Magnetic polarity zonation within the El Teniente copper–molybdenum porphyry deposit, central Chile

El Teniente porphyry copper deposit, the world’s greatest intrusion-related Cu–Mo ore body, is hosted within basaltic–andesitic volcanic and gabbroic rocks (mafic complex). This ore body is strongly affected by multiple events of alteration/mineralization with pervasive potassic and chloritic alteration and coetaneous with associated copper mineralization. We present paleomagnetic results obtained from oriented samples at four locations within the mine and from two drill cores, 200 and 400 m long, respectively. Samples are representative of all the main hydrothermally altered rock units, with emphasis on the mafic host rock and dacitic (Teniente dacite porphyry) and dioritic porphyry intrusions. Magnetic experiments [hysteresis loop, isothermal remanent magnetization (IRM), k–T curves, thermal, and alternating field demagnetization] show the presence of prevailing magnetite. Microscope and SEM observations show two families of magnetite, (a) large multidomain magnetite grains, associated with biotite and chlorite of various different hydrothermal alteration events, and (b) abundant small to medium grain-size magnetite (<10 μm) contained within plagioclase, either related to an early Na–Ca–Fe alteration or included within plagioclase during magmatic crystal growth. While the Teniente dacite porphyry and the quartz diorite–tonalite have low magnetic susceptibility (<0.0005 SI) and low natural remanent magnetization (NRM, 10⁻⁴–10⁻³ Am⁻¹), the mineralized mafic host rocks have usually high susceptibility (>0.01 and up to 0.2 SI) with NRM in the range 0.1–2 Am⁻¹. Most mafic complex rock samples have univectorial magnetizations during alternating field or thermal demagnetization. Within the mine, the magnetic polarity is spatially distributed. In the northern part of the deposit, the Teniente dacite porphyry, the associated hydrothermal breccias, and the hosting mafic complex record a reverse polarity magnetization, also observed in the El Teniente sub-6 mine sector immediately to the east and southeast. In the eastern part of the deposit, a normal polarity is observed for samples of the mafic complex from the two long drill cores. There is no evidence for superimposed magnetizations of opposite polarities in samples of the mafic complex. Anhysteretic remanent magnetization (ARM) in a DC field of 40 μT and NRM have similar magnitude and comparable behavior upon alternating field demagnetization. The well-defined strong remanent magnetizations associated with high unblocking temperatures (>500°C) indicate an acquisition of remanent magnetization during mineralization by circulating high temperature fluids related with ore deposition. Paleomagnetic results and the recorded polarity zonation suggest multiple mineralization events occurred at El Teniente, each one with its own evolution stages, superimposed within the district. These results indicate that a simplified broad four-stage model for El Teniente, as presented and overly employed by many authors, divided in (1) late magmatic, (2) main hydrothermal, (3) late hydrothermal, and (4) posthumous stage, does not recognize various short-lived single mineralization events, some superimposed and some distinctly separated in time and space. There is no paleomagnetic evidence for post-mineralization deformation     

A Case Study on the Effects of Heterogeneous Soil Moisture on Mesoscale Boundary-Layer Structure in the Southern Great Plains, U.S.A. Part II: Mesoscale Modelling

The importance of soil moisture inputs and improved model physics in the prediction of the daytime boundary-layer structure during the Southern Great Plains Hydrology Experiment 1997 (SGP97) is investigated using the non-hydrostatic fifth-generation Pennsylvania State University/National Center for Atmospheric Research (PSU/NCAR) Mesoscale Model MM5. This is Part II of a two-part study examining the relationship of surface heterogeneity to observed boundary-layer structure. Part I focuses on observations and utilizes a simple model while Part II uses observations and MM5 modelling. Soil moisture inputs tested include a lookup table based on soil type and season, output from an offline land-surface model (LSM) forced by atmospheric observations, and high-resolution ( 800 m) airborne microwave remotely sensed data. Model physics improvements are investigated by comparing an LSM directly coupled with the MM5 to a simpler force-restore method at the surface. The scale of land surface heterogeneities is compared to the scale of their effects on boundary-layer structure.The use of more detailed soil moisture fields allowed the MM5 to better represent the large-scale (hundreds of km) and small-scale (tens of km) horizontal gradients in surface-layer weather and, to a lesser degree, the atmospheric boundary-layer (ABL) height, which was evaluated against observations measured by differential absorption lidar (DIAL). The benefits of coupling an LSM to the MM5 were not readily evident in this summertime case, with the model having particular difficulty simulating the timing of maximum surface fluxes while underestimating the depth of the mixed layer.     

