Towards a model for the in situ origin of PGE reefs in layered intrusions: insights from chromitite seams of the Rum Eastern Layered Intrusion, Scotland

The current debate on the origin of platinum-group element (PGE) reefs in layered intrusions centres mostly on gravity settling of sulphide liquid from overlying magma versus its introduction with interstitial melt/fluids migrating upward from the underlying cumulate pile. Here, we show that PGE-rich chromitite seams of the Rum Eastern Layered Intrusion provide evidence for an alternative origin of such deposits in layered intrusions. These laterally extensive 2-mm-thick chromitite seams occur at the bases of several cyclic mafic–ultramafic units and show lithological and textural relationships suggesting in situ growth directly at a crystal–liquid interface. This follows from chromitite development along the edges of steeply inclined culminations and depressions at unit boundaries, even where these are vertically oriented or overhanging. High concentrations of PGE (up to 2–3 ppm Pd + Pt) are controlled by fine-grained base-metal sulphides, which are closely associated with chromitite seams. The following sequence of events explains the origin of the PGE-rich chromitite seams: (a) emplacement of picritic magma that caused thermal and mechanical erosion of underlying cumulate, followed by in situ growth of chromite against the base, (b) precipitation of sulphide droplets on chromite grains acting as favourable substrate or catalyst for sulphide nucleation, (c) the scavenging of PGE by sulphide droplets from fresh magma continuously brought towards the base by convection. Since the rate of magma convection is 10⁵–10⁷ times higher than that of the solidification (km/year to km/day versus 0.5–1.0 cm/year), the in situ formed sulphide droplets can equilibrate with picritic magma of thousands to million times their own volume. As a result, the sulphide-bearing rocks are able to reach economic concentrations of PGE (several ppm). We tentatively suggest that the basic principles of our model may be used to explain the origin of PGE-rich chromitites and classical PGE reefs in other layered mafic–ultramafic intrusions.     

Constraints on the structure and dynamics of the β-cristobalite polymorphs of SiO2 and AlPO4 from 31P, 27Al and 29Si NMR spectroscopy to 770 K

Nuclear magnetic resonance spectroscopic data are presented for the cristobalite polymorphs of AlPO₄ and SiO₂ from RT to 770 K, through their respective α-β transitions. The nuclear magnetic resonance (NMR) data include chemical shifts for ³¹P, ²⁷Al, and ²⁹Si, ²⁷Al quadrupole coupling parameters, and ³¹P and ²⁷Al spin-lattice relaxation rates. Also presented are electron diffraction patterns of β-cristobalite AlPO₄ that show diffuse scattering similar to that reported previously for SiO₂. For the α-phases of both AlPO₄ and SiO₂, the chemical shifts decrease approximately linearly with increasing temperature from RT to T_c and discontinuously by -2 to -3 ppm from α to β. This result is consistent with a small, continuous increase in the mean T-O-T angle (〈θ〉) of the α-phases with increasing T and an increase of 〈θ〉 by about 4° across the α-β transition for both cristobalite and its AlPO₄ analogue. Based on the ²⁹Si chemical shifts, the mean Si-O-Si angle for β-cristobalite is 152.7±1° near T_c. For AlPO₄-cristobalite, the ²⁷Al nuclear quadrupole coupling constant (C_Q) decreases approximately linearly from 1.2 MHz at RT to 0.94 MHz near T_c (493±10 K). At the α-β transition the ²⁷Al C_Q approaches zero, in agreement with the cubic average structure observed by diffraction. The satellite transitions retain a small frequency distribution above the α-β transition from electric field gradients attributed to defects. The short-range cubic symmetry of the Al-site and non-linear Al-O-P angle support a dynamically disordered model of the β-cristobalite structure. Complete averaging of the ²⁷Al quadrupole coupling in the β-phase indicates that the lifetime of any short-range ordered domains must be shorter than about 1 μs.     

The baseflow and storm flow hydrology of a precambrian shield headwater peatland

A hydrological investigation was conducted in a small headwater peatland located in the Experimental Lakes Area, north-western Ontario, Canada, to determine the subsurface and surface flow paths within the peatland, and between the peatland and an adjacent forested upland during baseflow and storm flow conditions. Distinct zones of groundwater recharge and discharge were observed within the peatland. These zones are similar to those found in much larger flow systems even though the peatland was only influenced by local groundwater flow. Groundwater emerging in seeps and flowing beneath the peatland sustained the surface wetness of the peatland and maintained a constant baseflow. The response of the peatland stream to summer rain events was controlled by peatland water table position when the basin was dry and antecedent moisture storage on the uplands when the basin was wet. The magnitude and timing of peak runoff during wet conditions were controlled by the degree of hydrological connectivity between the surrounding upland terrain and the peatland. © 1998 John Wiley & Sons, Ltd.     

