Chronostratigraphy and paleoclimatic meaning of cryogenic deformations in the Central European loess

Cryoturbations in loess reflect cold and wet environments but not necessarily permafrost. Only flat bottomed cryoturbations are indicative of it. Outside the permafrost zone they occur during the wet period of the last glaciation: during the early Weichselian, the lower pleniglacial, the end of the middle pleniglacial and the late glacial. Their morphology ist related to the frost susceptibility of the superimposed layers, expressed in form of differential frost heaving, ruled by the drainage quality and the frost susceptibility gradient. Their diagenesis is discussed.     

TEM investigation of the crystal microstructures in a quartz-coesite assemblage of the western alps

Atransmission electron microscope (TEM) study of quartz-coesite inclusions in garnet in crustal rocks from the Western Alps is presented. Coesite shows a low dislocation density (<10⁷ cm^?2), and quartz a higher density of defects, Brasil twins (10⁴ cm^?1) and dislocations (10⁸ cm^?2). It is concluded that coesite has been not or only slightly plastically deformed and that the yield strength of coesite is higher than that of quartz. The large scale deformation implications are briefly discussed. TEM observations show no systematic topotactic relationship between the two polymorphs and their boundaries have a scalloped morphology which suggests that growth of quartz from coesite was controlled by a diffusion process.     

Raman spectroscopic studies of carbonates part I: High-pressure and high-temperature behaviour of calcite,magnesite, dolomite and aragonite

The room-temperature Raman spectra of aragonite, magnesite and dolomite have been recorded up to 30 GPa and 25 GPa, respectively and no phase changes were observed during compression, unlike calcite. The effect of temperature on the room-pressure Raman spectra of calcite, aragonite, magnesite and dolomite is reported up to 800–1100 K. The measured relative pressure and temperature-shifts of the Raman lines are greater for the lattice modes than for the internal modes of the CO₃ groups. These shifts are used to calculate the mode anharmonic parameters of the observed Raman modes; they are negative and their absolute values are smaller (close to 0) for the internal CO₃ modes than for the lattice modes (4–17 10^?5 K^?1). The temperature shifts of the lattice modes in calcite are considerably larger than those for dolomite and magnesite, and a marked non-linear increase in linewidth is observed above 400° C for calcite. This is consistent with an increasing relaxational component to the libration of the CO₃ groups about their threefold axes, premonitory to the rotational order-disorder transition at higher temperature. This behaviour is not observed for the other calcite structured minerals in this study. We examine systematic variations in the lattice mode frequencies and linewidths with composition, to begin to understand these differences in their anharmonic behaviour. Finally, we have used a simple Debye-Waller model to calculate atomic displacements in calcite, magnesite and dolomite with increasing temperature from the vibrational frequency data, to provide a direct comparison with atomic positional data from high-temperature structure refinements.     

A theoretical approach to the kinetics of calcite ⇌ aragonite transition: application to laboratory experiments

A theoretical approach to the calcite ? aragonite transformation is presented for the case of a dislocation glide mechanism obeying first-order kinetics. The kinetic parameters are determined from recent experimental data from the literature; the sensitivity of the model to these and other parameters like the grain size and the deviatoric stresses are discussed.The model results in the definition of what could be the actual transformation domains of the CaCO₃ polymorphs in the (P,T) plane. These domains are different from the classical ones, i.e. different from the stability fields defined with respect to Clapeyron's curve; they can evolve in the (P,T) plane when a deviatoric stress is applied to the system. In this case, we can define a domain in which the two senses of the calcite ? aragonite transition are activated simultaneously.The application of the model to laboratory experiments needs the integration of the kinetic differential equation (K varying withP andT). Using this method, we demonstrate the role of (P,T,t) path on reaction rate and the role of experimental uncertainties on the reaction parametersK andn.Finally, we discuss the problem of the synthesis of polymorphs out of their stability field and of their formation by grinding; these problems, difficult to tackle in terms of diffusion, can be approached with the proposed dislocation transformation kinetic model.     

