In search of water vapor on Jupiter: Laboratory measurements of the microwave properties of water vapor under simulated jovian conditions

Detection and measurement of atmospheric water vapor in the deep jovian atmosphere using microwave radiometry has been discussed extensively by Janssen et al. (Janssen, M.A., Hofstadter, M.D., Gulkis, S., Ingersoll, A.P., Allison, M., Bolton, S.J., Levin, S.M., Kamp, L.W. [2005]. Icarus 173 (2), 447-453.) and de Pater et al. (de Pater, I., Deboer, D., Marley, M., Freedman, R., Young, R. [2005]. Icarus 173 (2), 425-447). The NASA Juno mission will include a six-channel microwave radiometer system (MWR) operating in the 1.3-50 cm wavelength range in order to retrieve water vapor abundances from the microwave signature of Jupiter (see, e.g., Matousek, S. [2005]. The Juno new frontiers mission. Tech. Rep. IAC-05-A3.2.A.04, California Institute of Technology). In order to accurately interpret data from such observations, nearly 2000 laboratory measurements of the microwave opacity of H₂O vapor in a H₂/He atmosphere have been conducted in the 5-21 cm wavelength range (1.4-6 GHz) at pressures from 30 mbars to 101 bars and at temperatures from 330 to 525 K. The mole fraction of H₂O (at maximum pressure) ranged from 0.19% to 3.6% with some additional measurements of pure H₂O. These results have enabled development of the first model for the opacity of gaseous H₂O in a H₂/He atmosphere under jovian conditions developed from actual laboratory data. The new model is based on a terrestrial model of Rosenkranz et al. (Rosenkranz, P.W. [1998]. Radio Science 33, 919-928), with substantial modifications to reflect the effects of jovian conditions. The new model for water vapor opacity dramatically outperforms previous models and will provide reliable results for temperatures from 300 to 525 K, at pressures up to 100 bars and at frequencies up to 6 GHz. These results will significantly reduce the uncertainties in the retrieval of jovian atmospheric water vapor abundances from the microwave radiometric measurements from the upcoming NASA Juno mission, as well as provide a clearer understanding of the role deep atmospheric water vapor may play in the decimeter-wavelength spectrum of Saturn.     

The effects of humic substances on the transport of radionuclides: Recent improvements in the prediction of behaviour and the understanding of mechanisms

Some recent developments made during the European Union 6th Framework Integrated Project FUNMIG in the understanding and prediction of behaviour in ternary systems of radionuclides, humic substances and mineral surfaces are described. These developments are placed in the context of the existing literature. The aim is to describe the current understanding of humic substance mediated radionuclide transport as it may be applied to calculations in support of Radiological Performance Assessment. Some improvements in experimental techniques that provide the raw data to calibrate metal ion binding models are explained. The various metal ion binding models that are available are described and contrasted, before the recent development of ternary system models, in particular the Ligand Charge Distribution model that can predict metal ion and humic substance behaviour in ternary systems. The kinetic effects in ternary systems are described along with the models that are used to describe them. Finally, the remaining challenges in making predictions of radionuclide transport for the Radiological Performance Assessment of radioactive waste repositories are discussed.     

The Cainozoic geology of the Middle Shoalhaven Plain

The Middle Shoalhaven Plain is a large, tray‐like depression bounded in the west by the Mulwaree fault and in the east by cliffed Permian sediments. The plain is probably Mesozoic in origin and was partially alluviated during the Early to mid‐Eocene. Much of the plain and sediments were covered by basalts during the Late Eocene. This was followed by an episode of deep weathering, which culminated in the formation of widespread bauxitic and lateritic crusts and manganocrete and silcrete during the mid‐Tertiary. A second minor weathering event is recorded during the latest Tertiary to Early Pleistocene. Two new basalt dates are consistent with earlier ones at about 43 Ma. Palaeomagnetism shows bauxites and ferricretes to be mid‐Tertiary.     

Geochronology and geochemistry of the Devonian Gumbardo Formation (Adavale Basin): evidence for cratonisation of the Central Thomson Orogen by the Early Devonian

Abstract

The Devonian subsurface Adavale Basin occupies a central position in the Paleozoic central Thomson Orogen of eastern Australia and records its tectonic setting during this time interval. Here, we have focussed on the basal volcanics of the Gumbardo Formation to clarify the tectonic setting of the basin. The approach has been to undertake stratigraphic logging, LA-ICP-MS U–Pb zircon geochronology and whole-rock geochemical analysis. The data indicate that basin initiation was rapid occurring at ca 401?Ma. The volcanic rocks are dominated by K-feldspar phyric rhyodacitic ignimbrites. The whole-rock geochemical data indicate little evidence for extensive fractional crystallisation, with the volcanic suite resembling the composition of the upper continental crust and exhibiting transitional I- to A-type tectonomagmatic affinities. One new U–Pb zircon age revealed an Early Ordovician emplacement age for a volcanic rock previously interpreted to be part of the Early Devonian Gumbardo Formation, and older basement age is consistent with seismic interpretations of uplifted basement in this region of the western Adavale Basin. Five ignimbrites dated from different stratigraphic levels within the formation yield similar emplacement ages with a pooled weighted age of 398.2?±?1.9?Ma (mean square weighted deviation?=?0.94, n?=?93). Significant zircon inheritance in the volcanic rocks records reworking of Ordovician and Silurian silicic igneous basement from the Thomson Orogen and provides insight into the crustal make-up of the Thomson Orogen. Collectively, the new data presented here suggest the Adavale Basin is a cover-type basin that developed on a stabilised Thomson Orogen after the major Bindian deformation event in the late Silurian.     

