f electrons (and hence the average valence state) of U in solids. We found excellent agreement between the nominal valence states of U and the average valence states determined directly by EELS and estimated by EDX analysis (with assumptions regarding stoichiometry) in two of the three synthetic brannerite test samples. The average U oxidation states of the five synthetic brannerite samples, as derived from XPS analyses, are also in good agreement with those determined by other techniques. The average valence states of U in three amorphous (metamict) natural brannerite samples with alpha decay doses ranging from 3.6×10¹⁶ to 6.9×10¹⁷ /mg were found to be 4.4, 4.7, and 4.8, consistent with the presence of U⁵⁺ and/or U⁶⁺ as well as U⁴⁺ in these samples. These results are in general agreement with previous wet chemical analyses of natural brannerite. However, the average valence states inferred by SEM-EDX for two of the natural brannerite samples do not show satisfactory agreement with the EELS determined valence. This may be due to the occurrence of OH^– groups, cation vacancies, anion vacancies, or excess oxygen in the radiation-damaged structure of natural brannerite.     

Verformung von Hornblende-Einkristallen bei Drucken bis 21kb

Zusammenfassung Hornblende-Einkristallzylinder (Fundort: Luckow, Böhmen) verschiedener Orientierung wurden in einer Stempel-Zylinder Hochdruck-Apparatur bei Drucken bis 21 kb und 20° C verformt. Die Versuche haben gezeigt, daß an Hornblenden durch Anwendung von Drucken >10 kb kristallographisch indizierbare Deformationsstrukturen erzeugt werden können. Bei Druck [001] und [h0l] beobachtet man mechanische, polysynthetische Zwillingsbildung nach (¯101) (Aufstellung (C2/m). Ab ca. 20 kb bilden sich daneben Scherbrüche nach {141}. Druck [010] bewirkt ab ca. 15 kb eine {120}-Spaltbarkeit, die jedoch hinter der nach {110} stark zurückbleibt.

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Deformation of hornblende single crystals at pressures up to 21 kbs

Cylinders drilled from hornblende single crystals were deformed at 20° C in a pistoncylinder high-pressure apparatus in the following orientations: [001], [h0l], normal to (110), normal to (100) and [010]. Pyrophyllite was used for transmitting the confining pressure. Experiments with cylinder axis [001] and [h0l] revealed lamellar twinning on (¯101) at pressures above l0 kbs. The twinning elements are: K ₁=(¯101), ₁ = [¯10¯1], K ₂=(100), ₂=[001], s=0.56 (space group setting C2/m). At pressures around 20 kbs, {141}-shear fracture was observed. This means that the SiO₄-ribbons parallel to [001] are broken. Crystals compressed parallel to [010] show {120} cleavage at pressures above 15 kbs.

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Der überwiegende Teil der experimentellen Arbeit wurde im Mineralogischen Institut der Technischen Hochschule Darmstadt durchgeführt. Der Deutschen Forschungsgemeinschaft sei für materielle Hilfe gedankt.