Shoreline features of Titan's Ontario Lacus from Cassini/VIMS observations

We analyze observations of Titan's south polar lake Ontario Lacus obtained by Cassini's Visual and Infrared Mapping Spectrometer during the 38th flyby of Titan (T38; 2007 December 5). These near-closest-approach observations have the highest signal-to-noise, the finest spatial resolution, and the least atmospheric influence of any near-infrared lake observation to date. We use the large, spatially flat, and low-albedo interior of Ontario Lacus as a calibration target allowing us to derive an analytical atmospheric correction for emission angle. The dark lake interior is surrounded by two separate annuli that follow the lake interior's contours. The inner annulus is uniformly dark, but not so much as the interior lake, and is generally 5-10 kilometers wide at the lake's southeastern margin. We propose that it represents wet lakebed sediments exposed by either tidal sloshing of the lake or seasonal methane loss leading to lower lake-volume. The exterior annulus is bright and shows a spectrum consistent with a relatively low water-ice content relative to the rest of Titan. It may represent fine-grained condensate deposits from a past era of higher lake level. Together, the annuli seem to indicate that the lake level for Ontario Lacus has changed over time. This hypothesis can be tested with observations scheduled for future Titan flybys.     

Orbital properties of Jupiter-family comets

The history of “comet families”, in particular the Jupiter comet family, is reviewed, together with ways in which the Jupiter family has been defined. New criteria are proposed, particularly with regard to distinguishing Jupiter-family comets (JFCs) from centaurs. The effect of nongravitational forces on JFCs is also discussed.     

The 2dF-SDSS LRG and QSO Survey: the spectroscopic QSO catalogue

We present the final spectroscopic QSO catalogue from the 2dF-SDSS LRG (luminous red galaxy) and QSO (2SLAQ) survey. This is a deep,  18 < g < 21.85  (extinction corrected), sample aimed at probing in detail the faint end of the broad line active galactic nuclei luminosity distribution at   z ≲ 2.6  . The candidate QSOs were selected from SDSS photometry and observed spectroscopically with the 2dF spectrograph on the Anglo-Australian Telescope. This sample covers an area of 191.9 deg² and contains new spectra of 16 326 objects, of which 8764 are QSOs and 7623 are newly discovered [the remainder were previously identified by the 2dF QSO Redshift Survey (2QZ) and SDSS]. The full QSO sample (including objects previously observed in the SDSS and 2QZ surveys) contains 12 702 QSOs. The new 2SLAQ spectroscopic data set also contains 2343 Galactic stars, including 362 white dwarfs, and 2924 narrow emission-line galaxies with a median redshift of   z = 0.22  .
We present detailed completeness estimates for the survey, based on modelling of QSO colours, including host-galaxy contributions. This calculation shows that at   g ≃ 21.85  QSO colours are significantly affected by the presence of a host galaxy up to redshift   z ∼ 1  in the SDSS ugriz bands. In particular, we see a significant reddening of the objects in   g − i   towards the fainter g -band magnitudes. This reddening is consistent with the QSO host galaxies being dominated by a stellar population of age at least 2–3 Gyr.
The full catalogue, including completeness estimates, is available on-line at http://www.2slaq.info/ .     

The eclipsing intermediate polar V597 Pup (Nova Puppis 2007)

JL 82 is a known binary, consisting of an sdB star and a companion which is not directly observable in the optical. Photometric measurements reported in this paper show it to variable with both the binary period (∼0.75 d), as well as on much shorter time-scales. The shorter periods are ascribed to pulsation of the sdB star, making it a member of the PG 1716 class of pulsating stars.     

Application of 4D-Variational data assimilation to the California Current System

The Incremental Strong constraint 4D-Variational (IS4DVAR) data assimilation system of the Regional Ocean Model System (ROMS) is used to study the controllability of a realistic, high resolution configuration of the California Current System. The configuration and results of assimilating both satellite-derived surface observations along with in situ data are presented. Results show consequent improvements in many characteristics of the model circulation, and some of the strengths of the adjoint method for data assimilation are highlighted. General issues of the sensitivity of the results to the configuration of ROMS-IS4DVAR are also discussed.     

