Synoptic measurements of episodic offshore flow events in the central mid-Atlantic Bight

Sub-inertial across-shelf flows over the central mid-Atlantic Bight were examined using long-range CODAR SeaSonde type HF-radar surface velocities for the period August 2002 through February 2004. Across-shelf flow in this region was found to be episodic, with offshore flow occurring six times more often than onshore flow. Several recurring spatial patterns in offshore flow are identified, and two of these patterns emerge as statistically significant using empirical orthogonal functions. The most common type of offshore flow was a shelf-wide flow with events occurring throughout the year. The most energetic and well-defined shelf-wide flow events occurred during October through April, when the water column was less stratified. Other offshore flow patterns were more localized, with a flow at the bend or ‘point’ in the New Jersey coast being most common and most energetic. The offshore flow events identified here are capable of driving significant offshore transport, with more than one-third of offshore flow episodes having potential transport distances of greater than 14 km. In addition, clusters of multiple offshore flow events are shown to be capable of transporting near-surface material across much of the continental shelf.     

Hydrological change in the central interior of British Columbia,Canada: diatom and pollen evidence of millennial-to-centennial scale change over the Holocene

Diatom-based inferences of post-glacial hydrological change from a sedimentary record from Felker Lake, British Columbia, show millennial-scale pacing of climate over the past approximately 11670 calendar years with change at ca. 8140 cal. year BP, ca. 6840 cal. year BP, ca. 5700 cal. year BP, and ca. 2230 cal. year BP. Early postglacial diatom assemblages are dominated by fragilaroid taxa, suggesting that cool and moist climate conditions and relatively high lake levels prevailed at this time. Early Holocene warming near ca. 8140 cal. year BP promoted Cyclotella bodanica var. lemanica, a fall bloomer competitive in limnological conditions associated with warmer water and stratified conditions. Short-lived peaks of Stephanodiscus parvus/minutulus between ca. 6340 cal. year BP and ca. 5860 cal. year BP indicate periodic increases in nutrient availability and prolonged mixing likely associated with long cool and moist spring seasons. The diatom-inferred depth of Felker Lake increased during the mid-Holocene to reach a record high-stand at ca. 5860 cal. year BP. Large changes in hydrological variability and terrestrial vegetation at Felker Lake occurred after ca. 2230 cal. year BP when high-amplitude centennial-scale fluctuations in diatom-inferred lake depth and salinity are observed. Change is first documented in terrestrial vegetation at this time by a shift from open Pinus parklands to a landscape that periodically supported populations of Cupressaceae. Three record low-stand high-salinity events are reconstructed between ca. 1910 cal. year BP and ca. 1800 cal. year BP, ca. 1030 cal. year BP and ca. 690 cal. year BP, and ca. 250 cal. year BP and ca. 140 cal. year BP. The low lake-level episode of ca. 1030 cal. year BP–ca. 690 cal. year BP is coeval with the Medieval Warm Period (ca. 1000 cal. year BP–ca. 600 cal. year BP), a period of intense drought in western North America. Post-glacial hydrological change at Felker Lake is coherent with regional, hemispherical, and global paleoclimate events, suggesting that millennial-and centennial-scale shifts in water availability are a persistent feature of the climate of western North America.     

Mineralogy and origin of rhizoliths on the margins of saline,alkaline Lake Bogoria,Kenya Rift Valley

A wide range of rhizoliths occurs around the margins of Lake Bogoria, Kenya. These include root casts, moulds, tubules, rhizocretions, and permineralised root systems. These rhizoliths are variably composed of opaline silica, calcite, zeolites (mainly analcime), fluorite, and possibly fluorapatite, either alone or in combinations. Some rhizoliths are infilled moulds with detrital silicate grains. Most rhizoliths are in situ, showing both vertical and horizontal orientations. Reworked rhizoliths have been concentrated locally to form dense rhizolites.Hot-spring fluids, concentrated by evapotranspiration and capillary evaporation, have provided most of the silica for the permineralisation of the plant tissues. Precipitation involved the growth of silica nanospheres and microspheres that coalesced into homogeneous masses. Calcite rhizoliths formed following evaporative concentration, evapotranspiration, and (or) CO₂ degassing of Ca-bearing runoff water that infiltrated the sediment, or by mixing of runoff with saline, alkaline groundwater. Fluorite precipitated in areas where mixing of hot-spring and meteoric waters occurred, or possibly where hot-spring fluids came into contact with pre-existing calcite. Zeolitic rhizoliths formed during a prolonged period of aridity, when capillary rise and evaporative pumping brought saline, alkaline waters into contact with detrital silicate minerals around roots.     

A comparison between rubble-pile and monolithic targets in impact simulations: Application to asteroid satellites and family size distributions

Collisions are a fundamental process in the creation of asteroid families and in satellite formation. For this reason, understanding the outcome of impacts is fundamental to the accurate modeling of the formation and evolution of such systems. Smoothed-Particle Hydrodynamics/N-body codes have become the techniques of choice to study large-scale impact outcomes, including both the fragmentation of the parent body and the gravitational interactions between fragments. It is now possible to apply this technique to targets with either monolithic or rubble-pile internal structures. In this paper we apply these numerical techniques to rubble-pile targets, extending previous investigations by Durda et al. (Durda, D.D., Bottke, W.F., Enke, B.L., Merline, W.J., Asphaug, E., Richardson, D.C., Leinhardt, Z.M. [2004]. Icarus 170, 243–257; Durda, D.D., Bottke, W.F., Nesvorný, D., Enke, B.L., Merline, W.J., Asphaug, E., Richardson, D.C. [2007]. Icarus 186, 498–516). The goals are to study asteroid–satellite formation and the morphology of the size–frequency distributions (SFDs) from 175 impact simulations covering a range of collision speeds, impact angles, and impactor sizes. Our results show that low-energy impacts into rubble-pile and monolithic targets produce different features in the resulting SFDs and that these are potentially diagnostic of the initial conditions for the impact and the internal structure of the parent bodies of asteroid families. In contrast, super-catastrophic events (i.e., high-energy impacts with large specific impact energy) result in SFDs that are similar to each other. We also find that rubble-pile targets are less efficient in producing satellites than their monolithic counterparts. However, some features, such as the secondary-to-primary diameter ratio and the relative separation of components in binary systems, are similar for these two different internal structures of parent bodies.     