High‐frequency precipitation and stream water quality time series from Plynlimon,Wales: an openly accessible data resource spanning the periodic table

This scientific briefing announces the availability of a new multi‐element high‐frequency water quality data set that is openly accessible to the research community. The data set comprises up to 2 years of 7‐hourly water quality data for two streams and one rainfall site in the Upper Severn catchment at Plynlimon in Mid‐Wales. The measurements cover 50 analytes ranging from H⁺ to U and spanning six orders of magnitude in concentration, including major, minor and trace elements as well as nutrients, and they complement decades of weekly measurements of the same analytes at the Upper Severn. Together, the weekly and 7‐hourly time series provide a unique data set for studying both long‐term trends and short‐term dynamics. The data show complex behaviour over a wide range of timescales, challenging our understanding of catchment processes and informing future modelling efforts. Copyright © 2013 John Wiley & Sons, Ltd.     

Effects of the invasive plant Lupinus polyphyllus on vertical accretion of fine sediment and nutrient availability in bars of the gravel-bed Paloma river

Floodplain vegetation is fundamental in fluvial systems, controlling river corridor geomorphology and ecology through a series of hydraulic, sedimentological, and biological processes. Changes caused by introduced plant species can thus result in shifts in river regime, succession trajectories and nutrient availability, affecting native biodiversity. The exotic bigleaf or marsh lupine Lupinus polyphyllus, introduced in Patagonia in the last decades, is aggressively invading fluvial corridors. It fills unoccupied ecological niches in southern Chilean rivers, due to its capacity for nitrogen fixation, its perennial habit, and high shoot density and leaf surface area.We investigated the effects of L. polyphyllus on vertical accretion of fine sediment, and soil carbon and nitrogen content, on gravel bars of the Paloma river, Chilean Patagonia, where lupine is believed to have been introduced in 1994. We sampled plot pairs with and without lupine, with each pair located at the same elevation above river stage, and plots distributed over the reach scale. We measured the thickness of the fine soil horizon, grain size distribution, and soil carbon and nitrogen content. We also compared aerial photographs to evaluate changes in spatial coverage of lupine along the study reach.Presence of lupine was strongly correlated with a thicker layer of finer sediment, in turn characterized by higher organic carbon, carbon to nitrogen ratio, and inorganic carbon content. Contrary to our expectations, we did not find any significant differences in total nitrogen. Aerial photographs did not reveal important differences in coverage between 2007 and 2010, but plant density appears to have increased between the two dates, and invaded gravel bars also appear to be more stable. Lupine dominance of otherwise sparsely vegetated gravel bars in Patagonian rivers appears to have greatest consequences on bar physical structure (increased rates of accretion of fines) and secondary repercussions on soil quality (increase in recalcitrant organic matter), with potential transient effects on nutrient availability (possible increased soil metabolism, followed by carbon mineralization and loss of lupine nitrogen subsidy).     

Ecotoxicological effects of a semi-submerged municipal dump (Castle harbour, Bermuda) on the Calico scallop Argopecten gibbus

A biomarker study was undertaken using the Calico scallop Argopecten gibbus to assess the ecotoxicological effects of a semi-submerged municipal dump on the adjacent patch reef lagoon ecosystem (Castle harbour, Bermuda). Caged scallops were deployed in situ for 2 months at various distances from the dump (50 m, 900 m and 2.7 km) and at a reference site (14 km). A suite of biomarkers comprising metallothionein (MT), lipid peroxidation (LPO), vitellin-like proteins (Vn), glutathione S-transferase (GST), DNA strand breaks and condition factor (CF) were investigated in various tissues of the scallop (gill, digestive gland and gonad). Levels of heavy metals were also measured in the whole scallop soft tissue. While there was some variation in response between tissues, in general the results indicated that the dump was negatively impacting scallops deployed in the adjacent marine environment: elevated levels of MT, DNA strand breaks, Vn and GST and reduced condition factor were found for scallops deployed nearest to the dump and at the site 1.5 km from this point source of contamination (Tuckers town) in Castle harbour, with respect to the reference site, North Rock (although this exhibited some degree of metal contamination). The gills from scallops deployed at the dump site were the most responsive tissue, with the highest expression of MT, LPO and DNA damage. This study indicates the potential of the Calico scallop as a convenient bioindicator species in the marine tropical benthos.     