Automated cleaning and uncertainty attribution of archival bathymetry based on a priori knowledge

Hydrographic offices hold large valuable historic bathymetric data sets, many of which were collected using older generation survey systems that contain little or no metadata and/or uncertainty estimates. These bathymetric data sets generally contain large outlier (errant) data points to clean, yet standard practice does not include rigorous automated procedures for systematic cleaning of these historical data sets and their subsequent conversion into reusable data formats. In this paper, we propose an automated method for this task. We utilize statistically diverse threshold tests, including a robust least trimmed squared method, to clean the data. We use LOESS weighted regression residuals together with a Student-t distribution to attribute uncertainty for each retained sounding; the resulting uncertainty values compare favorably with native estimates of uncertainty from co-located data sets which we use to estimate a point-wise goodness-of-fit measure. Storing a cleansed validated data set augmented with uncertainty in a re-usable format provides the details of this analysis for subsequent users. Our test results indicate that the method significantly improves the quality of the data set while concurrently providing confidence interval estimates and point-wise goodness-of-fit estimates as referenced to current hydrographic practices.     

Suffocation of pilchards (Sardinops sagax) by a green microalgal bloom in Wellington Harbour,New Zealand

A bloom of the green microalga Tetraselmis sp. in a small lagoon in Wellington Harbour, New Zealand, is considered to have caused a fish kill of pilchards (Sardinops sagax). The fish deaths are attributed to anoxia brought about by a combination of reduced dissolved oxygen levels and the microalgae sticking to and clogging the secondary gill lamellae of the fish.     

Mechanism and kinetics of pseudomorphic mineral replacement reactions: A case study of the replacement of pentlandite by violarite

Although pseudomorphic mineral replacement reactions are common in all geological environments, and have long been considered important to many geological processes such as metamorphism, metasomatism, diagenesis, and chemical weathering, their mechanisms are still not well known. We present a combined textural and kinetic study of the replacement of pentlandite, (Fe,Ni)₉S₈, by violarite (NiFe)₃S₄, and describe the mechanisms and kinetic behavior of this reaction by considering the role of the fluid phase, the causes of coupling between pentlandite dissolution and violarite precipitation, the rate-limiting steps controlling the kinetic behavior, and the origin of the length scale of the features preserved during pseudomorphism.The experiments were conducted under mild hydrothermal conditions (80-210 °C, vapor saturated pressures). Reaction kinetics shows a complex behavior depending on various physical and chemical parameters including temperature, pH, concentrations of various reaction species, solid-weight-to-fluid-volume-ratio and specific surface area. The rate of replacement (i) increases with temperature from 80 to 125 °C, then decreases as temperature further increases to 210 °C, (ii) first increases then decreases with decreasing pH from pH 6 to 1, (iii) increases with increasing concentration of oxidants such as O_2(aq), H₂O₂, and KMnO₄, but decreases with increasing concentration of Ni²⁺ and Fe³⁺, and with increasing solid-weight-to-fluid-volume ratio, (iv) increases linearly with the specific surface area. This kinetic behavior as well as the resulting textures revealed a coupled dissolution-reprecipitation reaction mechanism.Nanometer-scale pseudomorphic replacement, through which the crystallographic orientation of pentlandite is inherited by violarite, occurs only between 1 < pH < 6, and spatial coupling between dissolution and reprecipitation is controlled by the local solution chemistry as well as by epitaxial nucleation mediated by the pentlandite substrate. The kinetic results show that pentlandite dissolution is rate-limiting under mild acidic to neutral conditions (1 < pH < 6), while violarite precipitation is rate-limiting under strong acidic conditions (pH 1). The difference in rate-limiting steps influences the coupling mechanism and causes the different degrees of preservation (length scale of pseudomorphism) and different morphologies observed at high and low pHs: pentlandite dissolution being rate-limiting results in nanoscale coupling between dissolution and precipitation and thus nanoscale pseudomorphism (length scale <20 nm), in which the replacement precisely preserves the morphology and internal details, resembling remarkably the natural pentlandite/violarite assemblages. In contrast, violarite precipitation being rate-limiting results in microscale pseudomorphism (length scale ∼10 μm): the morphology of the pentlandite grains is only roughly preserved and internal details are not preserved.This case study illustrates some general principles of replacement reactions proceeding via the coupled dissolution-reprecipitation mechanism: (i) primary mineral dissolution needs to be rate-limiting compared to the secondary mineral precipitation in order to achieve a high degree pseudomorphic replacement; (ii) the effects of solution composition on reaction kinetics can be qualitatively rationalized by considering the rate-limiting step reaction.     

