Fine-scale volume heterogeneity measurements in sand

As part of the effort to characterize the acoustic environment during the high frequency sediment acoustics experiment (SAX99), fine-scale variability of sediment density was measured by an in situ technique and by core analysis. The in situ measurement was accomplished by a newly developed instrument that measures sediment conductivity. The conductivity measurements were conducted on a three-dimensional (3-D) grid, hence providing a set of data suited for assessing sediment spatial variability. A 3-D sediment porosity matrix is obtained from the conductivity data through an empirical relationship (Archie's Law). From the porosity matrix, sediment bulk density is estimated from known average grain density. A number of cores were taken at the SAX99 site, and density variations were measured using laboratory techniques. The power spectra were estimated from both techniques and were found to be appropriately fit by a power-law. The exponents of the horizontal one-dimensional (1-D) power-law spectra have a depth-dependence and range from 1.72 to 2.41. The vertical 1-D spectra have the same form, but with an exponent of 2.2. It was found that most of the density variability is within the top 5 mm of the sediment, which suggests that sediment volume variability will not have major impact on acoustic scattering when the sound frequency is below 100 kHz. At higher frequencies, however, sediment volume variability is likely to play an important role in sound scattering.     

High-pressure metamorphism of stratiform sulphide deposits from the Diahot region,New Caledonia

Stratiform Cu-Pb-Zn (-Au-Ag) mineralization associated with black carbonaceous schists and acid metatuffs is restricted to distinct horizons within the Cretaceous sequence of the Diahot region. The sulphides occur in sharply bounded lenses which show varying degrees of compositional banding conformable with the foliation of the country schists. The deposits are sedimentary-exhalative of the Rio Tinto-type and have been modified by mid-Tertiary high-pressure metamorphism (lawsonite-albite and glaucophanitic greenschist facies). The ores are not strongly deformed by the metamorphism and sedimentary structures, pyrite framboids and atoll structures are preserved in some deposits. With increasing metamorphic grade sphalerite becomes more iron-rich, pyrrhotite becomes more abundant, and the sulphides show a general increase in grain-size which parallels that of the silicates in the enclosing rocks. In the more highly metamorphosed deposits the sulphide associations are retrograde assemblages. There is no evidence of large-scale metamorphic remobilization of sulphides. No differences were observed in either the sulphide assemblages or in the composition of the sulphides to indicate that the metamorphism was of the high pressure rather than the low pressure type.     

Characterization of interface roughness of rippled sand off Fort Walton Beach, Florida

As part of the environmental characterization to model acoustic bottom scattering during the high-frequency sediment acoustics experiment (SAX99), fine-scale sediment roughness of a medium sand was successfully measured within a 600 /spl times/ 600-m area by two methods: stereo photography and a technique using a conductivity system. Areal coverage of the two methods, representing approximately 0.16 m/sup 2/ of the sea floor, was comparable, resulting in the depiction and quantification of half-meter wavelength sand ripples. Photogrammetric results were restricted to profiles digitized at 1-mm intervals; sediment conductivity results generated gridded micro-bathymetric measurements with 1- to 2-cm node spacing. Roughness power spectra give similar results in the low-spatial-frequency domains where the spectra estimated from both approaches overlap. However, spectra derived from higher resolution photogrammetric results appear to exhibit a multiple-power-law fit. Roughness measurements also indicate that spectrum changes as a function of time. Application of statistical confidence bounds on the power spectra indicates that roughness measurements separated by only 1-2 m may be spatially nonstationary.     

The BATSE search for absorption lines

No absorption lines between 15 and 100 keV have been detected in burst spectra accumulated by BATSE. Almost 250 bursts have been inspected visually, and a computerized search has begun. Our simulations show that BATSE could indeed detect lines similar to those observed byGinga in strong bursts, and our tests of the detectors' actual capabilities demonstrate they function as understood. The apparent discrepancy between BATSE andGinga is not yet compelling, and therefore the BATSE nondetections do not invalidate theGinga detections. Nonetheless, the absence of BATSE line detections indicates a low line-occurrence frequency.     

THE IMPACT OF FEDERAL LOCAL PUBLIC TRANSPORTATION ASSISTANCE UPON TRAVEL BEHAVIOR

Despite substantial amounts of federal assistance to local public transportation, ridership has declined considerably in the country as a whole since 1964, suggesting an ineffective government program. A city-by-city comparison of assistance received with changes in transit ridership shows that declines in transit usage were least in cities receiving the most federal aid, and greatest in cities receiving the least aid. This demonstrates that federal aid has had an impact upon travel behavior. Indeed, it is the single most important factor explaining differences between cities in travel behavior changes in the 1970's.     

A new class of steady solutions of the barotropic vorticity equation

Early studies of the wind-driven ocean problem were concerned with finding steady solutions of the equations of motion, first by analytic, and later by numerical methods. The problem is characterized by an Ekman number (?) and a Rossby number (α). Prior to this study, steady solutions were confined to the ranges α, ? < < 1.In this work the problem is considered in a circular domain with lateral friction and a partial-slip boundary condition. Steady solutions are found analytically in the new regime α > 1. Furthermore, for large enough values of ?, steady solutions are determined numerically in the intermediate range between this high-α regime and the classical low-α regime. That is, for some values of ?, steady solutions can be found through all values of α. Numerical evidence suggests that below a critical value of ?, steady solutions in this intermediate range exist, but cease to be stable. Similar results have been obtained with bottom friction and with different boundary conditions.     