Parsimonious sediment transport equations based on Bagnold's stream power approach

It is increasingly recognized that effective river management requires a catchment scale approach. Sediment transport processes are relevant to a number of river functions but quantifying sediment fluxes at network scales is hampered by the difficulty of measuring the variables required for most sediment transport equations (e.g. shear stress, velocity, and flow depth). We develop new bedload and total load sediment transport equations based on specific stream power. These equations use data that are relatively easy to collect or estimate throughout stream networks using remote sensing and other available data: slope, discharge, channel width, and grain size. The new equations are parsimonious yet have similar accuracy to other, more established, alternatives. We further confirm previous findings that the dimensionless critical specific stream power for incipient particle motion is generally consistent across datasets, and that the uncertainty in this parameter has only a minor impact on calculated sediment transport rates. Finally, we test the new bedload transport equation by applying it in a simple channel incision model. Our model results are in close agreement to flume observations and can predict incision rates more accurately than a more complicated morphodynamic model. These new sediment transport equations are well suited for use at stream network scales, allowing quantification of this important process for river management applications. Copyright © 2017 John Wiley & Sons, Ltd.     

Design, Installation, and Uses of Combination Ground Water and Gas Sampling Wells

Waste disposal sites with volatile organic compounds (VOCs) frequently contain contaminants that are present in both the ground water and vadose zone. Vertical sampling is useful where transport of VOCs in the vadose zone may effect ground water and where steep vertical gradients in chemical concentrations are anticipated. Designs for combination ground water and gas sampling wells place the tubing inside the casing with the sample port penetrating the casing for sampling. This physically interferes with pump or sampler placement. This paper describes a well design that combines a ground water well with gas sampling ports by attaching the gas sampling tubing and ports to the exterior of the casing. Placement of the tubing on the exterior of the casing allows exact definition of gas port depth, reduces physical interference between the various monitoring equipment, and allows simultaneous remediation and monitoring in a single well. The usefulness and versatility of this design was demonstrated at the Idaho National Engineering and Environmental Laboratory (INEEL) with the installation of seven wells with 53 gas ports, in a geologic formation consisting of deep basalt with sedimentary interbeds at depths from 7.2 to 178 m below land surface. The INEEL combination well design is easy to construct, install, and operate.     

Seismic design, modelling and assessment of self-centering steel frames using post-tensioned connections with web hourglass shape pins

A new self-centering steel post-tensioned connection using web hourglass shape pins (WHPs) has been recently developed and experimentally validated. The connection isolates inelastic deformations in WHPs, avoids damage in other connection parts as well as in beams and columns, and eliminates residual drifts. WHPs do not interfere with the composite slab and can be very easily replaced without bolting or welding, and so, the connection enables non-disruptive repair and rapid return to building occupancy in the aftermath of a strong earthquake. This paper presents a simplified nonlinear model for the connection and the associated beams and columns that consists of nonlinear beam-column elements, and hysteretic and contact zero-length spring elements appropriately placed in the beam-column interface. The model was calibrated against experimental results and found to accurately simulate the connection behaviour. A prototype building was selected and designed as a conventional steel moment-resisting frame (MRF) according to Eurocode 8 or as a self-centering steel MRF (SC-MRF) using the connection with WHPs. Seismic analyses results show that the conventional MRF and the SC-MRF have comparable peak storey drifts, and highlight the inherent potential of the SC-MRF to eliminate damage in beams and residual drifts. The paper also shows that repair of damage in the conventional MRF will be costly and disruptive after the design basis earthquake, and, not financially viable after the maximum considered earthquake due to large residual drifts.     

Field Survey of the March 28, 2005 Nias-Simeulue Earthquake and Tsunami

On the evening of March 28, 2005 at 11:09?p.m. local time (16:09 UTC), a large earthquake occurred offshore of West Sumatra, Indonesia. With a moment magnitude (M _w) of 8.6, the event caused substantial shaking damage and land level changes between Simeulue Island in the north and the Batu Islands in the south. The earthquake also generated a tsunami, which was observed throughout the source region as well as on distant tide gauges. While the tsunami was not as extreme as the tsunami of December 26th, 2004, it did cause significant flooding and damage at some locations. The spatial and temporal proximity of the two events led to a unique set of observational data from the earthquake and tsunami as well as insights relevant to tsunami hazard planning and education efforts.