Re-Os and Mo isotope systematics of black shales from the Middle Proterozoic Velkerri and Wollogorang Formations, McArthur Basin, northern Australia

Joint application of the Mo isotope paleoredox proxy and Re-Os deposition-age geochronometer to euxinic black shales has potential for tracing the evolution of ocean redox chemistry over geological time. Here, we report new Re-Os and Mo isotope data for the Mesoproterozoic Velkerri Formation (Roper Group) and Paleoproterozoic Wollogorang Formation (Tawallah Group), McArthur Basin, northern Australia. New Re-Os ages of 1361 ± 21 Ma (2σ, n = 14, mean square of weighted deviates [MSWD] = 1.3, Model 1) and 1417 ± 29 Ma (2σ, n = 12, MSWD = 1.3, Model 1) constrain the depositional age of the Velkerri Formation and its contained biomarkers, as well as acritarchs and microfossils from the Roper Group. Black shales from the upper Velkerri Formation have high Mo abundances (105-119 ppm) and degree of pyritization [DOP] values (0.90-0.92) implying quantitative conversion of molybdate (MoO₄²⁻) to thiomolybdate (MoS₄²⁻) in overlying bottom waters. The average δ^97/95Mo (0.72 ± 0.10‰, 2σ, n = 6) of these shales is consistent with previous data, but represents a significantly more precise determination for global seawater δ^97/95Mo at 1.4 Ga. This value is lighter than present-day seawater by ∼0.85‰ and reflects expanded strongly euxinic deep ocean conditions ([H₂S]_aq > 11 μM) relative to oxic, suboxic, and weakly/intermittently euxinic ([H₂S]_aq < 11 μM) marine deposition in the 1.4 Ga oceans. Mass-balance modelling suggests Mo removal into strongly euxinic and oxic sediments may have comprised 30-70% and less than 15%, respectively, of the oceanic Mo sink at 1.4 Ga as opposed to 5% and 35% today, respectively.The Re-Os radioisotope system in organic-rich shales serves as a test for post-depositional alteration that could affect the usefulness of paleoredox tracers such as Mo stable isotopes. Re-Os isotope data for the Wollogorang Formation black shales are scattered and yield a highly imprecise date of 1359 ± 150 Ma (2σ, n = 21, MSWD = 85, Model 3). This age is younger than U-Pb zircon ages from interbedded tuffs that constrain the age of deposition at ca. 1730 Ma. In conjunction with previous petrological, geochemical, and paleomagnetic data, the Re-Os isotope data suggest hydrothermal fluid flow through the Wollogorang Formation, possibly associated with formation of the ca. 1640 Ma McArthur River Pb-Zn-Ag sedimentary exhalative deposit, resulted in post-depositional mobilization of Re and Os. Based on the degree of deviation of the Re-Os data from a 1730 Ma reference line, open-system behavior of Re and Os was greatest near the base of the black shale unit. Wollogorang Formation black shales are enriched in Mo (41-58 ppm), but are characterized by variable δ^97/95Mo (0.3-0.8‰) and DOP (0.57-0.92). The lightest δ^97/95Mo values occur near the base of the black shale unit. Based on the Re-Os systematics, hydrothermal fluids have probably overprinted the authigenic δ^97/95Mo signature in those shales. However, the heaviest δ^97/95Mo values in the Wollogorang Formation come from stratigraphically higher shales, and are similar to those observed for the Velkerri Formation, and thus may reflect seawater δ^97/95Mo at 1.73 Ga.