Structures caused by repeated freezing and thawing in various loamy sediments: A comparison of active,fossil and experimental data

In this paper, the authors present the results of both macroscopic and microscopic investigations on structure development created by repeated ice lensing in various loamy experiments. Experimental data are compared with observations performed on active forms in High Arctic and Alpine Mountain environments. Those observations are also compared with phenomena observed in fossil periglacial formations of Western Europe. Platy and short prismatic structure formation is bonded to the hydraulic and thermal conditions during ice segregation. When a long series of alternating freezing and thawing affects platy structures, the fabric evolves, also being influenced by slope and drainage conditions: cryoturbations, frostcreep, and gelifluction can appear. They are characterized by specific microfabrics which are better developed with an increasing number of cycles: this is clear in experiments where hydraulic and thermal parameters are better controlled. Vesicles are also a prominent characteristic of the surface horizon in experiments and arctic soils. The genesis of vesicles is discussed on the basis of new observations and is related to the mechanical collapse of frost-created aggregates under the mechanical work of soil air escape during soil saturation by water at thaw.     

Origin of EL3 chondrites: Evidence for variable C/O ratios during their course of formation—A state of the art scrutiny

Mineral inventories of enstatite chondrites; (EH and EL) are strictly dictated by combined parameters mainly very low dual oxygen (fO₂) and sulfur (fS₂) fugacities. They are best preserved in the Almahata Sitta MS‐17, MS‐177 fragments, and the ALHA 77295 and MAC 88136 Antarctic meteorites. These conditions induce a stark change of the geochemical behavior of nominally lithophile elements to chalcophile or even siderophile and changes in the elemental partitioning thus leading to formation of unusual mineral assemblages with high abundance of exotic sulfide species and enrichment in the metallic alloys, for example, silicides and phosphides. Origin and mode of formation of these exotic chondrites, and their parental source regions could be best scrutinized by multitask research experiments of the most primitive members covering mineralogical, petrological, cosmochemical, and indispensably short‐lived isotopic chronology. The magnitude of temperature and pressure prevailed during their formation in their source regions could eventually be reasonably estimated: pre‐ and postaccretionary could eventually be deduced. The dual low fugacities are regulated by the carbon to oxygen ratios estimated to be >0.83 and <1.03. These parameters not only induce unusual geochemical behavior of the elements inverting many nominally lithophile elements to chalcophile or even siderophile or anthracophile. Structure and mineral inventories in EL3 and EH3 chondrites are fundamentally different. Yet EH3 and EL3 members store crucial information relevant to eventual source regions and importantly possible variation in C/O ratio in the course of their evolution. EL3 and EH3 chondrites contain trichotomous lithologies (1) chondrules and their fragments, (2) polygonal enstatite‐dominated objects, and (3) multiphase metal‐rich nodules. Mineralogical and cosmochemical inventories of lithologies in the same EL3 indicate not only similarities (REE inventory and anomalies in oldhamite) but also distinct differences (sinoite‐enstatite‐graphite relationship). Oldhamite in chondrules and polygonal fragments in EL3 depict negative Eu anomaly attesting a common cosmochemical source. Metal‐dominated nodules in both EL3 and EH3 are conglomerates of metal clasts and sulfide fragments in EH3 and concentrically zoned C‐bearing metal micropebbles (≥25 μm ≤50 μm) in EL3 thus manifesting a frozen in unique primordial accretionary metal texture and composition. Sinoite‐enstatite‐diopside‐graphite textures reveal a nucleation and growth strongly suggestive of fluctuating C/O ratio during their nucleation and growth in the source regions. Mineral inventories, sulfide phase relations, sinoite‐enstatite‐graphite intergrowth, carbon and nitrogen isotopic compositions of graphite, spatial nitrogen abundance in graphite in metal nodules, and last but not least ¹²⁹I/¹²⁹Xe and ⁵³Mn/⁵³Cr systematics negate any previously suggested melting episode, pre‐accretionary or dynamic, in parental asteroids.     