Stromatoporoid growth forms and Devonian reef fabrics in the Upper Devonian Alexandra Reef System,Canada – Insight on the challenges of applying Devonian reef facies models

Existing facies models for Devonian reef systems can be divided into high‐energy and low‐energy types. A number of assumptions have been made in the development of these models and, in some cases, criteria that distinguish important aspects of the models are poorly defined. The Upper Devonian Alexandra Reef System contains a variety of reef fabrics from different depositional environments and is ideal for studying the range of environments in which stromatoporoids thrived and the facies from these different environments. A wide variety of stromatoporoid growth forms including laminar, tabular, anastamosing laminar and tabular, domal, bulbous, dendroid, expanding conical, concave‐up whorled‐laminar, concave‐up massive tabular and platy‐multicolumnar are present in the Alexandra Reef System. The whorled‐laminar and massive tabular concave‐up growth forms are virtually undocumented from other Devonian reefs but were common in the reef front of the Alexandra, where they thrived in a low‐energy environment around and below fair‐weather wave base. In contrast, high‐energy parts of the reef margin were dominated by bioclastic rubble deposits with narrow ribbon‐like discontinuous bodies of laminar stromatoporoid framestone. In the lagoon, laminar stromatoporoids formed steep‐sided sediment‐dominated bioherms in response to sea‐level rise and flooding. Relying mostly on the different reef facies in the Alexandra system, a new classification scheme for Devonian reef fabrics has been developed. Devonian reef fabrics can be classified as being: (i) sediment‐laden metazoan dominated; (ii) metazoan–microbial dominated (boundstone); (iii) metazoan dominated (framestone); or (iv) metazoan–marine cement dominated. Distinction of these fabrics carries important sedimentary and palaeoecological implications for reconstructing the depositional environment. With examples from the Alexandra Formation, it is demonstrated that reef facies accumulated in a range of depositional environments and that the simple observation of massive stromatoporoids with or without microbial deposits does not automatically imply a high‐energy reef margin, as otherwise portrayed in a number of the existing facies models for these systems.     

Neogene echinoids from the Cayman Islands,West Indies: regional implications

The first fossil echinoids are recorded from the Cayman Islands. A regular echinoid, Arbacia? sp., the spatangoids Brissus sp. cf. B. oblongus Wright and Schizaster sp. cf. S. americanus (Clark), and the clypeasteroid Clypeaster sp. are from the Middle Miocene Cayman Formation. Test fragments of the mellitid clypeasteroid, Leodia sexiesperforata (Leske), are from the Late Pleistocene Ironshore Formation. Miocene echinoids are preserved as (mainly internal) moulds; hence, all species are left in open nomenclature because of uncertainties regarding test architecture. All Miocene taxa are recorded from single specimens apart from the 27 assigned to Brissus. Schizaster sp. cf. S. americanus (Clark) is compared to a species from the Oligocene of the south‐east USA. Brissus sp. cf. B. oblongus is close in gross morphology to a taxon from the Miocene of Malta. Leodia sexiesperforata is identified from fragments with confidence, being the only extant Antillean sand dollar with elongate ambulacral petals that is limited to carbonate substrates. The Miocene echinoids of Grand Cayman, although of limited diversity, are mainly comprised of genera common in comparable mid‐Cenozoic carbonate environments. Copyright © 2015 John Wiley & Sons, Ltd.     

Potential for localized groundwater contamination in a porous pavement parking lot setting in Rhode Island

The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria) originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m²/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals and 27% for nutrients, respectively.     

Predation on the rocky shores of Patagonia,Argentina

Rocky intertidal communities of Argentinean Patagonia are exposed to harsh physical conditions caused by dry, strong southern trade winds (mean speed 45 km h^-1, gusts up to 140 km h^-1) that result in intense desiccation of intertidal organisms. Predator distributions in these communities were evaluated from April 2003 to December 2004 at two exposed headlands and six protected bays in Cabo dos Bahias (44°50′S, 65°40′W). Crabs and sea stars dominated the predator assemblage, with occasional scavenger snails and fish also present. During low tide, predators were never found in the open but were always associated with shelter (primarily within mussel beds and coralline algae), suggesting a strong predator dependency on foundation species to buffer them from physical stress. Few predators (mostly crabs) emerged from shelter at high tide. Unlike the larger predators found on Chilean rocky shores, invertebrate predators in this system are diminutive, generally < 2 cm. The lone exception was the newly discovered invasive green crab,Carcinus mamas. Feeding trials, gut content analyses, and visual surveys indicated that native predators feed primarily on small, soft-bodied prey.C. mamas fed on slow-moving and sessile animals, including the super abundant musselPerumytilus purpuratus, with much greater voracity than native predators. Because native intertidal organisms are dependent on mussel beds and coralline algae for shelter from desiccation, successful invasion ofC. mamas may lead to a significant decrease in native diversity by consuming foundation species. This study represents a preliminary survey of predator distributions and feeding habits on the rocky shores of Argentinean Patagonia and provides important baseline data to evaluate trophic linkages and predatory effects on Patagonian rocky shores.     

