Effects of stormwater nutrient discharges on eutrophication processes in nearshore waters of the Florida keys

Rainfall events cause episodic discharges of groundwaters contaminated with septic tank effluent into nearshore waters of the Florida keys, enhancing eutrophication in sensitive coral reef communities. Our study characterized the effects of stormwater discharges by continuously (30-min intervals) measuring salinity, temperature, tidal stage, and dissolved oxygen (DO) along an offshore eutrophication gradient prior to and following heavy rainfall at the beginning of the 1992 rainy season. The gradient included stations at a developed canal system (PP) on Big Pine Key, a seagrass meadow in a tidal channel (PC), a nearshore patch reef (PR), a bank reef at Looe Key National Marine Sanctuary (LK), and a blue water station (BW) approximately 9 km off of Big PIne Key. Water samples were collected at weekly intervals during this period to determine concentrations of total nitrogen (TN), ammonium (NH₄ ⁺), nitrate plus nitrite NO₃ ^? plus NO₂ ^?), total phosphorus (TP), total dissolved phosphorus (TDP), soluble reactive phosphorus (SRP), and chlorophyll a (chl a). Decreased salinity immediately followed the first major rainfall at Big Pine Key, which was followed by anoxia (DO <0.1 mg I^?1), high concentrations of NH₄ ⁺ (≈24 μM), TDP (≈1.5 μM), and chl a (≈20 μg I^?1). Maximum concentration of TDP (≈0.30 μM) also followed the initial rainfall at the PC, PR, and LK stations. In contrast, NH₄ ⁺ (≈4.0 μM) and chl a (0.45 μg I^?1) lagged the rain event by 1–3 wk, depending on distance from shore. The highest and most variable concentrations of NH₄ ⁺, TDP, and chl a occurred at PP, and all nutrient parameters correlated positively with rainfall. DO at all stations was positively correlated with tide and salinity and the lowest values occurred during low tide and low salinity (high rainfall) periods. Hypoxia (DO <2.5 mg I^?1) was observed at all stations follwing the stormwater discharges, including the offshore bank reef station LK. Our study demonstrated that high frequency (daily) sampling is necessary to track the effects of episodic rainfall events on water quality and that such effects can be detected at considerable distances (12 km) from shore. The low levels of DO and high levels of nutrients and chl a in coastal waters of the Florida Keys demand that special precautions be exercised in the treatment and discharge of wastewaters and land-based runoff in order to preserve sensitive coral reef communities.     

Adjusting to Policy Expectations in Climate Change Modeling

This paper surveys and interprets the attitudes of scientists to the use of flux adjustments in climate projections with coupled Atmosphere Ocean General Circulation Models. The survey is based largely on the responses of 19 climate modellers to several questions and a discussion document circulated in 1995. We interpret the responses in terms of the following factors: the implicit assumptions which scientists hold about how the environmental policy process deals with scientific uncertainty over human-related global warming; the different scientific styles that exist in climate research; and the influence of organisations, institutions, and policy upon research agendas. We find evidence that scientists' perceptions of the policy process do play a role in shaping their scientific practices. In particular, many of our respondents expressed a preference for keeping discussion of the issue of flux adjustments within the climate modeling community, apparently fearing that climate contrarians would exploit the issue in the public domain. While this may be true, we point to the risk that such an approach may backfire. We also identify assumptions and cultural commitments lying at a deeper level which play at least as important a role as perceptions of the policy process in shaping scientific practices. This leads us to identify two groups of scientists, pragmatists and purists, who have different implicit standards for model adequacy, and correspondingly are or are not willing to use flux adjustments.     

The occultation of κ geminorum by Eros

The predictions and observations of the occultation of κ Gem by Eros on January 24, 1975, are described. At least eight positive and several critical negative observations were made in western New England. The paucity of observations on the western side of the track makes the analysis somewhat ambiguous, but a circular cross section of diameter up to 23 km gives a good fit to most of the available data. Consideration of a crucial, unconfirmed negative observation indicates that an elliptical solution 17 by 7 km (with the long axis in the direction of motion of the “shadow” of Eros) may be preferable, but this does not represent the positive observations so satisfactorily. The ellipse was therefore distorted into a more irregular shape about 20 km long and 7 km wide, rounded on one long side and flattened on the other. Both this irregular shape and the ellipse yield geometric albedos near 0.5, which is considerably higher than has been derived for most other planets or satellites lacking an atmosphere. The albedo that corresponds to the circular solution (0.1) is less than the polarimetric albedo of 0.21 for Eros. It is suggested either that the circle should be warped into an ellipse of dimensions 21 by 13 km, or, if some weight is given to the critical negative observation and the westernmost positive observation, that the profile is a kind of dumbbell.     

The structure of rotating stars from an extension of the Kippenhahn-Thomas method

A method is presented whereby the structure of rotating stars may be determined from an initial guess at the geometry of equipotential surfaces. The method may be considered an extension of the work of Kippenhahn and Thomas in that a uniformly continuous geometry is defined in terms of the appropriate spherical model with Roche characteristics at the surface of the configuration and sphericity at the centre. A simple Cowling model in uniform rotation is employed to illustrate the technique and for comparison purposes with previous work.     

Potentiometric and F nuclear magnetic resonance spectroscopic study of fluoride substitution in the GaAl12 polyoxocation: implications for aluminum (hydr)oxide mineral surfaces

Fluoride replacement of oxygens in the GaO₄Al₁₂(OH)₂₄(H₂O)127+(aq) molecule [GaAl₁₂] was studied via ¹⁹F nuclear magnetic resonance (NMR) at 4 < pH < 5 and 278 K in order to elucidate similar reactions at the surfaces of clays. Peaks are identified in the ¹⁹F-NMR spectra that correspond to both terminal and bridging fluorides on the GaAl₁₂ molecule, with relative peak positions similar to those previously identified in fluoridated aluminum (hydr)oxide mineral surfaces (Nordin, J. P., Sullivan, D. J., Phillips, B. L., and Casey, W. H. [1999], “Mechanisms for fluoride-promoted dissolution of bayerite [β-Al(OH)₃(s)] and boehmite [γ-AlOOH(s)]-¹⁹F-NMR spectroscopy and aqueous surface chemistry,” Geochim. Cosmochim. Acta63, 3513-3524). Fluoride substitutes for oxygen at three different sites in the GaAl₁₂ molecule, but at dramatically different rates.The kinetics of fluoride substitution follow a rate law that includes parallel and reversible transfer of fluoride from nonbridging sites to the two bridging sites. The essential features of the rate law are as follows: (1) fluoride replaces bound water molecules (η-OH₂) within minutes at 278 K at rates that are quantitatively similar to fluoride uptake by Al(H₂O)63+(aq) to form AlF²⁺(aq) at similar conditions; (2) fluoride substitutes onto the two topologically distinct μ₂-OH sites at different rates, as was previously observed for oxygen exchange, but here, the reaction is complete in hours to days at 278 K. Most importantly, rates of fluoride substitution onto μ₂-OH sites are 10² times more rapid than the corresponding rates of oxygen exchange with bulk waters, indicating that fluoride considerably labilizes the molecule, as is also observed at the surfaces of minerals. The largest cause of this labilization is the reduced molecular charge on the GaAl₁₂ upon replacement of bound waters by fluoride, which for mineral surfaces corresponds to a reduction in surface charge density.