Seasonal temperature responses to land-use change in the western United States

In the western United States, more than 79 000 km² has been converted to irrigated agriculture and urban areas. These changes have the potential to alter surface temperature by modifying the energy budget at the land–atmosphere interface. This study reports the seasonally varying temperature responses of four regional climate models (RCMs) – RSM, RegCM3, MM5-CLM3, and DRCM – to conversion of potential natural vegetation to modern land-cover and land-use over a 1-year period. Three of the RCMs supplemented soil moisture, producing large decreases in the August mean (− 1.4 to − 3.1 °C) and maximum (− 2.9 to − 6.1 °C) 2-m air temperatures where natural vegetation was converted to irrigated agriculture. Conversion to irrigated agriculture also resulted in large increases in relative humidity (9% to 36% absolute change). Modeled changes in the August minimum 2-m air temperature were not as pronounced or consistent across the models. Converting natural vegetation to urban land-cover produced less pronounced temperature effects in all models, with the magnitude of the effect dependent upon the preexisting vegetation type and urban parameterizations. Overall, the RCM results indicate that the temperature impacts of land-use change are most pronounced during the summer months, when surface heating is strongest and differences in surface soil moisture between irrigated land and natural vegetation are largest.     

Thermal marking of rainbow trout (Oncorhynchus mykiss) otoliths

A small‐scale experiment was done to test the feasibility of thermally marking hatchery‐reared rainbow trout (Oncorhynchus mykiss Walbaum) fry that are released into rivers and impoundments in New South Wales (NSW), Australia. Fry of rainbow trout were exposed to two different 48‐h thermal cycles each of a cold and warm water period. One thermal regime consisted of a cold water period during which the temperature was reduced from 14 to 8°C for 18 h followed by a return to 14°C for 30 h. For the second thermal treatment, water temperature was reduced to 4°C for 10 h followed by a period of 38 h at 14°C. Thermal cycles were repeated 4 and 8 times for each thermal regime, respectively. Following a growth period after treatment, obvious marks were visible on all treated otoliths as distinct from control otoliths. The 10°C differential treatment created the most visible patterns and growth of these fish was not significantly different from control fish. This marking method could be applied to normal hatchery practices to evaluate the effectiveness of large‐scale rainbow trout stockings in NSW.     

Katabatic flow induced by a cross-slope band of surface cooling

This paper investigates the behavior of katabatic flow induced by an idealized, thermally inhomogeneous surface; a strip of surface cooling that has a finite width in the along-slope direction and is infinitely long in the cross-slope direction. Numerical simulations using the Boussinesq equations of motion and the thermodynamic energy equation are performed for various slope angles and strip lengths. The underlying dynamical processes in the katabatic jet and the near environment are explored by considering the along-slope momentum balance after a steady state has been achieved. The inhomogeneous nature of the surface forcing also induces a response in the environment that extends very far away from the sloped surface. Nearly horizontal jets close to the vertical heights of both sides of the cold strip are observed in the environment. A horizontal vorticity analysis is performed on these horizontal jets to ascertain their dynamical structure.     

Flow energy and channel adjustments in rills developed in loamy sand and sandy loam soils

The storms usually associated with rill development in nature are seldom prolonged, so development is often interrupted by interstorm disturbances, e.g. weathering or tillage. In laboratory simulated rainfall experiments, active rill development can be prolonged, and under these conditions typically passes through a period of intense incision, channel extension and bifurcation before reaching quasi‐stable conditions in which little form change occurs. This paper presents laboratory experiments with coarse textured soils under simulated rainfall which show how channel adjustment processes contribute to the evolution of quasi‐stability. Newly incised rills were stabilized for detailed study of links between rill configuration and flow energy. On a loamy sand, adjustment towards equilibrium occurred due to channel widening and meandering, whereas on a sandy loam, mobile knickpoints and chutes, pulsations in flow width and flow depth and changes in stream power and sediment discharge occurred as the channel adjusted towards equilibrium. The tendency of rill systems towards quasi‐stability is shown by changes in stream power values which show short‐lived minima. Differences in energy dissipation in stabilized rills indicate that minimization of energy dissipation was reached locally between knickpoints and at the downstream ends of rills. In the absence of energy gradients in knickpoints and chutes, stabilized rill sections tended toward equilibrium by establishing uniform energy expenditure. The study confirmed that energy dissipation increased with flow aspect ratio. In stabilized rills, flow acceleration reduced energy dissipation on the loamy sand but not on the sandy loam. On both soils flow deceleration tended to increase energy dissipation. Understanding how rill systems evolve towards stability is essential in order to predict how interruptions between storms may affect long‐term rill dynamics. This is essential if event‐based physical models are to become effective in predicting sediment transport on rilled hillslopes under changing weather and climatic conditions. Copyright © 2008 John Wiley and Sons, Ltd.