When hazard avoidance is not an option: lessons learned from monitoring the postdisaster Oso landslide,USA

On 22 March 2014, a massive, catastrophic landslide occurred near Oso, Washington, USA, sweeping more than 1 km across the adjacent valley flats and killing 43 people. For the following 5 weeks, hundreds of workers engaged in an exhaustive search, rescue, and recovery effort directly in the landslide runout path. These workers could not avoid the risks posed by additional large-scale slope collapses. In an effort to ensure worker safety, multiple agencies cooperated to swiftly deploy a monitoring and alerting system consisting of sensors, automated data processing and web-based display, along with defined communication protocols and clear calls to action for emergency management and search personnel. Guided by the principle that an accelerating landslide poses a greater threat than a steadily moving or stationary mass, the system was designed to detect ground motion and vibration using complementary monitoring techniques. Near real-time information was provided by continuous GPS, seismometers/geophones, and extensometers. This information was augmented by repeat-assessment techniques such as terrestrial and aerial laser scanning and time-lapse photography. Fortunately, no major additional landsliding occurred. However, we did detect small headscarp failures as well as slow movement of the remaining landslide mass with the monitoring system. This was an exceptional response situation and the lessons learned are applicable to other landslide disaster crises. They underscore the need for cogent landslide expertise and ready-to-deploy monitoring equipment, the value of using redundant monitoring techniques with distinct goals, the benefit of clearly defined communication protocols, and the importance of continued research into forecasting landslide behavior to allow timely warning.

     

Time scale of an early to mid-Paleozoic orogenic cycle of the long-lived Central Asian Orogenic Belt, Inner Mongolia of China: Implications for continental growth

We present a detailed, new time scale for an orogenic cycle (oceanic accretion–subduction–collision) that provides significant insights into Paleozoic continental growth processes in the southeastern segment of the long-lived Central Asian Orogenic Belt (CAOB). The most prominent tectonic feature in Inner Mongolia is the association of paired orogens. A southern orogen forms a typical arc-trench complex, in which a supra-subduction zone ophiolite records successive phases during its life cycle: birth (ca. 497–477 Ma), when the ocean floor of the ophiolite was formed; (2) youth (ca. 473–470 Ma), characterized by mantle wedge magmatism; (3) shortly after maturity (ca. 461–450 Ma), high-Mg adakite and adakite were produced by slab melting and subsequent interaction of the melt with the mantle wedge; (4) death, caused by subduction of a ridge crest (ca. 451–434 Ma) and by ridge collision with the ophiolite (ca. 428–423 Ma). The evolution of the magmatic arc exhibits three major coherent phases: arc volcanism (ca. 488–444 Ma); adakite plutonism (ca. 448–438 Ma) and collision (ca. 419–415 Ma) of the arc with a passive continental margin. The northern orogen, a product of ridge-trench interaction, evolved progressively from coeval generation of near-trench plutons (ca. 498–461 Ma) and juvenile arc crust (ca. 484–469 Ma), to ridge subduction (ca. 440–434 Ma), microcontinent accretion (ca. 430–420 Ma), and finally to forearc formation. The paired orogens followed a consistent progression from ocean floor subduction/arc formation (ca. 500–438 Ma), ridge subduction (ca. 451–434 Ma) to microcontinent accretion/collision (ca. 430–415 Ma); ridge subduction records the turning point that transformed oceanic lithosphere into continental crust. The recognition of this orogenic cycle followed by Permian–early Triassic terminal collision of the CAOB provides compelling evidence for episodic continental growth.     

Gaseous mercury emissions from urban surfaces: Controls and spatiotemporal trends

The spatial and temporal variability of Hg emissions from urban paved surfaces was assessed through repeated measurements under varying environmental conditions at six sample sites in Toronto, Ontario, Canada. The results show significant spatial variability of the Hg emissions with median values ranging from below detection limit to 5.2 ng/m²/h. Two of the sites consistently had higher Hg emissions (on several occasions >20 ng/m²/h) than the other 4, which were equivalently low (maximum emission: 2.1 ng/m²/h). A surrogate measure of the pavement Hg concentrations was obtained during each day of sampling through the collection of street dust. The median street dust concentration also showed significant spatial variability (ranging from 9.6 to 44.5 ng/g). Regression analysis showed that the spatial variability of the Hg emissions was significantly related to the street dust concentrations. Controlled experiments using Hg amended street dust confirmed the relationship between Hg surface concentration and emission magnitude. Within a given sample site, Hg emissions varied temporally and multiple regression analysis showed that within-site variability was significantly influenced by changes in solar radiation with only a minor effect from surface temperature. Controlled experiments using shade cloths confirmed that solar radiation can have a large influence on the magnitude of Hg emissions within a given site. The emissions measured in Toronto were contextualized through comparison sampling in Austin, Texas. The Hg emissions measured in Austin were within the range detected in Toronto and also showed significant correlation with Hg street dust concentrations between sites. To provide a holistic assessment of Hg emissions from urban environments, samples were also collected from other common urban surfaces (soil, roofs, and windows). Soils consistently had higher emissions than all the other surfaces (7.3 ng/m²/h, n = 39).