Geochemical processes in the Onyx River, Wright Valley, Antarctica: Major ions, nutrients, trace metals

We present data on major ions, nutrients and trace metals in an Antarctic stream. The Onyx River is located in Wright Valley (77-32 S; 161-34 E), one of a group of ancient river and glacier-carved landforms that comprise the McMurdo Dry Valleys of Antarctica. The river is more than 30 km long and is the largest of the glacial meltwater streams that characterize this relatively ice-free region near the Ross Sea. The complete absence of rainfall in the region and the usually small contributions of glacially derived tributaries to the main channel make this a comparatively simple system for geochemical investigation. Moreover, the lack of human impacts, past or present, provides an increasingly rare window onto a pristine aquatic system.For all major ions and silica, we observe increasing concentrations with distance from Lake Brownworth down to the recording weir near Lake Vanda. Chemical weathering rates are unexpectedly high and may be related to the rapid dissolution of ancient carbonate deposits and to the severe physical weathering associated with the harsh Antarctic winter. Of the nutrients, nitrate and dissolved reactive phosphate appear to have quite different sources. Nitrate is enriched in waters near the Lower Wright Glacier and may ultimately be derived from stratospheric sources; while phosphate is likely to be the product of chemical weathering of valley rocks and soils. We confirm the work of earlier investigations regarding the importance of the Boulder Pavement as a nutrient sink.Dissolved Mn, Fe, Ni, Cu, and Cd are present at nanomolar levels and, in all cases, the concentrations of these metals are lower than in average world river water. We hypothesize that metal uptake and exchange with particulate phases along the course of the river may serve as a buffer for the dissolved load. Concurrent study of these three solute classes points out significant differences in the mechanisms and sites of their removal from the Onyx River.     

The solar occultation for ice experiment

The Solar Occultation For Ice Experiment (SOFIE) was launched onboard the Aeronomy of Ice in the Mesosphere (AIM) satellite on 25 April 2007, and began science observations on 14 May 2007. SOFIE conducts solar occultation measurements in 16 spectral bands that are used to retrieve vertical profiles of temperature, O₃, H₂O, CO₂, CH₄, NO, and polar mesospheric cloud (PMC) extinction at wavelengths from 0.330 to 5.006 μm. SOFIE performs 15 sunset measurements at latitudes from 65° to 85°S and 15 sunrise measurements from 65° to 85°N each day. This work describes the SOFIE instrument, measurement approach, and retrieval results for the northern summer of 2007.     

Variability of Monsoon Climate in East Asia at the End of the Last Glaciation

High-resolution paleomonsoon proxy records from peat and eolian sand–paleosol sequences at the desert–loess transition zone in China denote a rapid oscillation from cold–dry conditions (11,200–10,600¹⁴C yr B.P.) to cool–humid conditions (10,600–10,200¹⁴C yr B.P.), followed by a return to cold–dry climate (10,200–10,000¹⁴C yr B.P.). Variations in precipitation proxies suggest that significant climatic variability occurred in monsoonal eastern Asia during the Younger Dryas interval. Late-glacial climate in the Chinese desert–loess belt that lies downwind from Europe was strongly influenced by cold air from high latitudes and from the North Atlantic via the westerlies. The inferred precipitation variations were likely caused by variations in the strength of the Siberian high, which influenced the pressure gradient between land and ocean and therefore influenced the position of the East Asian monsoon front.     

Characterisation of a Natural Quartz Crystal as a Reference Material for Microanalytical Determination of Ti,Al, Li,Fe, Mn,Ga and Ge

A natural smoky quartz crystal from Shandong province, China, was characterised by laser ablation ICP‐MS, electron probe microanalysis (EPMA) and solution ICP‐MS to determine the concentration of twenty‐four trace and ultra trace elements. Our main focus was on Ti quantification because of the increased use of this element for titanium‐in‐quartz (TitaniQ) thermobarometry. Pieces of a uniform growth zone of 9 mm thickness within the quartz crystal were analysed in four different LA‐ICP‐MS laboratories, three EPMA laboratories and one solution‐ICP‐MS laboratory. The results reveal reproducible concentrations of Ti (57 ± 4 μg g^?1), Al (154 ± 15 μg g^?1), Li (30 ± 2 μg g^?1), Fe (2.2 ± 0.3 μg g^?1), Mn (0.34 ± 0.04 μg g^?1), Ge (1.7 ± 0.2 μg g^?1) and Ga (0.020 ± 0.002 μg g^?1) and detectable, but less reproducible, concentrations of Be, B, Na, Cu, Zr, Sn and Pb. Concentrations of K, Ca, Sr, Mo, Ag, Sb, Ba and Au were below the limits of detection of all three techniques. The uncertainties on the average concentration determinations by multiple techniques and laboratories for Ti, Al, Li, Fe, Mn, Ga and Ge are low; hence, this quartz can serve as a reference material or a secondary reference material for microanalytical applications involving the quantification of trace elements in quartz.