On the significance of aragonite occurrences in the Western Alps

Aragonite occurrences from two areas of the Western Alps are described. It is shown that aragonite has been formed under blueschist metamorphic conditions in the Western Vanoise, while it has been precipitated under sub-surface conditions in the Queyras region. An uplift (P, T) path of the aragonite-bearing rocks of the Western Vanoise is constructed using two independent methods: (1) temperature estimates using the Sr⁺⁺ content of aragonite in the successive veins and (2) the kinetics of the aragonitecalcite solid-state transition. The uplift (P, T) path has an unusual shape with an important temperature decrease (100° to 150° C for a pressure decrease of 0.2 GPa) following blueschists metamorphism (P=0.7 GPa, T=300° C). Thermal models show that this unusual (P, T) path of the Western Vanoise can be explained if one maintains a low temperature (between 125° and 175° C) at the base of the tectonic unit containing the aragonite-bearing rocks during part of its burial history, followed by the whole of its exhumation. A tectonic scenario is proposed to account for the observed and modelled (P, T) path.     

Correlation of Plio-Pleistocene deposits of the Lower Rhine Basin (North-West Germany) and the Valle Ricca pits (Central Italy)

Biostratigraphic and palaeomagnetic research has been carried out on selected profiles in North-Western Germany and Central Italy in order to correlate Plio-Pleistocene sections.Around the Réunion subchronozone, vegetation in the Valle Ricca was dominated by a mountain forest type pointing to cool climatic conditions. In the Lower Rhine Basin vegetation had a slightly warmer character, but was also dominated strongly by a mountain type of forest vegetation, characteristic of cooler summers and higher precipitation than at present.Two warmer periods have been determined in the Central Italian profiles; the youngest around the Olduvai reversal, should correspond to the youngest Tiglian beds of the Lower Rhine Basin.Deposits older than the Réunion subzone have not been found in the Valle Ricca. In the Lower Rhine Basin, on the other hand, the Gauss-Matuyama boundary is located between the uppermost Pliocene, the Reuverian C and the Praetiglian.     

The pelagic community of a gravel pit lake: Significance of Coleps hirtus viridis (Prostomatida) and its role as a scavenger

Coleps hirtus viridis was the dominant species of the planktonic ciliate community of Lake Fühlinger See (Germany) during the study in 1999 and 2000. Total ciliate densities ranged from 120 to 42,000 ind. l⁻¹ in 1999 and up to 8,000 ind. l⁻¹ in 2000. Coleps contributed up to 98% to both total ciliate abundance and biomass and made up an average of 64% of the total ciliate biomass. Oligotrichs (Rimostrombidium, Strobilidium) dominated the epilimnetic zone, whereas peritrich ciliates (Pelagovorticella, Vorticella) were predominantly located in the hypolimnion. The population maximum of Coleps changed locations from the epilimnion in early summer to the hypolimnion (up to 40,000 ind. l⁻¹) during stratification. High growth rates in the hypolimnion, presence of endosymbiontic algae and the ability to ingest detritus seem to be important for the success.Growth rates of Coleps in June were determined by Landry-Hassett dilution experiments in both the epilimnion and the hypolimnion. The instantaneous growth rates were similar in both layers (0.6 d⁻¹), but a distinctly higher instantaneous mortality was estimated for the epilimnion. These high loss rates may be due to grazing pressure by cladocerans.The significance of the histophagous feeding of Coleps was evaluated through an experiment using killed zooplankton. Parts of Daphnia magna were incorporated at rates of about 1,100 μm³ ind.⁻¹ h⁻¹ by Coleps without endosymbiotic algae and at rates of 500 μm³ ind.⁻¹ h⁻¹ by Coleps with endosymbionts. These high feeding rates support the conclusion that Coleps can use dead organic matter as an additional food source.