Rapid incorporation of lipids into macromolecules during experimental decay of invertebrates: Initiation of geopolymer formation

Diagenetic alteration is critical for the preservation of fossil cuticles of plant and animal origin and to the formation of kerogen. The process takes place over millions of years, but the stage at which it is initiated is not known. Laboratory decay experiments were carried out on shrimps, scorpions and cockroaches to monitor changes in the chitin–protein of the arthropod cuticle and associated lipids. The cockroach and scorpion exoskeleton remained largely unaltered morphologically, but the shrimp experienced rapid decomposition within a month, which progressed through the 44 week duration of the experiment as revealed using electron microscopy. Mass spectrometry and ¹³C NMR (nuclear magnetic resonance) spectroscopy revealed the association of an n-alkyl component with labile lipids, such as fatty acids with up to 24 carbon atoms, which were incorporated into the decaying macromolecule. The scorpion and cockroach cuticle did not reveal the incorporation of additional lipids, indicating that decay is important in initiating in situ lipid association. This experiment provides evidence that lipids can become associated with carbohydrate and proteinaceous macromolecules during the very early stages of decay, representing the first stage in the transformation process that contributes to the aliphatic rich composition ubiquitous in organic fossils and kerogen.     

Titan's atmospheric chemistry: Photolysis of gas mixtures containing hydrogen cyanide and carbon monoxide at 185 and 254 nm

The formation of organic compounds in the atmosphere of Titan is an ongoing process of the generation of complex organics from the simplest hydrocarbon, methane. Solar radiation and magnetosphere electrons are the main energy sources that drive the reactions in Titan's atmosphere. Since energy from solar radiation is 200 times greater than that from magnetosphere electrons, we have investigated the products formed by the action of UV radiation (185 and 254 nm) on a mixture of gases containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene, the basic gas mixture (BGM) that simulates aspects of Titan's atmosphere using a flow reactor [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. Icarus 162, 114-124; Tran, B.N., Joseph, J.C., Force, M., Briggs, R.G., Vuitton, V., Ferris, J.P., 2005. Icarus 177, 106-115]. The present research extends these studies by the addition of carbon monoxide and hydrogen cyanide to the BGM. Quantum yields for the loss of reactants and the formation of volatile products were determined and compared with those measured in the absence of the hydrogen cyanide and carbon monoxide. The GCMS analyses of the volatile photolysis products from the BGM, with added hydrogen cyanide, had a composition similar to that of the BGM while the photolysis products of the BGM with added carbon monoxide contained many oxygenated compounds. The infrared spectrum of the corresponding solid product revealed the absorption band of a ketone group, which was probably formed from the reaction of carbon monoxide with the free radicals generated by photolysis of acetylene and ethylene. Of particular interest was the observation that the addition of HCN to the gas mixture only resulted in a very small change in the C/N ratio and in the intensity of the CN frequency at 2210 cm⁻¹ in the infrared spectrum suggesting that little HCN is incorporated into the haze analog. The C/N ratio of the haze analogs was found to be in the 10-12 range. The UV spectra of the solid products formed when HCN or CO added to the BGM is similar to the UV absorption formed from the BGM alone. This result is consistent with absence of additional UV chromophores to the solid product when these mixtures are photolyzed. The following photoproducts, which were not starting materials in our photochemical studies, have been observed on Titan: acetonitrile, benzene, diacetylene, ethane, propene, propane, and propyne.     

Using Diurnal Temperature Signals to Infer Vertical Groundwater‐Surface Water Exchange

Heat is a powerful tracer to quantify fluid exchange between surface water and groundwater. Temperature time series can be used to estimate pore water fluid flux, and techniques can be employed to extend these estimates to produce detailed plan‐view flux maps. Key advantages of heat tracing include cost‐effective sensors and ease of data collection and interpretation, without the need for expensive and time‐consuming laboratory analyses or induced tracers. While the collection of temperature data in saturated sediments is relatively straightforward, several factors influence the reliability of flux estimates that are based on time series analysis (diurnal signals) of recorded temperatures. Sensor resolution and deployment are particularly important in obtaining robust flux estimates in upwelling conditions. Also, processing temperature time series data involves a sequence of complex steps, including filtering temperature signals, selection of appropriate thermal parameters, and selection of the optimal analytical solution for modeling. This review provides a synthesis of heat tracing using diurnal temperature oscillations, including details on optimal sensor selection and deployment, data processing, model parameterization, and an overview of computing tools available. Recent advances in diurnal temperature methods also provide the opportunity to determine local saturated thermal diffusivity, which can improve the accuracy of fluid flux modeling and sensor spacing, which is related to streambed scour and deposition. These parameters can also be used to determine the reliability of flux estimates from the use of heat as a tracer.